TiO 2 films with nano-porous structures were obtained by adding the poly-ethylene glycol(PEG) in the TiO 2 colloid. Then the as-prepared films were sensitized by the trithiophene carboxylic diacid(TTDA), pentathiophen...TiO 2 films with nano-porous structures were obtained by adding the poly-ethylene glycol(PEG) in the TiO 2 colloid. Then the as-prepared films were sensitized by the trithiophene carboxylic diacid(TTDA), pentathiophene carboxylic diacid(PTDA), N3[Ru(Ⅱ)L 2(SCN) 2, L=2,2′-bipyridyl-4,4′-dicarboxylate] dye and the mixture of PTDA and N3 dye, respectively. After fabricating the films into devices, the I-V curves were determined and their photovoltaic properties were studied. The results show that the porous TiO 2 films can be sensitized by both TTDA and PTDA effectively, while the film sensitized by the mixture of PTDA and N3 dye has a maximum photo-electric conversion efficiency.展开更多
The application of the natural dyes extracted from grapes skin in dye-sensitized solar cells as the photosensitive agents was investigated.Two samples battery capability were tested in the dye-sensitized solar cells.T...The application of the natural dyes extracted from grapes skin in dye-sensitized solar cells as the photosensitive agents was investigated.Two samples battery capability were tested in the dye-sensitized solar cells.The results show that the grapes skin pigment possesses a wide absorption near the 520nm.The hydrogen bonds are easy formed between the hydroxy of anthocyanin pigment existing in the grapes skin pigment and the surface oxygen of TiO2,that leads the grapes skin pigment to display the excellent properties in photoelectric conversion comparing with the red roses pigment.Under the sunlight shinning,the grapes skin pigment dye-sensitized solar cells can produce a max photocurrent of 60μA and a steady open voltage of 0.4V,the results demonstrate that the photosensitive agent is a good photoelectricity conversion material.展开更多
A novel unsymmetrical cyanine dye(noted as CD) was applied to dye sensitized nanoporous TiO 2 photoelectrochemical cells. The incident photon to electron conversion efficiency up to 84 34% was achieved, which is notab...A novel unsymmetrical cyanine dye(noted as CD) was applied to dye sensitized nanoporous TiO 2 photoelectrochemical cells. The incident photon to electron conversion efficiency up to 84 34% was achieved, which is notably high for cells employing pure organic dyes. To circumvent the sealing difficulties present in wet type cells, the solid state cell was fabricated using poly(ethyleneoxide)(PEO) based gel network polymer electrolyte as charge transfer material between two electrodes. The resulting solid state cell had an energy conversion efficiency of 0 86%, with open circuit voltage of 0 53 V and short circuit current density of 0 96 mA/cm 2 under 38 1 mW/cm 2 white light illumination. The results show that the gel network polymer electrolyte is appropriate for assembling solid state photoelectrochemical cells.展开更多
近年来,第三代太阳能电池——染料敏化太阳能电池(dye-sensitized solar cells,DSSC)因制造成本低、环境污染少、生产工序简单等优点而备受关注。对电极作为DSSC的重要组成部分是影响其光电转换性能及稳定性的重要因素。综述了对电极材...近年来,第三代太阳能电池——染料敏化太阳能电池(dye-sensitized solar cells,DSSC)因制造成本低、环境污染少、生产工序简单等优点而备受关注。对电极作为DSSC的重要组成部分是影响其光电转换性能及稳定性的重要因素。综述了对电极材料在DSSC中的作用以及研究现状,重点介绍了过渡金属硫化物(transition-metal sulfides,TMSs)在DSSC中的研究进展,阐述了TMSs与其他对电极材料相比具有的优异性能及其制备方法和性能参数,最后提出了今后DSSC研究的主要方向是继续开发各种原料易得、成本低廉和稳定高效的新型对电极材料。TMSs染料敏化太阳能电池作为化合物薄膜太阳能电池中非常重要的组成部分,具有很大的应用前景。展开更多
文摘TiO 2 films with nano-porous structures were obtained by adding the poly-ethylene glycol(PEG) in the TiO 2 colloid. Then the as-prepared films were sensitized by the trithiophene carboxylic diacid(TTDA), pentathiophene carboxylic diacid(PTDA), N3[Ru(Ⅱ)L 2(SCN) 2, L=2,2′-bipyridyl-4,4′-dicarboxylate] dye and the mixture of PTDA and N3 dye, respectively. After fabricating the films into devices, the I-V curves were determined and their photovoltaic properties were studied. The results show that the porous TiO 2 films can be sensitized by both TTDA and PTDA effectively, while the film sensitized by the mixture of PTDA and N3 dye has a maximum photo-electric conversion efficiency.
文摘The application of the natural dyes extracted from grapes skin in dye-sensitized solar cells as the photosensitive agents was investigated.Two samples battery capability were tested in the dye-sensitized solar cells.The results show that the grapes skin pigment possesses a wide absorption near the 520nm.The hydrogen bonds are easy formed between the hydroxy of anthocyanin pigment existing in the grapes skin pigment and the surface oxygen of TiO2,that leads the grapes skin pigment to display the excellent properties in photoelectric conversion comparing with the red roses pigment.Under the sunlight shinning,the grapes skin pigment dye-sensitized solar cells can produce a max photocurrent of 60μA and a steady open voltage of 0.4V,the results demonstrate that the photosensitive agent is a good photoelectricity conversion material.
文摘A novel unsymmetrical cyanine dye(noted as CD) was applied to dye sensitized nanoporous TiO 2 photoelectrochemical cells. The incident photon to electron conversion efficiency up to 84 34% was achieved, which is notably high for cells employing pure organic dyes. To circumvent the sealing difficulties present in wet type cells, the solid state cell was fabricated using poly(ethyleneoxide)(PEO) based gel network polymer electrolyte as charge transfer material between two electrodes. The resulting solid state cell had an energy conversion efficiency of 0 86%, with open circuit voltage of 0 53 V and short circuit current density of 0 96 mA/cm 2 under 38 1 mW/cm 2 white light illumination. The results show that the gel network polymer electrolyte is appropriate for assembling solid state photoelectrochemical cells.
文摘近年来,第三代太阳能电池——染料敏化太阳能电池(dye-sensitized solar cells,DSSC)因制造成本低、环境污染少、生产工序简单等优点而备受关注。对电极作为DSSC的重要组成部分是影响其光电转换性能及稳定性的重要因素。综述了对电极材料在DSSC中的作用以及研究现状,重点介绍了过渡金属硫化物(transition-metal sulfides,TMSs)在DSSC中的研究进展,阐述了TMSs与其他对电极材料相比具有的优异性能及其制备方法和性能参数,最后提出了今后DSSC研究的主要方向是继续开发各种原料易得、成本低廉和稳定高效的新型对电极材料。TMSs染料敏化太阳能电池作为化合物薄膜太阳能电池中非常重要的组成部分,具有很大的应用前景。
