Theoretical Model Calculation for d+~8Li Reaction

Based on the theoretical models for light nuclei, the calculations of reaction cross sections and the angular distributions for d ＋^8Li reaction are performed. Since all of the particle emissions are from the compound nucleus to the discrete levels, the angular momentum coupling effect in pre-equilibrium mechanism is taken into account. The three- body break-up process and the recoil effect are involved. The theoretical calculated results are compared to existing experimental data.

Synthesis and Characterization of Oxy-Vanadium （Ⅳ） Complex of 4-（2, 4-dihydroxybenzaldimine） Antipyrine

The reaction of VCl3 with 4-（2, 4-dihydroxybenzaldimine） antipyrine （LH） in a l ： 1 molar ratio results in formation of the general complex of [VOL（CI）OH]. The nature of bonding and stereochemistry of the complex was deduced from the elemental analysis, IR, UV-Vis, 1H and ^13C NMR spectroscopy. This complex has a coordination number five （square pyramidal） as known for many vanadyl complexes. The formation of the vanadyl ion （VO^2＋） and the mode of bonding of the Schiff base through the oxygen of the pyrazol ring and the nitrogen of the azomethine group to the vanadyl ion were established by IR technique.

DETERMINATION OF EQUILIBRIUM MOISTURE OF SOME CHINESE AND AUSTRALIAN COALS BY PULSE PROTON NMR

The varying temperature pulse proton NMR method was adopted to determine the e-quilibrium moisture content of several Chinese and Australian coals. The pulse proton NMR spec-trometry is sensible to the hydrogen at different physical state which occurs for water when temperature changes through 273 K. The equilibrium water,with some interactions to the coal surface, will not transform from one phase to another while the free water does. The measured results are reasonable comparing to the conventional gravimetric method.

Semi-supervised kernel FCM algorithm for remote sensing image classification

These problems of nonlinearity, fuzziness and few labeled data were rarely considered in traditional remote sensing image classification. A semi-supervised kernel fuzzy C-means （SSKFCM） algorithm is proposed to overcome these disadvantages of remote sensing image classification in this paper. The SSKFCM algorithm is achieved by introducing a kernel method and semi-supervised learning technique into the standard fuzzy C-means （FCM） algorithm. A set of Beijing-1 micro-satellite＇s multispectral images are adopted to be classified by several algorithms, such as FCM, kernel FCM （KFCM）, semi-supervised FCM （SSFCM） and SSKFCM. The classification results are estimated by corresponding indexes. The results indicate that the SSKFCM algorithm significantly improves the classification accuracy of remote sensing images compared with the others.

Fast MR Spectroscopic Imaging Technologies and Data Reconstruction Methods

MRSI plays a more and more important role in clinical application. In this paper,we compare several fast MRSI technologies and data reconstruction methods. For the conventional phase encoding MRSI,the data reconstruction using FFT is simple. But the data acquisition is very time consuming and thus prohibitive in clinical settings. Up to now,the MRSI technologies based on echo-planar, spiral trajectories and sensitivity encoding are the fastest in data acquisition,but their data reconstruction is complex. EPSI reconstruction uses shift of odd and even echoes. Spiral SI uses gridding FFT. SENSE-SI,a new approach to reducing the acquisition time,uses the distinct spatial sensitivities of the individual coil elements to recover the missing encoding information. These improvements in data acquisition and image reconstruction provide a potential value of metabolic imaging as a clinical tool.

Down-shifting luminescence of water soluble NaYF_4:Eu^(3+)@Ag core-shell nanocrystals for fluorescence turn-on detection of glucose

Techniques for detecting glucose are developing at a breathtaking speed because diabetes mellitus can cause many serious complications, such as blindness, high blood pressure heart disease and kidney failure. Herein, water sol- uble NaYF4：Eu^3＋@Ag core-shell nanocrystals for glucose de- tection with lower detection limit have been successfully de- veloped, using NaYF4：Eu^3＋ cores as the energy donors and Ag shells as the efficient quenchers through energy transfer. After immobilization of glucose oxidase （GOx） on the sur- face of NaYF4：Eu^3＋@Ag core-shell nanocrystals, the Ag shells can be decomposed in the presence of glucose, accompanied by down-shifting luminescence recovery. The limit of detec- tion of NaYF4：Eu^3＋@Ag was 0.12 μmol L^-1. Therefore, the NaYF4：Eu^3＋@Ag can be easily extended to the detection of a variety of H2O2-involved analytes.

Investigation of radionuclide～(63)Ni(Ⅱ) sequestration mechanisms on mordenite by batch and EXAFS spectroscopy study

The sorption behavior and microscopic sequestration mechanisms of radionuclide 63Ni（II） on mordenite as a function of aging time, ionic srength, initial 63Ni（II） concentrations, solid content and coexistent electrolyte ions were investigated by the combination of batch and EXAFS techniques. Macroscopic experiment results show that the sorption of 63Ni（II） is dependent on ionic strength at pH〈7, and independent of ionic strength at pH〉7. The sorption percentage of 63Ni（II） on mordenite increases with increasing solid content, while the sorption capacity decreases as solid content increases. The presence of different electrolyte ions can enhance or inhibit the sorption of Ni（II） on mordenite in various degrees. EXAFS analysis results of the sam- ples under three different ionic strengths suggest that the retained 63Ni（II） in these samples exists in an octahedral environment with six water ligands. In the initial period of rapid uptake, the sorption of 63Ni（II） is dominated by the formation of innersphere surface complexes. As aging time increases, 63Ni（II） sequestration behavior tends to be mainly controlled by the formation of Ni phyllosilicate coprecipitates and/or Ni（OH）2（s） precipitates. Results for the second shell fit of the sample prepared at an initial 63Ni（II） concentration of 100 mg/L indicate the possible formation of Ni polynuclear surface complexes. Both the macroscopic sorption data and the molecular level evidence of 63Ni（II） surface speciation at the mordenite/water interfaces should be factored into better predictions of the mobility and bioavailability of 63Ni（II） in environment mediums.

Cloning and Sequence Analysis of a Full-length cDNA Encoding Light-harvesting Complexes of Photosystem II in Phyllostachys edulis

The light-harvesting chlorophyll a/b-protein complex plays an important role in photosynthesis of plants. A full-length cDNA of light-harvesting chlorophyll a/b （cab） gene was cloned from the first strand of Moso （Phyllostachys edulis） cDNA through RT-PCR and RACE methods, named as cabPhEIO （cab gene 10 from Ph. edulis）. The length of cab- PhEIO （GenBank accession number： EU118754） is 1 151 bp, which contains an open reading frame encoding 283 amino acids from 81st to 932nd position. The bioinformatics analysis indicated that the protein encoded by cab-PhElO had a chlorophll a/b binding domain （83rd -247th position）, two protein kinase C-phosphorylation sites, three Nmyristoylation sites and a yia A/B double helix domain.The amino acid sequence of cab-PhElO showed high similarity with the cab genes of Oryza sativa, Zea mays, Hordeum vulgare, and Vitis vinifera, more than 80%, respectively, which indicated that cab-PhElO gene belongs to lhcb5 gene family.