Based on the correlation between certain properties of liquid and the properties of the corresponding liquid drop formed under given conditions, a liquid drop measuring device is utilized to monitor the drop formation...Based on the correlation between certain properties of liquid and the properties of the corresponding liquid drop formed under given conditions, a liquid drop measuring device is utilized to monitor the drop formation process of the liquid sample with photoelectric measuring methods. The mechanical and optical characteristic of the liquid is explored with the optical fibers from the internal of the liquid drop during its formation. The drop head capacitor is utilized to monitor the growth process of the liquid drop to gain the drop volume information related to the physical property of liquid. The unique liquid drop trace containing the integrated properties of liquid is generated, and it is proved by experiment that for different liquids their liquid drop traces are different. The analysis on liquid properties and discrimination between different liquids can be proceeded with the liquid drop trace obtained by the liquid drop measuring device.展开更多
Temperature sensitivity is greatly improved by taking the following three measures: proper long-period fiber grating (LPFG) whose strain coefficient of the core is larger than that of the cladding is employed, the ...Temperature sensitivity is greatly improved by taking the following three measures: proper long-period fiber grating (LPFG) whose strain coefficient of the core is larger than that of the cladding is employed, the LPFG is coated with a thin film of the material whose refractive index decreases with the temperature, and the sensor is encapsulated by metal material whose thermal expansion coefficient is large. By computer simulation, a measured temperature coefficient of 0.2375 nm/℃ and a temperature resolution less than 0.1 ℃ are obtained.展开更多
As an important optical constant of optical properties for spectacle lens,the refractive index measurement is studied using V prism refractometer. In the experiment,according to various factors inducing measurement er...As an important optical constant of optical properties for spectacle lens,the refractive index measurement is studied using V prism refractometer. In the experiment,according to various factors inducing measurement error,the experimental results are analyzed,which include right angle deviation,contact liquid,curvature,and focusing accuracy. The study results show that focusing accuracy is the most important factor of influence for measurement,consists of contact liquid wettability,sample shape,and effective width of light transmission. In addition,the refractive index measurement is less affected by angle deviation of sample and the refractive index deviation of contact liquid. On the basis of the experimental data analysis,it is possible to relax the deviation of right angle of the sample to 1' or 2'.展开更多
The electronic structures,chemical bonding,elastic and optical properties of the novel hP24 phase WB3 were investigated by using density-functional theory(DFT) within generalized gradient approximation(GGA).The calcul...The electronic structures,chemical bonding,elastic and optical properties of the novel hP24 phase WB3 were investigated by using density-functional theory(DFT) within generalized gradient approximation(GGA).The calculated energy band structures show that the hP24 phase WB3 is metallic material.The density of state(DOS) and the partial density of state(PDOS) calculations show that the DOS near the Fermi level is mainly from the W 5d and B 2p states.Population analysis suggests that the chemical bonding in hP24-WB3 has predominantly covalent characteristics with mixed covalent-ionic characteristics.Basic physical properties,such as lattice constant,bulk modulus,shear modulus and elastic constants Cij were calculated.The elastic modulus E and Poisson ratio υ were also predicted.The results show that hP24-WB3 phase is mechanically stable and behaves in a brittle manner.Detailed analysis of all optical functions reveals that WB3 is a better dielectric material,and reflectivity spectra show that WB3 can be promised as good coating material in the energy regions of 8.5-11.4 eV and 14.5-15.5 eV.展开更多
In order to obtain high efficiency of organic light-emitting diodes and organic solar cells,a series of DPP-based four-coordinate organoboron compounds have been designed for photoelectric functional materials.The eff...In order to obtain high efficiency of organic light-emitting diodes and organic solar cells,a series of DPP-based four-coordinate organoboron compounds have been designed for photoelectric functional materials.The effects of electron-donating and-withdrawing substituent on the electronic and optical properties have been investigated by using density functional theory(DFT)and time-dependent DFT(TD-DFT)approaches systematically.It turned out that electron-donating and-withdrawing groups can tune effectively the frontier molecular orbital(FMO)energy level,energy gap,and absorption and fluorescence spectra.The introduction of electron-withdrawing groups for the parent molecule HBDPP(2,5-bis(diphenylboryl)-3,6-bis(pyridin-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione)favors the decrease for the FMO energy(E_(LUMO)and E_(HOMO)),HOMO-LUMO gaps(E_(g)),and the downhill energetic driving force(ΔEL-L),while the electron-donating groups can increase E_(LUMO),E_(HOMO),E_(g),andΔEL-L compared with that of HBDPP,respectively.The absorption and fluorescence spectra of the electron-withdrawing substituted derivatives exhibit bathochromic shifts,while the absorption and fluorescence spectra of the electrondonating substituted derivatives show hypsochromic shifts compared with the parent molecule HBDPP,respectively.Furthermore,the stronger the electron-withdrawing/donating ability of group is,the more significant the effect in the optoelectronic properties.展开更多
