A Multi-channel Oceanographic Fluorescence Lidar(MOFL), with a UV excitation at 355 nm and multiple receiving channels at typical wavelengths of fluorescence from oil spills and chlorophyll-a(Chl-a), has been develope...A Multi-channel Oceanographic Fluorescence Lidar(MOFL), with a UV excitation at 355 nm and multiple receiving channels at typical wavelengths of fluorescence from oil spills and chlorophyll-a(Chl-a), has been developed using the Laser- induced Fluorescence(LIF) technique. The sketch of the MOFL system equipped with a compact multi-channel photomultiplier tube(MPMT) is introduced in the paper. The methods of differentiating the oil fluorescence from the background water fluorescence and evaluating the Chl-a concentration are described. Two field experiments were carried out to investigate the field performance of the system, i.e., an experiment in coastal areas for oil pollution detection and an experiment over the Yellow Sea for Chl-a monitoring. In the coastal experiment, several oil samples and other fluorescence substances were used to analyze the fluorescence spectral characteristics for oil identification, and to estimate the thickness of oil films at the water surface. The experiment shows that both the spectral shape of fluorescence induced from surface water and the intensity ratio of two channels(I495/I405) are essential to determine oil-spill occurrence. In the airborne experiment, MOFL was applied to measure relative Chl-a concentrations in the upper layer of the ocean. A comparison of relative Chl-a concentration measurements by MOFL and the Moderate Resolution Imaging Spectroradiometer(MODIS) indicates that the two datasets are in good agreement. The results show that the MOFL system is capable of monitoring oil spills and Chl-a in the upper layer of ocean water.展开更多
The estimation of oil spill coverage is an important part of monitoring of oil spills at sea.The spatial resolution of images collected by airborne hyper-spectral remote sensing limits both the detection of oil spills...The estimation of oil spill coverage is an important part of monitoring of oil spills at sea.The spatial resolution of images collected by airborne hyper-spectral remote sensing limits both the detection of oil spills and the accuracy of estimates of their size.We consider at-sea oil spills with zonal distribution in this paper and improve the traditional independent component analysis algorithm.For each independent component we added two constraint conditions:non-negativity and constant sum.We use priority weighting by higher-order statistics,and then the spectral angle match method to overcome the order nondeterminacy.By these steps,endmembers can be extracted and abundance quantified simultaneously.To examine the coverage of a real oil spill and correct our estimate,a simulation experiment and a real experiment were designed using the algorithm described above.The result indicated that,for the simulation data,the abundance estimation error is 2.52% and minimum root mean square error of the reconstructed image is 0.030 6.We estimated the oil spill rate and area based on eight hyper-spectral remote sensing images collected by an airborne survey of Shandong Changdao in 2011.The total oil spill area was 0.224 km^2,and the oil spill rate was 22.89%.The method we demonstrate in this paper can be used for the automatic monitoring of oil spill coverage rates.It also allows the accurate estimation of the oil spill area.展开更多
In the recent decades oil spills in the aquatic environments are one of the major sources of environmental pollutions, which are steadily growing with the increase in oil consumption. Adsorption is a rapid and cost ef...In the recent decades oil spills in the aquatic environments are one of the major sources of environmental pollutions, which are steadily growing with the increase in oil consumption. Adsorption is a rapid and cost effective process to minimize the environmental impacts of oil spills and cleanup these pollutants. In this work, the crude oil sorption capacity was examined with raw sugarcane bagasse and acetylated sugarcane bagasse. Results show that the acetylated bagasse was significantly more oleophilic than the raw bagasse and acetylation reaction can increase bagasse oil sorption ability by about 90%. The maximum sorption capacities of acetylated bagasse were obtained about 11.3 g and 9.1 g in dry system(crude oil sorption) and oil layer sorption, respectively. The physicochemical characteristics of the sorbents such as composition, water solubility, moisture content and density were measured according to ASTM standard methods. Also Fourier transform infrared spectroscopy(FTIR) of raw and acetylated bagasse was performed to investigate the effect of acetylation on sugarcane bagasse structure.展开更多
The active sites for hydrogenation over Ru/SBA‐15catalysts were identified using in situ Fourier‐transform infrared spectroscopy.The amount of active sites was proportional to the interfacial circumference of the Ru...The active sites for hydrogenation over Ru/SBA‐15catalysts were identified using in situ Fourier‐transform infrared spectroscopy.The amount of active sites was proportional to the interfacial circumference of the Ru particles.In contrast,the rate of hydrogen spillover from Ru to the support was inversely proportional to the size of the Ru metal particles.Consequently,a catalyst with small Ru metal particles has a high rate of hydrogen spillover but a low density of active sites,whereas one with large Ru particles has a low rate of hydrogen spillover but a high density of active sites.The formation of these active sites is probably an intermediate step in hydrogen spillover.展开更多
