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光纤光化学氨传感器的研究及应用 被引量:4
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作者 戴媛静 陈曦 +2 位作者 庄峙厦 李伟 王小如 《海洋技术》 北大核心 2003年第2期37-43,共7页
氨是导致海洋水体富营养化的重要因素之一 ,基于光纤光化学检测的氨传感器特别适于氨的原位或在线分析。文章介绍了光纤光化学氨传感器的基本原理 ,光纤敏感膜的制备方法及其一些应用情况。发展小型、实用的光纤光化学传感器是未来海水... 氨是导致海洋水体富营养化的重要因素之一 ,基于光纤光化学检测的氨传感器特别适于氨的原位或在线分析。文章介绍了光纤光化学氨传感器的基本原理 ,光纤敏感膜的制备方法及其一些应用情况。发展小型、实用的光纤光化学传感器是未来海水中氨的原位、在线检测的发展趋势之一。 展开更多
关键词 光纤光化学氨传感器 海洋水体 富营养化 光纤敏感膜 制备方法
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基于荧光猝灭的磷酸盐光化学溶胶-凝胶传感膜 被引量:5
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作者 陈曦 钟振明 +3 位作者 李真 李伟 庄峙厦 王小如 《分析测试学报》 CAS CSCD 北大核心 2002年第1期11-14,共4页
利用溶胶 -凝胶技术对荧光物质铝 -桑色素进行包埋 ,根据荧光猝灭原理制取了对水体中磷酸根离子有较好响应的光纤光化学传感膜 ;研究了温度、pH值对传感膜荧光强度的影响以及膜的响应时间、泄漏性、光稳定性及干扰情况等性能指标 ;该传... 利用溶胶 -凝胶技术对荧光物质铝 -桑色素进行包埋 ,根据荧光猝灭原理制取了对水体中磷酸根离子有较好响应的光纤光化学传感膜 ;研究了温度、pH值对传感膜荧光强度的影响以及膜的响应时间、泄漏性、光稳定性及干扰情况等性能指标 ;该传感膜的响应时间t95 % =6min ,磷酸根离子的线性范围在0.1~7.0mg/L,检出限为0.02mg/L。 展开更多
关键词 溶胶-凝胶 磷酸根 桑色素 荧光猝灭 光化学传感膜 包埋 磷酸盐 测定 光纤光化学传感器 水污染 分析
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基于钌配合物荧光猝灭氧二次传感BOD检测的研究 被引量:1
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作者 林玲 肖来龙 +2 位作者 辛玲玲 赵丽 陈曦 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2006年第1期15-18,共4页
考察了利用溶胶凝胶基质制备的氧荧光传感膜的光谱性质,实验结果表明,溶胶凝胶基质与Ru(dpp)3(ClO4)2配合物的基态之间不存在较强的相互作用,具有较好的透光性。将氧光化学传感器作为二次传感,制备了响应良好的光化学BOD微生物传感器,... 考察了利用溶胶凝胶基质制备的氧荧光传感膜的光谱性质,实验结果表明,溶胶凝胶基质与Ru(dpp)3(ClO4)2配合物的基态之间不存在较强的相互作用,具有较好的透光性。将氧光化学传感器作为二次传感,制备了响应良好的光化学BOD微生物传感器,研究结果表明这种传感器对于较低浓度的BOD含量有着良好的线性范围,并且其响应活性保持良好,具有较长的使用寿命和良好的稳定性。 展开更多
关键词 溶解氧 BOD传感 钌配合物 光纤光化学
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Supercontinuum generation pumped by a regeneratively mode-locked fiber laser
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作者 JIA Dong-fang TAN Bin WANG Zhao-ying GE Chun-feng NI Wen-jun LI Shi-chen 《Optoelectronics Letters》 EI 2005年第2期117-120,共4页
Supercontinuum(SC) generation in a dispersion-shifted fiber(DSF) pumped by a 10 GHz regeneratively mode-locked fiber laser(RMLFL) is presented.Optimization of pump wavelength leads to a 20 dB bandwidth of 58.73 nm,whi... Supercontinuum(SC) generation in a dispersion-shifted fiber(DSF) pumped by a 10 GHz regeneratively mode-locked fiber laser(RMLFL) is presented.Optimization of pump wavelength leads to a 20 dB bandwidth of 58.73 nm,which covers the whole C band and part of L band.Using an angle-tuning thin film filter,multi-wavelength and pico-second pulse trains of low chirp could be chosen from the SC spectrum.Amplified spontaneous emission(ASE) induced degeneration of the achieved pulse trains is observed and discussed. 展开更多
关键词 超连续 激光技术 光学纤维 优化设计 SC光谱
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A selective optical chemical sensor for the determination of iodine based on fluorescence quenching of LiTOE
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作者 LONG Li-ping ZHONG Tong-sheng WANG Jiao-liang YIN Zhi-fang LI Wang-ying LEI Cun-xi 《Journal of Environmental Science and Engineering》 2008年第1期72-77,共6页
An optical chemical sensor has been developed for the determination of iodine based on the reversible fluorescence quenching of 2, 2, 7, 7, 12, 12, 17, 17-octamethyl-21, 22, 23, 24-tetraoxaquaterene-Li (LiTOE) imm... An optical chemical sensor has been developed for the determination of iodine based on the reversible fluorescence quenching of 2, 2, 7, 7, 12, 12, 17, 17-octamethyl-21, 22, 23, 24-tetraoxaquaterene-Li (LiTOE) immobilized in a plasticized poly(vinyl chloride) (PVC) membrane. The optimum membrane of the sensor consists