This paper introduces a study on modelling surface finish in EDM （Electrical Discharge Machining） of tablet shape punches when using copper as electrode material. In this study, 27 experiments were performed based o...This paper introduces a study on modelling surface finish in EDM （Electrical Discharge Machining） of tablet shape punches when using copper as electrode material. In this study, 27 experiments were performed based on BBD （Box-Behnken Design） and the work-piece material was 9CrSi steel. The input process parameters were the current, the pulse on time, the pulse off time and the voltage. The effects of the input parameters on the surface finish were evaluated by analysing variance. Besides, from the results of the experiments, a regression equation for determining the surface roughness is introduced. Also, the optimum input parameter values were found in order to get the minimum surface roughness.展开更多
Microstructural analysis and fatigue crack propagation behavior of three types of rail steels, was performed. These are premium pearlitic, austenitic manganese （AM） and bainitic rail steels. Rectangular un-notched a...Microstructural analysis and fatigue crack propagation behavior of three types of rail steels, was performed. These are premium pearlitic, austenitic manganese （AM） and bainitic rail steels. Rectangular un-notched and notched test specimens were machined from railheads of each material using electrical discharge machining （EDM） and used for the mechanical properties and fatigue evaluation respectively. Bainitic steel has the highest yield strength, ultimate strength, and strain to failure as compared to both pearlitic and austenitic manganese steels. Fatigue studies showed that the crack speed for the bainitic steel is lower than that for the pearlitie and the AM steels over the entire range of the energy release rate. The bainitic steel exhibits a higher rate of crack deceleration in the second stage, as indicated by the lower slope of the fatigue crack propagation kinetics curve in comparison with the pearlitic and manganese rail steels. This attests to the superior fatigue damage tolerance of the bainitic rail steel in comparison to pearlitic and austenitic manganese rail steels. Microstructural analysis of the three rail steels revealed that bainitic steel has a more intricate structure than AM and pearlitic steels. AM steel shows very few signs of being work hardened or toughened, which usually increases the mechanical properties of the material. As the number of alloying elements increase, the microstructure of the steel becomes more complex, resulting in the increase of mechanical properties and fatigue fracture resistance of bainitic rail steel.展开更多
Here, we report a trap-assisted photomultiplication （PM） phenomenon in solution-processed organic photodetectors （OPDs） using poly（3-hexylthiophene） （P3HT）： indene-C60 bisadduct （ICBA） as the active layer. ...Here, we report a trap-assisted photomultiplication （PM） phenomenon in solution-processed organic photodetectors （OPDs） using poly（3-hexylthiophene） （P3HT）： indene-C60 bisadduct （ICBA） as the active layer. The maximum external quantum efficiency （EQE） is 685% for the device with 2% ICBA doping ratio, which is much higher than that of OPDs with P3HT：ICBA （1：1） as the active layer. The PM phenomenon is attributed to the hole tunneling injection assisted by trapped electron in ICBA near A1 cathode, which can be demonstrated from the EQE spectra and transient photocurrent curves of OPDs with different ICBA doping ratios.展开更多
In-plane heteroatom substitution of graphene is a promising strategy to modify its properties. The ability to dope graphene with electron-donor nitrogen heteroatoms is highly important for modulating electrical proper...In-plane heteroatom substitution of graphene is a promising strategy to modify its properties. The ability to dope graphene with electron-donor nitrogen heteroatoms is highly important for modulating electrical properties of graphene. Here we demonstrate a transfer-free method to directly grow large area quasi free-standing N-doped graphene bilayers on an insulating substrate （Si3N4）. Electron-bombardment heating under nitrogen flux results in simultaneous growth of N-doped graphene and a Si3N4 layer on the SiC surface. The decoupling of N-doped graphene from the substrate and the presence of Si3N4 are identified by X-ray photoemission spectroscopy and low-energy electron diffraction. The substitution of nitrogen atoms in the graphene planes was confirmed using high resolution X-ray photoemission spectroscopy which reveals several atomic configurations for the nitrogen atoms： Graphitic-like, pyridine-like, and pyrrolic- like. Furthermore, we demonstrated for the first time that N-doped graphene could be used to efficiently probe oxygen molecules via nitrogen atom defects.展开更多
文摘This paper introduces a study on modelling surface finish in EDM （Electrical Discharge Machining） of tablet shape punches when using copper as electrode material. In this study, 27 experiments were performed based on BBD （Box-Behnken Design） and the work-piece material was 9CrSi steel. The input process parameters were the current, the pulse on time, the pulse off time and the voltage. The effects of the input parameters on the surface finish were evaluated by analysing variance. Besides, from the results of the experiments, a regression equation for determining the surface roughness is introduced. Also, the optimum input parameter values were found in order to get the minimum surface roughness.