The third-order nonlinear optical(NLO)materials with stimuli-responsive properties have received extraordinary attention due to their controllable photophysical properties.In this work,two attractive metal complexes t...The third-order nonlinear optical(NLO)materials with stimuli-responsive properties have received extraordinary attention due to their controllable photophysical properties.In this work,two attractive metal complexes third-order NLO switches,which are far superior to congeneric optical switches in terms of their performance conversion,versatility,and fast response,were successfully designed and synthesized.The test of their third-order NLO properties proves that the metal complexes exhibit reverse saturable absorption and self-defocusing refraction.After light irradiation,the third-order NLO behavior turns quickly into self-focusing refraction.The relation between the molecular structures and the third-order NLO properties was investigated via1H nuclear magnetic resonance and ultraviolet-visible absorption.The results show that the metal ions have a significant influence on the NLO behavior and reveal the origin of third-order NLO properties via Z-scan determinations,pump-probe technology,and density functional theory calculations.These metal complexes can be used as third-order NLO switches with excellent fatigue resistance and broaden the application range of third-order NLO materials with adjustable performances.展开更多
Based on the density functional theory (DFT), the electronic structures and optical properties of Mg2Pb are calculated by using the local density approximation (LDA) and plane wave pseudo-potential method. The cal...Based on the density functional theory (DFT), the electronic structures and optical properties of Mg2Pb are calculated by using the local density approximation (LDA) and plane wave pseudo-potential method. The calculation results show that the indirect band gap width of Mg2Pb is 0.02796 eV. The optical properties of MgzPb have isotropic characteristics, the static dielectric function of Mg2Pb is ε1(0) = 10.33 and the refractive index is n0 = 3.5075. The maximum absorption coefficient is 4.8060×10^5 cm-1. The absorption in the photon energy range of 25-40 eV approaches to zero, shows the optical colorless and transparent behaviors.展开更多
This article describes in detail a technique for model!ng cavity optomechanical field sensors. A magnetic or electric field induces a spatially varying stress across the sensor, which then induces a force on mechanica...This article describes in detail a technique for model!ng cavity optomechanical field sensors. A magnetic or electric field induces a spatially varying stress across the sensor, which then induces a force on mechanical eigenmodes of the system. The force on each oscillator can then be determined from an overlap integral between magnetostrictive stress and the corresponding eigenmode, with the optomechanical coupling strength determining the ultimate resolution with which this force can be detected. Furthermore, an optomechanical magnetic field sensor is compared to other magnetic field sensors in terms of sensitivity and potential for miniaturization. It is shown that an optomechanical sensor can potentially outperform state-of-the-art magnetometers of similar size, in particular other sensors based on a magnetostrictive mechanism.展开更多
A planes waves pseudo-potential calculations are performed for the SrMO4 (M=Mo and W) compound in order to investigate the structural, electronic, elastic and optical properties. The calculated lattice constants are...A planes waves pseudo-potential calculations are performed for the SrMO4 (M=Mo and W) compound in order to investigate the structural, electronic, elastic and optical properties. The calculated lattice constants are in good agreement with experiment ones. The electronic structures show that SrMO4 has a direct band gap situated at F point. The calculated elastic constants indicate that both structures are mechanically stable. The bulk modulus, shear modulus, Young's modulus and Poisson ratio are investigated from the elastic constants, in the same time the anisotropy of the elastic properties is discussed. The imaginary part of the dielectric functions is calculated and the contributions of various transitions peaks are analyzed. Furthermore, the other optical properties such as absorption coefficient I(w), optical reflectivity R(w), energy-loss spectrum L(w), and the refractive index n(w) have been investigated.展开更多
基金Supported by Singapore-China Joint R&D Project (No. 003/101/04)
文摘Based on the correlation between certain properties of liquid and the properties of the corresponding liquid drop formed under given conditions, a liquid drop measuring device is utilized to monitor the drop formation process of the liquid sample with photoelectric measuring methods. The mechanical and optical characteristic of the liquid is explored with the optical fibers from the internal of the liquid drop during its formation. The drop head capacitor is utilized to monitor the growth process of the liquid drop to gain the drop volume information related to the physical property of liquid. The unique liquid drop trace containing the integrated properties of liquid is generated, and it is proved by experiment that for different liquids their liquid drop traces are different. The analysis on liquid properties and discrimination between different liquids can be proceeded with the liquid drop trace obtained by the liquid drop measuring device.