of 100 mg of PVC, 200 mg of bis (2-ethytbexyl) sebacate (BOS) and 3.0 mg of LiTOE. The maximum response of the optode membrane for iodine is obtained in Tris-HCl buffer solutlon (pH 8.0). With the optimum conditions described, the proposed sensor responds linearly in the measuring range of 3.90×10^-2 to 3.90×10^-4 mol/L, and has a detection limit of 6.0×10^-8 mol/L. The response time of the sensor is less than I rain. In addition to high reproducibility and reversibility of the fluorescence signal, the sensor also exhibits good selectivity. It is not interfered by some common anions and cations. It is applied for the determination of iodine in table salt samples. The results agree with those obtained by another method. 展开更多
关键词 a selective optical chemical sensor IODINE fluorescence quenching 2 2 7 7 12 12 17 17-Octamethyl-21 22 23 24-tetraoxaquaterene-Li (LiTOE) optode membrane
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Investigation on bismuth-oxide photonic crystal fiber for optical parametric amplification
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作者 金沧 饶岚 +2 位作者 苑金辉 申向伟 余重秀 《Optoelectronics Letters》 EI 2011年第3期194-197,共4页
A hexagonal solid-core bismuth-oxide micro-structure fiber is developed to balance its dispersion and nonlinearity.This simulation and calculation results show that the bismuth-oxide photonic crystal fiber(Bi-PCF) has... A hexagonal solid-core bismuth-oxide micro-structure fiber is developed to balance its dispersion and nonlinearity.This simulation and calculation results show that the bismuth-oxide photonic crystal fiber(Bi-PCF) has near zero dispersion around 1550 nm.Its dispersion slop in the communication wavelength range is also relatively flat.Moreover,both nonlinear coefficient and model field distribution are obtained.Compared with the experimental results by SiO2-PCF,it can be seen that the Bi-PCF shows excellent characteristics for the optical parametric amplification(OPA). 展开更多
关键词 AMPLIFICATION BISMUTH Crystal structure Crystal whiskers Dispersion (waves) Optical frequency conversion Photonic crystals Silicon compounds
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Laser tuned field emission of the carbon nanotube arrays grown on an optical fiber 被引量:1
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作者 WEI XianQi LI Xin +1 位作者 LIU WeiHua WANG XiaoLi 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第10期1936-1940,共5页
Laser was coupled into an optical fiber,on which covered a layer of well-aligned carbon nanotubes(CNTs)serving as cathode,to tune the field emission of the cathode.CNT arrays as field emission cathode were synthesized... Laser was coupled into an optical fiber,on which covered a layer of well-aligned carbon nanotubes(CNTs)serving as cathode,to tune the field emission of the cathode.CNT arrays as field emission cathode were synthesized by chemical vapor deposition(CVD)on a naked fiber core.When the laser was coupled into the fiber,the turn-on voltage(Vto at a current density of 1 mA cm?2)decreased from 1.0 to 0.9 kV and the emission current density increased from 0.83 mA cm?2(at a 1 kV bias voltage)to3.04 mA cm?2 on 40μm diameter fiber.A photon absorption mechanism is attributed to the field emission improvement.The estimated effective work function of CNT arrays on the optical fiber decrease from 4.89 to 4.29 eV.The results show the possibility of constructing a waveguide type laser modulated field emission cathode. 展开更多
关键词 LASER field emission carbon nanotubes optical fiber
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