文摘Microstructural analysis and fatigue crack propagation behavior of three types of rail steels, was performed. These are premium pearlitic, austenitic manganese （AM） and bainitic rail steels. Rectangular un-notched and notched test specimens were machined from railheads of each material using electrical discharge machining （EDM） and used for the mechanical properties and fatigue evaluation respectively. Bainitic steel has the highest yield strength, ultimate strength, and strain to failure as compared to both pearlitic and austenitic manganese steels. Fatigue studies showed that the crack speed for the bainitic steel is lower than that for the pearlitie and the AM steels over the entire range of the energy release rate. The bainitic steel exhibits a higher rate of crack deceleration in the second stage, as indicated by the lower slope of the fatigue crack propagation kinetics curve in comparison with the pearlitic and manganese rail steels. This attests to the superior fatigue damage tolerance of the bainitic rail steel in comparison to pearlitic and austenitic manganese rail steels. Microstructural analysis of the three rail steels revealed that bainitic steel has a more intricate structure than AM and pearlitic steels. AM steel shows very few signs of being work hardened or toughened, which usually increases the mechanical properties of the material. As the number of alloying elements increase, the microstructure of the steel becomes more complex, resulting in the increase of mechanical properties and fatigue fracture resistance of bainitic rail steel.
基金supported by the National Training Program of Innovation and Entrepreneurship for Undergraduates,Fundamental Research Funds for the Central Universities(Grant No.2014JBZ017)National Natural Science Foundation of China(Grant No.613770029)Beijing Natural Science Foundation(Grant No.2122050)
文摘Here, we report a trap-assisted photomultiplication （PM） phenomenon in solution-processed organic photodetectors （OPDs） using poly（3-hexylthiophene） （P3HT）： indene-C60 bisadduct （ICBA） as the active layer. The maximum external quantum efficiency （EQE） is 685% for the device with 2% ICBA doping ratio, which is much higher than that of OPDs with P3HT：ICBA （1：1） as the active layer. The PM phenomenon is attributed to the hole tunneling injection assisted by trapped electron in ICBA near A1 cathode, which can be demonstrated from the EQE spectra and transient photocurrent curves of OPDs with different ICBA doping ratios.
文摘In-plane heteroatom substitution of graphene is a promising strategy to modify its properties. The ability to dope graphene with electron-donor nitrogen heteroatoms is highly important for modulating electrical properties of graphene. Here we demonstrate a transfer-free method to directly grow large area quasi free-standing N-doped graphene bilayers on an insulating substrate （Si3N4）. Electron-bombardment heating under nitrogen flux results in simultaneous growth of N-doped graphene and a Si3N4 layer on the SiC surface. The decoupling of N-doped graphene from the substrate and the presence of Si3N4 are identified by X-ray photoemission spectroscopy and low-energy electron diffraction. The substitution of nitrogen atoms in the graphene planes was confirmed using high resolution X-ray photoemission spectroscopy which reveals several atomic configurations for the nitrogen atoms： Graphitic-like, pyridine-like, and pyrrolic- like. Furthermore, we demonstrated for the first time that N-doped graphene could be used to efficiently probe oxygen molecules via nitrogen atom defects.
