Formamidinium lead bromide(FAPbBr_(3))nanocrystals(NCs)have been considered to be a good optoelectronic material due to their pure green emission,excellent stability and superior carrier transport characteristics.Howe...Formamidinium lead bromide(FAPbBr_(3))nanocrystals(NCs)have been considered to be a good optoelectronic material due to their pure green emission,excellent stability and superior carrier transport characteristics.However,two-photon pumped amplified spontaneous emission(ASE)and the corresponding nonlinear optical properties of FAPbBr_(3) NCs are scarcely revealed.Herein,we synthesized colloidal FAPbBr_(3) NCs with different sizes by changing the molar ratio of FABr/PbBr_(2) in the precursor solution,using ligand assisted precipitation(LARP)technology at room temperature.Photoluminescence(PL)and time resolved photoluminescence(TRPL)spectroscopy were measured to characterize their ASE properties.And their nonlinear optical properties were studied through the Zscan technique and the two-photon excited fluorescence method.The stimulated emission properties including oneand two-photon pumped ASE have been realized from FAPbBr_(3) NCs.With large two-photon absorption coefficient(0.27 cm/GW)and high non-linear absorption cross-section(7.52×10^(5) GM),ASE with threshold as low as 9.8μJ/cm^(2) and 487μJ/cm^(2) have been obtained from colloidal FAPbBr_(3) NCs using one-and two-photon excitations.These results indicate that as a new possible green-emitting frequency-upconversion material with low thresholds,FAPbBr_(3) NCs hold great potential in the development of high-performance two-photon pump lasers.展开更多
Cloud point extraction (CPE) processes with two silicone surfactants, Dow Coming DC-190 and DC-193, were studied as preconcentration and treatment for the water polluted by three trace polycyclic aromatic hydrocarbo...Cloud point extraction (CPE) processes with two silicone surfactants, Dow Coming DC-190 and DC-193, were studied as preconcentration and treatment for the water polluted by three trace polycyclic aromatic hydrocarbons (PAHs): anthracene, phenanthrene and pyrene. For all cases, the volumes of surfactant-rich phase obtained by two silicone surfactants were very small, i.e. a lower water content in the surfactant-rich phase was obtained. For example, less than 3% of the initial solution was obtained in a 1% (by mass) surfactant solution, which was much smaller than that of TX-114 in the same surfactant concentration. And TX-114 is known as a high compact surfactant-rich phase among most nonionic surfactants, thus the comparison showed that an excellent enrichment was ensured in the analysis application by the CPE process with the silicone surfactants, and the lower water content obtained in the surfactant-rich phase is also important in the large scale water treatment. The influences of additives and phase separation methodology on the recovery of PAHs were discussed. Comparing with DC-193, DC-190 has a lower cloud point and a higher recovery (near 100%) of all the three PAHs in same surfactant concentration, which was required for application as a preconcentration process prior to HPLC system. However the DC-190 solution is hard to be phase separated only by heating, whereas DC-193 has a relative higher phase separating speed by heating, but a high cloud point (around 360K) limits its application. Due to the phase separation by heating is the only method of CPE suitable to the large scale water treatment, the mixtures of two silicone surfacrants solutions were investigated in this study. A solution containing 1% of mixed DC-190 and DC-193 (in the ratio of 90 : 10) removed anthracene, phenanthrene and pyrene near 100% with a relative low cloud point and quick phase separating speed.展开更多
An opportunity to use laser radiation as a means to reduce negative aftermath of acute and prolonged exposure to ionizing radiation was checked. The mice were exposed to γ- rays of ^60Co (whole body irradiation) in...An opportunity to use laser radiation as a means to reduce negative aftermath of acute and prolonged exposure to ionizing radiation was checked. The mice were exposed to γ- rays of ^60Co (whole body irradiation) in the dose of 7 Gy (the transitional clinical form of the acute radiation sickness). The dose rate at acute irradiation was 1.14 Gy/min, and at prolonged exposure, 0.027 Gy/min. Laser radiation in the dose l mJ/cm^2 was used to irradiate only the back of a mouse. First, the mice were exposed to γ-radiation, then to laser radiation. The time interval between two types of irradiation did not exceed 30 min. It was shown that the radiation protection of mice with laser radiation is possible at exposure to ionizing radiation in a wide dose interval and can reduce negative after-effects of both the acute and prolonged radiation exposure.展开更多
The mechanism of γ-ray radiation induced absorption loss of the optical fiber in visible range is analyzed. According to the mechanism, the quantitative relation between loss in optical fiber and γ-ray cumulation do...The mechanism of γ-ray radiation induced absorption loss of the optical fiber in visible range is analyzed. According to the mechanism, the quantitative relation between loss in optical fiber and γ-ray cumulation dose is found by use of methods of solid physics and statistic physics. This quantitative relation is certified in terms of the results of radiation experiment.展开更多
