The aim of this paper is to present the preliminary experimental analysis results carried out on the commercial internal combustion engine set in a CHP （combined heat and power） mode, fueled by renewable hydrogen an...The aim of this paper is to present the preliminary experimental analysis results carried out on the commercial internal combustion engine set in a CHP （combined heat and power） mode, fueled by renewable hydrogen and methane mixtures. The hydrogen is produced by an alkaline electrolyser fed by a 5.8 kWp grid connected PV （photovoltaic） plant. The acceptance test conducted with hydrogen percentages ranging from 0%-10% has been carried out at partial load： 45 kW^l instead of the full power of 60 kWe~. In order to evaluate the CHP energy consumption and environmental performance （NOx and CO）, the analysis was conducted for 240 h, using a portable flue gas analyser and two mass flow meters for hydrogen and methane. Without engine parameters optimization--relative equivalence ratio （2） and spark advance--increasing hydrogen addition rate, a slight enhancement in electrical efficiency occurs. Furthermore, due to the engine control system and lower blends LHV （lower heating value）, the methane consumption decreases disproportionately to the hydrogen amount in the mixture. Finally, referring to standard operating condition, the environmental results show that using enrichment of 10%, running the engine with 18 degrees spark advance and 2 of 1.4, CO and NOx emissions are reduced by 6.3% and 27% respectively.展开更多
The exponential growth of utilizing synthetic organic molecules in optoelectronic applications poses strong demands for rational control over the excited states of the materials. The manipulation of excited states thr...The exponential growth of utilizing synthetic organic molecules in optoelectronic applications poses strong demands for rational control over the excited states of the materials. The manipulation of excited states through molecular design has led to the development of high-performance optoelectronic devices with tunable emission colors, high quantum efficiencies and efficient energy/charge transfer processes. Recently, a significant breakthrough in lifetime tuning of excited states has been made;the purely organic molecules were found to have ultralonglived excited state under ambient conditions with luminescence lifetimes up to 1.35 s, which are several orders of magnitude longer than those of conventional organic fluorophores. Given the conceptual advance in understanding the fundamental behavior of excited state tuning in organic luminescent materials, the investigations of organic ultralong room-temperature phosphorescence(OURTP) should provide new directions for researches and have profound impacts on many different disciplines. Here, we summarized the recent understandings on the excited state tuning, the reported OURTP molecules and their design considerations,the spectacular photophysical performance, and the amazing optoelectronic applications of the newly emerged organic optoelectronic materials that free of heavy metals.展开更多
文摘The aim of this paper is to present the preliminary experimental analysis results carried out on the commercial internal combustion engine set in a CHP （combined heat and power） mode, fueled by renewable hydrogen and methane mixtures. The hydrogen is produced by an alkaline electrolyser fed by a 5.8 kWp grid connected PV （photovoltaic） plant. The acceptance test conducted with hydrogen percentages ranging from 0%-10% has been carried out at partial load： 45 kW^l instead of the full power of 60 kWe~. In order to evaluate the CHP energy consumption and environmental performance （NOx and CO）, the analysis was conducted for 240 h, using a portable flue gas analyser and two mass flow meters for hydrogen and methane. Without engine parameters optimization--relative equivalence ratio （2） and spark advance--increasing hydrogen addition rate, a slight enhancement in electrical efficiency occurs. Furthermore, due to the engine control system and lower blends LHV （lower heating value）, the methane consumption decreases disproportionately to the hydrogen amount in the mixture. Finally, referring to standard operating condition, the environmental results show that using enrichment of 10%, running the engine with 18 degrees spark advance and 2 of 1.4, CO and NOx emissions are reduced by 6.3% and 27% respectively.
基金supported in part by the National Natural Science Foundation of China(21274065,21304049,61204048 and 51173081)The Ministry of Education of China(IRT1148)+1 种基金a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(YX03001)the Qing Lan Project of Jiangsu Province
文摘The exponential growth of utilizing synthetic organic molecules in optoelectronic applications poses strong demands for rational control over the excited states of the materials. The manipulation of excited states through molecular design has led to the development of high-performance optoelectronic devices with tunable emission colors, high quantum efficiencies and efficient energy/charge transfer processes. Recently, a significant breakthrough in lifetime tuning of excited states has been made;the purely organic molecules were found to have ultralonglived excited state under ambient conditions with luminescence lifetimes up to 1.35 s, which are several orders of magnitude longer than those of conventional organic fluorophores. Given the conceptual advance in understanding the fundamental behavior of excited state tuning in organic luminescent materials, the investigations of organic ultralong room-temperature phosphorescence(OURTP) should provide new directions for researches and have profound impacts on many different disciplines. Here, we summarized the recent understandings on the excited state tuning, the reported OURTP molecules and their design considerations,the spectacular photophysical performance, and the amazing optoelectronic applications of the newly emerged organic optoelectronic materials that free of heavy metals.
