光温诱导饲料甜菜当年抽薹开花试验研究

利用人工智能气候箱,对饲料甜菜JZSL-7进行了光温诱导处理试验,结果表明:在温度4～6℃,相对湿度60%,光照5000 lx,连续光照条件下,在饲料甜菜两对真叶期,随着诱导时间的增加,饲料甜菜JZSL-7抽薹率和开花率均提早、提高,光温诱导40～120 d,饲料甜菜JZSL-7可以当年抽薹开花结实,从播种到种子成熟至少需要254 d,比通常情况下缩短100 d以上。

甜菜异地光温诱导效应初步研究

利用光因子诱导甜菜早抽薹结实,将在新疆玛纳斯夏播培育的小母根,当年移至海南栽植,夜间补充光照,迫使自然群体植株分离出正常植株(开花结实)、顽固植株(不抽薹)、无效植株(抽薹不形成花蕾)。其中正常植株抽薹开花率不同年份有所不同,抽薹率最高达76.36%,开花率达73.8%。正常植株比在原地新疆玛纳斯采种可早收获种子110余天。将收获的种子,在玛纳斯第二年3月春播鉴定,植株生长整齐,无抽薹株发生。将顽固植株移至玛纳斯正常栽植,结果继续分离出顽固植株、正常植株。本项研究,旨在通过补充光照,促使甜菜母根顶芽及缩短茎产生新的变异,即将从有复杂遗传背景的甜菜群体,分离出多态性个体,为开拓育种新途径、缩短育种周期、提高育种效率提供科学依据。

甜菜当年抽薹开花诱导技术在育种上的应用

对不同类型甜菜品系及不同苗龄幼苗光温诱导敏感性进行了研究。结果表明:不同类型甜菜品系、不同苗龄的幼苗均表现出随着光温诱导时间的延长,其抽薹率、开花率和结实率均有提高;但不同类型品系之间对光温诱导的敏感性存在着较明显的差异,同一品系幼苗的不同苗龄间也存在着一定的差异。饲料甜菜品系HSLTC在诱导80d以前各期的抽薹率明显高于糖甜菜品系DP10,但其开花率和结实率在各诱导时期均明显低于DP10。随着诱导时间的延长,各品系的抽薹率、开花率和结实率有所递增,糖甜菜幼苗的光温诱导时间以110d左右为宜,饲料甜菜应不少于130d。

New Insights into Folding Kinetics of α,ω Dye-Functionalized Poly(N-isopropylacrylamide)

Two narrowly-distributed poly(N-isopropylacrylamide)(PNIPAM) samples were prepared via atom transfer radical polymerization (ATRP) with a novel dansyl functionalized initiator. The other end of the PNIPAM was functionalized by dabcyl group via click reaction. From the static fluorescence measurements, the fluorescence intensity of dansyl group and energy transfer efficiency between dansyl and dabcyl groups increased when the temperature increased from 36 °C to 45 °C, indicating that the microenvironment surrounding dansyl became hydrophobic and the distance between dansyl and dabcyl decreased. The kinetics of the conformational change of the dye-labeled PNIPAM was studied by a home-made laser-induced temperature jump device with fluorescent measurement. Our results revealed that the characteristic transition time was 3.8 and 5.8 ms for PNIPAM with degrees of polymerization of 85 and 142, respectively, indicating that the characteristic transition time was related to the chain length. Besides, characteristic transition time for the change of the energy transfer efficiency was 2.9 ms for PNIPAM with the degree of polymerization of 85, suggesting that the energy transfer efficiency change was faster than the fluorescence intensity change of dansyl group.

Transitional Process of Ploy（N-isopropylacrylamide） in Deuterated Solution

The fast phase-transitional process of ploy（N-isopropylacrylamide） （PNIPAM） in deuterated solution was studied by laser induced temperature jump technique combined with time-resolved mid-infrared absorbance difference spectroscopy on nanosecond level. The multi-peaks of amide I＇band of PNIPAM among the energy range of 1565-1700 cm^-1 was experimentally resolved to three groups （i, ii, iii） for the first time, while the distinct threestage procedure in the phase transitional process of long-chain PNIPAM was observed firstly too. Furthermore, proper assignments were also made for the three group peaks in amide I＇band and the three steps in the kinetics process of long-chain PNIPAM.