Based on the power dissipating model of spherical sample in free convection gas medium and the expression of input power, the model of temperature calculation for electromagnetic levitation melting sample was establis...Based on the power dissipating model of spherical sample in free convection gas medium and the expression of input power, the model of temperature calculation for electromagnetic levitation melting sample was established. Considering the limitation of levitation force and levitation sample temperature,the principle of stability levitation zone computation was determined. A spherical sample (ThDy)Fe2 under the protection of argon gas was examined, and the effect of radius of levitation sample and perturbation on the stable levitation zone was investigated. The results show that longitudinal perturbation and transverse perturbation can shorten the length of stable levitation zone and the range of levitation sample radius. By increasing the sample radius and weakening the perturbation the electromagnetic levitation melting stability of sample can be improved.展开更多
1 INTRODUCTION Cloud radiation is one of the most important and indefinite factors in atmospheric radiation. As shown in a comparative study by Cess et al. with a climate model, differences can be very large in the ou...1 INTRODUCTION Cloud radiation is one of the most important and indefinite factors in atmospheric radiation. As shown in a comparative study by Cess et al. with a climate model, differences can be very large in the outcome of varying schemes of cloud parameterization. It is therefore of great significance to have a relatively accurate scheme of cloud parameterization for the atmospheric radiative transfer process. According to the Mie's scattering theory, the scale parameter of the particulate has a very important effect on its optical property. It is then seen that the number concentration and size distribution of cloud droplets play an important in the determination of the optical properties of cloud droplets.展开更多
The authors synthesized very pure dimer phase of coroneae by simple heat-treatment and subsequent sublimation purification. It was confirmed by laser desorption/ionization mass spectroscopy measurements that pure dime...The authors synthesized very pure dimer phase of coroneae by simple heat-treatment and subsequent sublimation purification. It was confirmed by laser desorption/ionization mass spectroscopy measurements that pure dimer phase of coronenes can be obtained by controlling the fusing and sublimation temperatures. The crystal structure of the dimer phase was analyzed by synchrotron XRD (X-ray diffraction) experiments. It was also found that very bright red light is emitted by irradiating ultra violet light (λ = 350 nm) to the dimer phase. The external and internal quantum yields were determined to be 5.56% and 6.95%, respectively.展开更多
A comparison is made of the intensity distribution of the horizontally and vertically polarized radiation sidescattered from small spherical particles in a cylindrical scattering volume.The incident radiation is a nea...A comparison is made of the intensity distribution of the horizontally and vertically polarized radiation sidescattered from small spherical particles in a cylindrical scattering volume.The incident radiation is a nearly collimated linearly polarized He-Ne laser beam.The scattering medium consists of various concentrations of particles which are either 0.22 μm or 0.494 μm in diameter and which were suspended in filtered,distilled water.In general,the effect of the diameter of the particle on depolari-zing the incident beam is more important than the particle concentration,detector depth,and so on.展开更多
The objective of this work is to assess the radiation hazards associated gamma rays from building materials. Natural gamma rays activities of natural radionuclide represented mainly by three natural radioactive series...The objective of this work is to assess the radiation hazards associated gamma rays from building materials. Natural gamma rays activities of natural radionuclide represented mainly by three natural radioactive series ^238U, ^235U and ^232Th, and the primordial ^40K in the samples of building materials which consist of bricks, ceramics, marble and gypsum from different areas of eastern Algeria are measured using gamma ray spectrometry. The values of the activities of these radionuclides do not clearly reflect the radiation hazard associated with these materials. Therefore, the radium equivalent (Raeq) concentration is defined taking into account the effectiveness of these isotopes in creating the radiation hazard. Radium equivalent activities, external and internal hazard indices (Hex and Hin) are calculated from the activities of ^226Ra, ^232Th and ^40K for suitability of the materials.展开更多
We examined the effects of polypeptide from Chlamys farreri (PCF) on the amount of hy-droxyproline in guinea pig skin irradiated by chronic ultraviolet A (UVA) and ultraviolet B (UVB) radiation. PCF was applied locall...We examined the effects of polypeptide from Chlamys farreri (PCF) on the amount of hy-droxyproline in guinea pig skin irradiated by chronic ultraviolet A (UVA) and ultraviolet B (UVB) radiation. PCF was applied locally before repeated exposure of guinea pig to UVA and UVB. The contents of hy-droxyproline and other amino acids in guinea pig skin were determined by automatic amino acid analyzer. Our results showed that: (1) long-time UVA and UVB radiation can reduce dramatically the amounts of hy-droxyproline, aspartic acid, threonine, glycine, phenylalanine and lysine in guinea pig skin in comparison with the control group (P < 0.05); (2) Compared with model group, pre-treatment with 5 % and 20 % PCF prior to UVA and UVB radiation can inhibit the decline of amino acids content in guinea pig skin in a dose-dependent manner (P < 0.05). As the decrease of hydroxyproline, glycine and lysine contents in the skin directly reflexes type I collagen degeneration, our results indicated that the chronic application of PCF can protect skin type I collagen against UV radiation, and thus protect skin from photoaging.展开更多