基金the Innovation Project of Guangxi Graduate Education Foundation (No.2007106020809M70).
文摘Temperature sensitivity is greatly improved by taking the following three measures: proper long-period fiber grating (LPFG) whose strain coefficient of the core is larger than that of the cladding is employed, the LPFG is coated with a thin film of the material whose refractive index decreases with the temperature, and the sensor is encapsulated by metal material whose thermal expansion coefficient is large. By computer simulation, a measured temperature coefficient of 0.2375 nm/℃ and a temperature resolution less than 0.1 ℃ are obtained.
文摘As an important optical constant of optical properties for spectacle lens,the refractive index measurement is studied using V prism refractometer. In the experiment,according to various factors inducing measurement error,the experimental results are analyzed,which include right angle deviation,contact liquid,curvature,and focusing accuracy. The study results show that focusing accuracy is the most important factor of influence for measurement,consists of contact liquid wettability,sample shape,and effective width of light transmission. In addition,the refractive index measurement is less affected by angle deviation of sample and the refractive index deviation of contact liquid. On the basis of the experimental data analysis,it is possible to relax the deviation of right angle of the sample to 1' or 2'.
基金Project(11271121)supported by the National Natural Science Foundation of ChinaProject(11JJ2002)supported by the Natural Science Foundation of Hunan Province,China+1 种基金Project(11K038)supported by Key Laboratory of Computational and Stochastic Mathematics of Ministry of Education of ChinaProject(2013GK3130)supported by the Scientific and Technological Plan of Hunan Province,China
文摘The electronic structures,chemical bonding,elastic and optical properties of the novel hP24 phase WB3 were investigated by using density-functional theory(DFT) within generalized gradient approximation(GGA).The calculated energy band structures show that the hP24 phase WB3 is metallic material.The density of state(DOS) and the partial density of state(PDOS) calculations show that the DOS near the Fermi level is mainly from the W 5d and B 2p states.Population analysis suggests that the chemical bonding in hP24-WB3 has predominantly covalent characteristics with mixed covalent-ionic characteristics.Basic physical properties,such as lattice constant,bulk modulus,shear modulus and elastic constants Cij were calculated.The elastic modulus E and Poisson ratio υ were also predicted.The results show that hP24-WB3 phase is mechanically stable and behaves in a brittle manner.Detailed analysis of all optical functions reveals that WB3 is a better dielectric material,and reflectivity spectra show that WB3 can be promised as good coating material in the energy regions of 8.5-11.4 eV and 14.5-15.5 eV.
基金the National Natural Science Foundation of China(21563002)the Natural Science Foundation of Inner Mongolia Autonomous Region(2021LHMS02001)the Research Program of Sciences at Universities of Inner Mongolia Autonomous Region(NJZY21175)
文摘In order to obtain high efficiency of organic light-emitting diodes and organic solar cells,a series of DPP-based four-coordinate organoboron compounds have been designed for photoelectric functional materials.The effects of electron-donating and-withdrawing substituent on the electronic and optical properties have been investigated by using density functional theory(DFT)and time-dependent DFT(TD-DFT)approaches systematically.It turned out that electron-donating and-withdrawing groups can tune effectively the frontier molecular orbital(FMO)energy level,energy gap,and absorption and fluorescence spectra.The introduction of electron-withdrawing groups for the parent molecule HBDPP(2,5-bis(diphenylboryl)-3,6-bis(pyridin-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione)favors the decrease for the FMO energy(E_(LUMO)and E_(HOMO)),HOMO-LUMO gaps(E_(g)),and the downhill energetic driving force(ΔEL-L),while the electron-donating groups can increase E_(LUMO),E_(HOMO),E_(g),andΔEL-L compared with that of HBDPP,respectively.The absorption and fluorescence spectra of the electron-withdrawing substituted derivatives exhibit bathochromic shifts,while the absorption and fluorescence spectra of the electrondonating substituted derivatives show hypsochromic shifts compared with the parent molecule HBDPP,respectively.Furthermore,the stronger the electron-withdrawing/donating ability of group is,the more significant the effect in the optoelectronic properties.