基金supported by the National High Technology Research and Development Program (2006AA06Z415)the Global Change Research Program of China (2012CB955603)
文摘A Multi-channel Oceanographic Fluorescence Lidar(MOFL), with a UV excitation at 355 nm and multiple receiving channels at typical wavelengths of fluorescence from oil spills and chlorophyll-a(Chl-a), has been developed using the Laser- induced Fluorescence(LIF) technique. The sketch of the MOFL system equipped with a compact multi-channel photomultiplier tube(MPMT) is introduced in the paper. The methods of differentiating the oil fluorescence from the background water fluorescence and evaluating the Chl-a concentration are described. Two field experiments were carried out to investigate the field performance of the system, i.e., an experiment in coastal areas for oil pollution detection and an experiment over the Yellow Sea for Chl-a monitoring. In the coastal experiment, several oil samples and other fluorescence substances were used to analyze the fluorescence spectral characteristics for oil identification, and to estimate the thickness of oil films at the water surface. The experiment shows that both the spectral shape of fluorescence induced from surface water and the intensity ratio of two channels(I495/I405) are essential to determine oil-spill occurrence. In the airborne experiment, MOFL was applied to measure relative Chl-a concentrations in the upper layer of the ocean. A comparison of relative Chl-a concentration measurements by MOFL and the Moderate Resolution Imaging Spectroradiometer(MODIS) indicates that the two datasets are in good agreement. The results show that the MOFL system is capable of monitoring oil spills and Chl-a in the upper layer of ocean water.
基金Supported by the National Scientific Research Fund of China(No.31201133)
文摘The estimation of oil spill coverage is an important part of monitoring of oil spills at sea.The spatial resolution of images collected by airborne hyper-spectral remote sensing limits both the detection of oil spills and the accuracy of estimates of their size.We consider at-sea oil spills with zonal distribution in this paper and improve the traditional independent component analysis algorithm.For each independent component we added two constraint conditions:non-negativity and constant sum.We use priority weighting by higher-order statistics,and then the spectral angle match method to overcome the order nondeterminacy.By these steps,endmembers can be extracted and abundance quantified simultaneously.To examine the coverage of a real oil spill and correct our estimate,a simulation experiment and a real experiment were designed using the algorithm described above.The result indicated that,for the simulation data,the abundance estimation error is 2.52% and minimum root mean square error of the reconstructed image is 0.030 6.We estimated the oil spill rate and area based on eight hyper-spectral remote sensing images collected by an airborne survey of Shandong Changdao in 2011.The total oil spill area was 0.224 km^2,and the oil spill rate was 22.89%.The method we demonstrate in this paper can be used for the automatic monitoring of oil spill coverage rates.It also allows the accurate estimation of the oil spill area.
文摘In the recent decades oil spills in the aquatic environments are one of the major sources of environmental pollutions, which are steadily growing with the increase in oil consumption. Adsorption is a rapid and cost effective process to minimize the environmental impacts of oil spills and cleanup these pollutants. In this work, the crude oil sorption capacity was examined with raw sugarcane bagasse and acetylated sugarcane bagasse. Results show that the acetylated bagasse was significantly more oleophilic than the raw bagasse and acetylation reaction can increase bagasse oil sorption ability by about 90%. The maximum sorption capacities of acetylated bagasse were obtained about 11.3 g and 9.1 g in dry system(crude oil sorption) and oil layer sorption, respectively. The physicochemical characteristics of the sorbents such as composition, water solubility, moisture content and density were measured according to ASTM standard methods. Also Fourier transform infrared spectroscopy(FTIR) of raw and acetylated bagasse was performed to investigate the effect of acetylation on sugarcane bagasse structure.
基金supported by the National Natural Science Foundation of China(21303163)the Natural Science Foundation of Zhejiang Province(LY13B030006,LY17B060006)+1 种基金the Qianjiang Talent Project in Zhejiang Province(QJD1302011)the Scientific Research Fund of Zhejiang Provincial Education Department(Y201328681)~~
文摘The active sites for hydrogenation over Ru/SBA‐15catalysts were identified using in situ Fourier‐transform infrared spectroscopy.The amount of active sites was proportional to the interfacial circumference of the Ru particles.In contrast,the rate of hydrogen spillover from Ru to the support was inversely proportional to the size of the Ru metal particles.Consequently,a catalyst with small Ru metal particles has a high rate of hydrogen spillover but a low density of active sites,whereas one with large Ru particles has a low rate of hydrogen spillover but a high density of active sites.The formation of these active sites is probably an intermediate step in hydrogen spillover.