充满辐射,大气
PSR B1257+12星系是人们最先发现的系外行星星系之一。据悉,该星系对于已知生物来说,就像是一个墓地。来自超新星的巨大冲击波,剥离了该星系的所有大气。行星被暴露在致命的宇宙辐射之下,致使该星系与生命无缘。...充满辐射,大气
PSR B1257+12星系是人们最先发现的系外行星星系之一。据悉,该星系对于已知生物来说,就像是一个墓地。来自超新星的巨大冲击波,剥离了该星系的所有大气。行星被暴露在致命的宇宙辐射之下,致使该星系与生命无缘。就算曾经有生物一度生活在这个星系中,也已走向覆灭。现在,星球上只留下众多阴森恐怖的岩石,并不时地发出强辐射光线。展开更多
X-ray emission from metal cathodes in glow discharge (current is up to 300 mA, voltage is 1,500-4,300 V) experiments in the spectral range from 700 eV to 6 keV has been observed. The effect has been seen with a vari...X-ray emission from metal cathodes in glow discharge (current is up to 300 mA, voltage is 1,500-4,300 V) experiments in the spectral range from 700 eV to 6 keV has been observed. The effect has been seen with a variety of different metal cathodes (including AI, Sc, Ti, V, Ni, Nb, Zr, Mo, Pd, Ta, W, and Pt), as well as with different gasses (including D2, H2, Kr, Ar, and Xe) at low pressure (3-10 Torr). We present results from a variety of diagnostics, including: pinhole camera imaging; thermo luminescent detector measurements; time-resolved scintillator measurements; and a curved mica spectrometer to register X-ray spectra. Both diffuse and collimated X-ray emission have been observed.. Diffuse emission occurs in bursts of X-rays; with up to 10^5 bursts per second, with up to 10^6 photons per burst during the discharge. Collimated X-ray emission appears in the form of beamlets directed normal to the cathodes surface with a very small angular divergence; with up to 104 bursts per second, and up to 1013 photons overall up to 20 h after discharge switch off. Based on these experimental results we propose a phenomenological model of processes.展开更多
A research was carried out to determine the period of time during which it is possible to reduce the radiation damage in mice by means of laser radiation (650 nm) after gamma irradiation. First, the mice were expose...A research was carried out to determine the period of time during which it is possible to reduce the radiation damage in mice by means of laser radiation (650 nm) after gamma irradiation. First, the mice were exposed to γ- radiation (whole body irradiation), then after 2 h or 24 h they were irradiated with laser radiation. The results of these studies have shown that the use of laser irradiation to reduce radiation damage in mice is effective 24 h after the exposure to 5 Gy ionizing radiation which leads to the bone-marrow clinical form of the ARS (Acute radiation sickness). In case of the lethal dose of ionizing radiation 7 Gy (the transitional clinical form of the ARS), the increase in life expectancy of mice is observed using laser radiation both 2 and 24 h after the exposure to γ- radiation, but the effectiveness of the laser used 2 h after the ionizing radiation is significantly more efficient.展开更多
The photoionization and dissociation of 2-methyl-2-propen-1-ol(MPO)have been investigated by using molecular beam experimental apparatus with tunable vacuum ultraviolet synchrotron radiation in the photon energy regio...The photoionization and dissociation of 2-methyl-2-propen-1-ol(MPO)have been investigated by using molecular beam experimental apparatus with tunable vacuum ultraviolet synchrotron radiation in the photon energy region of 8.0-15.5 eV.The photoionization efficiency(PIE)curves for molecule ion and fragment ions:C4H8O^+,C4H7O^+,C3H5O^+,C4H7^+,C4H6^+,C4H5^+,C2H4O^+,C2H3O+,C3H6^+,C3H5^+,C3H3^+,CH3O^+,CHO^+have been measured,and the ionization energy(IE)and the appearance energies(AEs)of the fragment ions have been obtained.The stable species and the first order saddle points have been calculated on the CCSD(T)/cc-pvTZ//B3LYP/6-31+G(d,p)level.With combination of theoretical and experimental results,the dissociative photoionization pathways of 2-methyl-2-propen-1-ol are proposed.Hydrogen migrations within the molecule are the dominant processes in most of the fragmentation pathways of MPO.展开更多
文摘Formamidinium lead bromide(FAPbBr_(3))nanocrystals(NCs)have been considered to be a good optoelectronic material due to their pure green emission,excellent stability and superior carrier transport characteristics.However,two-photon pumped amplified spontaneous emission(ASE)and the corresponding nonlinear optical properties of FAPbBr_(3) NCs are scarcely revealed.Herein,we synthesized colloidal FAPbBr_(3) NCs with different sizes by changing the molar ratio of FABr/PbBr_(2) in the precursor solution,using ligand assisted precipitation(LARP)technology at room temperature.Photoluminescence(PL)and time resolved photoluminescence(TRPL)spectroscopy were measured to characterize their ASE properties.And their nonlinear optical properties were studied through the Zscan technique and the two-photon excited fluorescence method.The stimulated emission properties including oneand two-photon pumped ASE have been realized from FAPbBr_(3) NCs.With large two-photon absorption coefficient(0.27 cm/GW)and high non-linear absorption cross-section(7.52×10^(5) GM),ASE with threshold as low as 9.8μJ/cm^(2) and 487μJ/cm^(2) have been obtained from colloidal FAPbBr_(3) NCs using one-and two-photon excitations.These results indicate that as a new possible green-emitting frequency-upconversion material with low thresholds,FAPbBr_(3) NCs hold great potential in the development of high-performance two-photon pump lasers.
