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介孔TiO2薄膜光波导共振传感器对苯并(a)芘的探测灵敏度 被引量:1
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作者 万秀美 王丽 +2 位作者 龚晓庆 逯丹凤 祁志美 《物理化学学报》 SCIE CAS CSCD 北大核心 2017年第12期2523-2531,共9页
采用溶胶-凝胶分子模板法在覆金的玻璃基底上制备了厚度约为295 nm的介孔TiO_2薄膜,再经表面化学修饰形成表面疏水的光波导共振(OWR)传感芯片,用于探测水中苯并(a)芘。利用Kretschmann棱镜耦合结构观测到OWR芯片在可见-近红外波段只有... 采用溶胶-凝胶分子模板法在覆金的玻璃基底上制备了厚度约为295 nm的介孔TiO_2薄膜,再经表面化学修饰形成表面疏水的光波导共振(OWR)传感芯片,用于探测水中苯并(a)芘。利用Kretschmann棱镜耦合结构观测到OWR芯片在可见-近红外波段只有一个共振波谷,基于相位匹配条件确定了该共振波谷对应于二级横磁导模(TM2);进一步利用Fresnel理论并结合Bruggeman介电常数近似方程对实验测得的导模共振波长进行拟合,得出介孔TiO_2薄膜的多孔度约为0.4;利用疏水介孔TiO_2薄膜OWR传感芯片对水中苯并(a)芘小分子进行了原位和离位探测,结果表明离位探测灵敏度比原位探测高2倍多,其最低检测限约为100 nmol·L^(-1);对比实验指出OWR传感芯片的多孔结构和疏水化处理都有助于提高芯片对苯并(a)芘的探测灵敏度。研究表明这种介孔TiO_2薄膜OWR传感芯片具有良好的稳定性,可重复利用。 展开更多
关键词 苯并(A)芘 光波导共振传感器 介孔TiO2薄膜 疏水处理 增敏
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Design of an Optical Water Pollution Sensor Using a Single-Layer Guided-Mode Resonance Filter 被引量:1
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作者 Edward SADER Abdallah SAYYED-AHMAD 《Photonic Sensors》 SCIE EI CAS 2013年第3期224-230,共7页
The optical characteristics of a simple, planar, single layer, dielectric Mg-based guided mode resonance filter (GMRF) were investigated by means of rigorous-coupled wave analysis (RCWA). This filter has great pot... The optical characteristics of a simple, planar, single layer, dielectric Mg-based guided mode resonance filter (GMRF) were investigated by means of rigorous-coupled wave analysis (RCWA). This filter has great potential for real-life applications, especially as bio- and environmental sensors. The structure of the proposed sensor is compact, and all of its layers can be grown in a single process. In this paper, we present results on the design of a water pollution sensor in the violet region of the visible spectrum. The spectral and angular sensitivities of the sensor for both the transverse electric (TE) and transverse magnetic (TM) polarization modes were estimated and compared for various regions in the violet spectrum. A spectral response characterized with a narrow bandwidth and low reflection side bands was realized by carrying out extensive parameter search and optimization. Optimal spectral and angular sensitivities were found for the sensor with a grating thickness of 100nm in the TM polarized mode where we found them to be 100nm and 40 degrees, per index refraction unit, respectively. 展开更多
关键词 Diffractive optics guided waves FILTERS SENSORS spectral sensitivity angular sensitivity
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