基金the National Natural Science Foundation of China(21671174 and U1904172)the Zhongyuan Thousand Talents Project,the Natural Science Foundation of Henan Province(182300410008)the Open Foundation of Guangxi Key Laboratory of Processing for Nonferrous Metals and Featured Materials,Guangxi University(2019GXYSOF12).
文摘The third-order nonlinear optical(NLO)materials with stimuli-responsive properties have received extraordinary attention due to their controllable photophysical properties.In this work,two attractive metal complexes third-order NLO switches,which are far superior to congeneric optical switches in terms of their performance conversion,versatility,and fast response,were successfully designed and synthesized.The test of their third-order NLO properties proves that the metal complexes exhibit reverse saturable absorption and self-defocusing refraction.After light irradiation,the third-order NLO behavior turns quickly into self-focusing refraction.The relation between the molecular structures and the third-order NLO properties was investigated via1H nuclear magnetic resonance and ultraviolet-visible absorption.The results show that the metal ions have a significant influence on the NLO behavior and reveal the origin of third-order NLO properties via Z-scan determinations,pump-probe technology,and density functional theory calculations.These metal complexes can be used as third-order NLO switches with excellent fatigue resistance and broaden the application range of third-order NLO materials with adjustable performances.
基金supported by the National Natural Science Foundation of China(Grant No.51201079)the Scientific Research Foundation for Introduced Talents of KMUST(Grant No.KKSY201251033)the Scientific Research Fund of Department of Education of Yunnan Province(Grant No.2012Z099)
文摘Based on the density functional theory (DFT), the electronic structures and optical properties of Mg2Pb are calculated by using the local density approximation (LDA) and plane wave pseudo-potential method. The calculation results show that the indirect band gap width of Mg2Pb is 0.02796 eV. The optical properties of MgzPb have isotropic characteristics, the static dielectric function of Mg2Pb is ε1(0) = 10.33 and the refractive index is n0 = 3.5075. The maximum absorption coefficient is 4.8060×10^5 cm-1. The absorption in the photon energy range of 25-40 eV approaches to zero, shows the optical colorless and transparent behaviors.
文摘This article describes in detail a technique for model!ng cavity optomechanical field sensors. A magnetic or electric field induces a spatially varying stress across the sensor, which then induces a force on mechanical eigenmodes of the system. The force on each oscillator can then be determined from an overlap integral between magnetostrictive stress and the corresponding eigenmode, with the optomechanical coupling strength determining the ultimate resolution with which this force can be detected. Furthermore, an optomechanical magnetic field sensor is compared to other magnetic field sensors in terms of sensitivity and potential for miniaturization. It is shown that an optomechanical sensor can potentially outperform state-of-the-art magnetometers of similar size, in particular other sensors based on a magnetostrictive mechanism.
文摘A planes waves pseudo-potential calculations are performed for the SrMO4 (M=Mo and W) compound in order to investigate the structural, electronic, elastic and optical properties. The calculated lattice constants are in good agreement with experiment ones. The electronic structures show that SrMO4 has a direct band gap situated at F point. The calculated elastic constants indicate that both structures are mechanically stable. The bulk modulus, shear modulus, Young's modulus and Poisson ratio are investigated from the elastic constants, in the same time the anisotropy of the elastic properties is discussed. The imaginary part of the dielectric functions is calculated and the contributions of various transitions peaks are analyzed. Furthermore, the other optical properties such as absorption coefficient I(w), optical reflectivity R(w), energy-loss spectrum L(w), and the refractive index n(w) have been investigated.