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天然和修饰环糊精的不对称光化学 被引量:4
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作者 童林荟 鲁润华 井上佳久 《化学进展》 SCIE CAS CSCD 北大核心 2006年第5期533-541,共9页
用修饰的α-,β-,γ-环糊精(CDs)的包结增感作用研究(Z)-环辛烯(1Z)向手性(E)-异构体(1E)的超分子对映差向光异构反应。建立定量圆二色(CD)和差圆二色(DCD)公式,研究修饰α-,β-,γ-环糊精衍生物与1Z包结反应的构象、化学量和稳定常数... 用修饰的α-,β-,γ-环糊精(CDs)的包结增感作用研究(Z)-环辛烯(1Z)向手性(E)-异构体(1E)的超分子对映差向光异构反应。建立定量圆二色(CD)和差圆二色(DCD)公式,研究修饰α-,β-,γ-环糊精衍生物与1Z包结反应的构象、化学量和稳定常数。实验发现结合诱导的CD光谱变化是温度和修饰环糊精浓度的临界函数。同时发现光稳态E/Z随照射时间增长而增加最后达到光稳定状态,但明显依赖于增感剂结构和溶液中甲醇含量,它与环糊精手性空腔被客体1Z占有率有直接关系。考查含o-,m-,p-羧酸甲酯基团的苯甲酸β-环糊精酯衍生物的光增感和对映差向能力,更好地认识到在CDs空腔内的有效光能转换是怎样发生的。用邻苯二甲酸β-环糊精酯的对映体过剩(ee)从2.9%增加到24%。有趣的是产物的ee值与取代基常数(Hammett,σ)间没有明显的关系,却与某些苯甲酸-βCD酯的主体占有率有直接关系,即是通过分析在不同甲醇含量的水溶液中被一些-βCD衍生物增感的对映差向光异构反应中的ee,得出被底物1Z占有主体空腔的百分率。 展开更多
关键词 修饰环糊精 超分子化学 不对称合成 对映差向异构反应 作用
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沥青对工人皮肤的损伤
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作者 朱国平 《职业与健康》 CAS 1987年第6期7-7,共1页
沥青是一种很重要的工业原料,主要来源蒸溜石油及煤焦油的付产品(釜底的残渣),所以就有石油沥青和煤焦油沥青的区别。石油沥青在普通温度下成固体形态,呈黑色或黑褐色而有光彩。煤焦油沥青在普通温度下成半固体形态,黑色,有特殊的气味,... 沥青是一种很重要的工业原料,主要来源蒸溜石油及煤焦油的付产品(釜底的残渣),所以就有石油沥青和煤焦油沥青的区别。石油沥青在普通温度下成固体形态,呈黑色或黑褐色而有光彩。煤焦油沥青在普通温度下成半固体形态,黑色,有特殊的气味,俗称为柏油。 展开更多
关键词 沥青 皮肤损伤 光感作用 工人 工资劳动者
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沥青对眼部的损害
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作者 陶华贵 周晓平 《职业卫生与应急救援》 1994年第2期41-41,共1页
沥青对眼部的损害芜湖市第二人民医院眼科陶华贵,周晓平沥青为建筑、铁道、炼钢、修路等行业中常用的原料,在经济建设中应用广泛。劳动部曾多次颁布有关“防止沥青中毒的办法”,对保障劳动人民的安全和健康起了重大作用。本文报导沥... 沥青对眼部的损害芜湖市第二人民医院眼科陶华贵,周晓平沥青为建筑、铁道、炼钢、修路等行业中常用的原料,在经济建设中应用广泛。劳动部曾多次颁布有关“防止沥青中毒的办法”,对保障劳动人民的安全和健康起了重大作用。本文报导沥青引起的眼损害18例。临床资料1、... 展开更多
关键词 沥青中毒 继发性青 职业性皮肤病 职业中毒 调查分析 人民卫生出版社 刺激症状 光感作用 职业病 内科学
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Varietal differences in photosynthetic characters and chlorophyll fluorescence induction kinetics parameters among intergeneric progeny derived from Oryza×Sorghum, its parents, and hybrid rice 被引量:2
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作者 KatsuyoshiShimizu 唐建军 陈欣 《Journal of Zhejiang University Science》 CSCD 2002年第1期113-117,共5页
A comparative study on the photosynthetic parameters among intergeneric progenies derived from \%Oryza sativa\% L.×\%Sorghum vulgare\% L., its maternal parent Gui 630 and commercial 3\|line hybrid rice Shanyou 63... A comparative study on the photosynthetic parameters among intergeneric progenies derived from \%Oryza sativa\% L.×\%Sorghum vulgare\% L., its maternal parent Gui 630 and commercial 3\|line hybrid rice Shanyou 63 in pot experiment in greenhouse was conducted. The morphological and photosynthetic characters of canopy leaves and chlorophyll fluorescence kinetic parameters including \%F\%\-v/\%F\%\-m, \%F\%\-v/\%F\%\-0, photochemical quenching coefficient and non\|photochemical coefficient of canopy leaves of 3 varieties were measured. The results showed the progeny, Yuanyou 1, derived from an intergeneric cross of rice and sorghum possesses better canopy spatial architecture with thicker, heavier and bigger canopy leaf than its maternal parent Gui 630. Higher photosynthetic rate due to higher chlorophyll content, higher primary energy transformation efficiency, potential of PSII and non\|photochemical quenching coefficient (\%q\%\-E) were also measured in Yuanyou 1. These explain partly why the intergeneric progeny has higher biomass production, and better tolerance to adverse conditions and higher field yields even under stress conditions. 展开更多
关键词 intergeneric hybrid PHOTOSYNTHESIS chlorophyll fluorescence kinetics non\|photochemical quenching
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FBS Effect and Temperature Dependence in Trench-Assisted Multimode Fiber
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作者 ZHANG Zelin LU Yuangang +2 位作者 XIE Youwen HUANG Jian ZHOU Lang 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2020年第S01期95-101,共7页