Effect of the interfacial electric field on the HER on Pt(111)modified with iron adatoms in alkaline media

The study of the hydrogen evolution reaction(HER)aimed to reach a deeper understanding of the parameters that control the rate of this reaction is of great importance given the technical relevance of hydrogen production as an energy vector in the so-called hydrogen economy.In previous works,laser-induced temperature jump(LITJ)experiments on Pt(111)modified with Ni(OH)_(2)in alkaline media have revealed the importance of the interfacial electric field in the rate of the HER.It was hypothesised that small amounts of Ni(OH)_(2)cause a decrease of the electric field because of a negative shift of the pzfc toward the onset of the hydrogen evolution.In this work,to test the validity of this hypothesis,the study has been extended to Pt(111)surfaces modified with Fe(OH)_(2).The modified surfaces have been studied voltammetrically,and the voltammetric charges have been analysed.The voltammograms show a peak in the hydrogen evolution region that suggest the transformation in the adlayer from Fe(II)to Fe(0).In agreement with the coulometric analysis,the voltammetric features in the OH adsorption region would be related with the oxidation to the+3 valence state.The results obtained with LITJ method reflect the existence of a strong interaction of the Fe oxophilic species with the water molecules,shifting the potential of maximum entropy away from the onset of the HER.Hence,the most catalytic surface is the one with the lowest Fe coverage.

Effect of Sample Temperature on Radiation Characteristics of Nanosecond Laser-Induced Soil Plasma

An Nd:YAG single pulse nanosecond laser of 532 nm wavelength with an 8 ns pulse width was projected on the soil samples collected from the campus of Bengbu College under 1 standard atmospheric pressure. Laser-induced breakdown spectroscopy at different sample temperatures was achieved. The intensity and signal-to-noise ratio (SNR) changes of different characteristic spectral lines could be analyzed when the sample temperature changes.The evolution of plasma electron temperature and electron density with the sample temperature was analyzed through Boltzmann oblique line method and Stark broadening method.The cause of the radiation enhancement of laser-induced metal plasma was discussed. Experimental results demonstrated that the spectral intensity, SNR, the electron temperature and electron density of plasma are positively related to the sample temperature, and reach saturation at 100℃.

Effects of Intermolecular Interactions on Luminescence Property in Organic Molecules

The organic solid-state lightemitting materials have attracted more and more attention owing to their promising applications in displays,lasers and optical communications.In contrast to isolated molecule,there are various weak intermolecular interactions in organic solids that sometimes have a large impact on the excited-state properties and energy dissipation pathways,resulting in strong fluorescence/phosphorescence.It is increasingly necessary to reveal the luminescence mechanism of organic solids.Here,we briefly review how intermolecular interactions induce strong normal fluorescence,thermally activate delayed fluorescence and room-temperature phosphorescence in organic solids by examining changes in geometry,electronic structures,electron-vibration coupling and energy dissipation dynamics of the excited states from isolated to aggregated molecules.We hope that the review will contribute to an in-depth understanding of the excited state properties of organic solids and to the design of excellent solid-state light-emitting materials.

Crystallization-induced phosphorescence of benzils at room temperature

Efficient room temperature phosphorescence (RTP) is rarely observed in pure organic luminogens. However, we have newly observed that benzil and its derivatives are nonluminescent in solvents and thin layer chromatography (TLC) plates, but become highly phosphorescent in crystal state at room temperature, exhibiting typical crystallization-induced phosphorescence (CIP) characteristics. The CIP phenomenon is ascribed to the restriction of intramolecular rotations in crystals owing to effective intermolecular interactions. Such intermolecular interactions greatly rigidify the molecular conformation and significantly decrease the nonradiative deactivation channels of the triplet excitons, thus giving boosted phosphorescent emission at room temperature.

Photoinduced Room-Temperature Phosphorescence of Triphenylamine-Phenothiazine Derivative-Doped Polymers

Photo-responsive room-temperature phosphorescent(RTP)materials have garnered significant interest due to the advantages of rapid response,spatiotemporal control,and contactless precision manipulation.However,the development of such materials remains in its infancy,underscoring the importance of exploiting novel and efficient light-responsive RTP molecules.In this work,three phenothiazine derivatives of TPA-PTZ,TPA-2PTZ,and TPA-3PTZ were successfully synthesized via the Buchwald-Hartwig C—N coupling reaction.By embedding these molecules as RTP guests into polymethyl methacrylate(PMMA)matrix,photo-induced RTP properties were realized.Upon sustained UV irradiation,there was an enhancement of 19 times in the quantum yield to reach a value of 5.68%.Remarkably,these materials exhibit superior alongside robust light and thermal stability,maintaining high phosphorescence intensity even after prolonged UV exposure(irradiation for>200 s by a 365 nm UV lamp with the power of 500μW·cm-2)or at higher temperature up to 75℃.The outstanding properties of these photo-induced RTP materials make them promising candidates for applications in information encryption,anti-counterfeiting,and advanced optical materials.