We propose the trench-assisted multimode fiber(TA-OM4)as a novel sensing fiber in forward Brillouin scattering(FBS)-based temperature sensor,due to its higher temperature sensitivity,better bending resistance and lowe... We propose the trench-assisted multimode fiber(TA-OM4)as a novel sensing fiber in forward Brillouin scattering(FBS)-based temperature sensor,due to its higher temperature sensitivity,better bending resistance and lower propagation loss,compared with the single mode fiber(SMF)and other sensing fibers.The FBS effect and acousto-optic interaction in TA-OM4 are the first time to be demonstrated and characterized at 1550 nm theoretically and experimentally.A 2.0 km long TA-OM4 is put into an oven to measure its temperature sensitivity,which can reach up to 80.3 kHz/℃,exceeding 53%of SMF(52.4 kHz/℃).The simulated and experimental results verify that the TA-OM4 may be a good candidate as the sensing fiber for the FBS-based temperature sensor. 展开更多
关键词 forward Brillouin scattering acousto-optic interaction optic-fiber sensor temperature sensitivity multimode fiber
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VIC Effect and Phase-Dependent Optical Properties of Five-Level K-Type Atoms Interacting with Coherent Laser Fields
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作者 JIA Wen-Zhi WANG Shun-Jin 《Communications in Theoretical Physics》 SCIE CAS CSCD 2008年第9期741-748,共8页
Due to interaction with the vacuum of the radiation field,a K-type atomic system with near-degenerateexcited and ground levels,which is driven by two strong coherent fields and two weak probe fields,has additional coh... Due to interaction with the vacuum of the radiation field,a K-type atomic system with near-degenerateexcited and ground levels,which is driven by two strong coherent fields and two weak probe fields,has additional coherenceterms—the vacuum-induced coherence (VIC) terms.In this paper,we find that,if the interference is optimized,thetwo-photon absorption properties of this atom system can be significantly modified and electromagnetically-inducedtransparency (EIT) is dependent on this interference.Furthermore,we find that in all the cases the coherence can suppressor enhance the partial two-photon transparency,while the complete transparency window is still strictly preserved,whichmeans that it cannot be affected by the VIC.Another important result is the finding of the crucial role played by therelative phase between the probe and coupling fields:the relative height of absorption peaks can be modulated by therelative phase.The physical interpretation of the phenomena has been given. 展开更多
关键词 vacuum-induced coherence electromagnetically-induced transparency phase-dependent opticalpro perties
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Effect of Rust Disease on Photosynthetic Rate of Wheat Plant
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作者 Sevda Abdulbagiyeva Atif Zamanov +1 位作者 Javanshir Talai Tofig Allahverdiyev 《Journal of Agricultural Science and Technology(B)》 2015年第7期486-490,共5页
The purpose of this research was to study the influence of rust diseases on photosynthetic rate of the created local varieties and introduced variety samples of wheat. Experiment was carried out with two variants-cont... The purpose of this research was to study the influence of rust diseases on photosynthetic rate of the created local varieties and introduced variety samples of wheat. Experiment was carried out with two variants-control and 25% Tilt treatment. The 25% solution of Tilt was used to prevent disease infection. The photosynthetic rate was measured by T-type URAS-2 infrared gas analyzer (made' in Germany). Disease infection rate was determined based on the Cobby balling scale. Ontogenetic and daily rate of photosynthesis by effect of the disease were decreased. The amount of assimilated CO2 during the day and vegetation period linearly depends on the disease infection degree. At the same time, the activation of non-infected parts' photosynthetic rate of some varieties was observed. The difference reaches up to 87% between the variants as a result of the rapid aging of photosynthesis apparatus. 展开更多
关键词 Wheat plant BREEDING PHOTOSYNTHESIS productivity.
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