文摘Cloud point extraction (CPE) processes with two silicone surfactants, Dow Coming DC-190 and DC-193, were studied as preconcentration and treatment for the water polluted by three trace polycyclic aromatic hydrocarbons (PAHs): anthracene, phenanthrene and pyrene. For all cases, the volumes of surfactant-rich phase obtained by two silicone surfactants were very small, i.e. a lower water content in the surfactant-rich phase was obtained. For example, less than 3% of the initial solution was obtained in a 1% (by mass) surfactant solution, which was much smaller than that of TX-114 in the same surfactant concentration. And TX-114 is known as a high compact surfactant-rich phase among most nonionic surfactants, thus the comparison showed that an excellent enrichment was ensured in the analysis application by the CPE process with the silicone surfactants, and the lower water content obtained in the surfactant-rich phase is also important in the large scale water treatment. The influences of additives and phase separation methodology on the recovery of PAHs were discussed. Comparing with DC-193, DC-190 has a lower cloud point and a higher recovery (near 100%) of all the three PAHs in same surfactant concentration, which was required for application as a preconcentration process prior to HPLC system. However the DC-190 solution is hard to be phase separated only by heating, whereas DC-193 has a relative higher phase separating speed by heating, but a high cloud point (around 360K) limits its application. Due to the phase separation by heating is the only method of CPE suitable to the large scale water treatment, the mixtures of two silicone surfacrants solutions were investigated in this study. A solution containing 1% of mixed DC-190 and DC-193 (in the ratio of 90 : 10) removed anthracene, phenanthrene and pyrene near 100% with a relative low cloud point and quick phase separating speed.
文摘An opportunity to use laser radiation as a means to reduce negative aftermath of acute and prolonged exposure to ionizing radiation was checked. The mice were exposed to γ- rays of ^60Co (whole body irradiation) in the dose of 7 Gy (the transitional clinical form of the acute radiation sickness). The dose rate at acute irradiation was 1.14 Gy/min, and at prolonged exposure, 0.027 Gy/min. Laser radiation in the dose l mJ/cm^2 was used to irradiate only the back of a mouse. First, the mice were exposed to γ-radiation, then to laser radiation. The time interval between two types of irradiation did not exceed 30 min. It was shown that the radiation protection of mice with laser radiation is possible at exposure to ionizing radiation in a wide dose interval and can reduce negative after-effects of both the acute and prolonged radiation exposure.
文摘The mechanism of γ-ray radiation induced absorption loss of the optical fiber in visible range is analyzed. According to the mechanism, the quantitative relation between loss in optical fiber and γ-ray cumulation dose is found by use of methods of solid physics and statistic physics. This quantitative relation is certified in terms of the results of radiation experiment.
文摘Based on the power dissipating model of spherical sample in free convection gas medium and the expression of input power, the model of temperature calculation for electromagnetic levitation melting sample was established. Considering the limitation of levitation force and levitation sample temperature,the principle of stability levitation zone computation was determined. A spherical sample (ThDy)Fe2 under the protection of argon gas was examined, and the effect of radius of levitation sample and perturbation on the stable levitation zone was investigated. The results show that longitudinal perturbation and transverse perturbation can shorten the length of stable levitation zone and the range of levitation sample radius. By increasing the sample radius and weakening the perturbation the electromagnetic levitation melting stability of sample can be improved.
文摘1 INTRODUCTION Cloud radiation is one of the most important and indefinite factors in atmospheric radiation. As shown in a comparative study by Cess et al. with a climate model, differences can be very large in the outcome of varying schemes of cloud parameterization. It is therefore of great significance to have a relatively accurate scheme of cloud parameterization for the atmospheric radiative transfer process. According to the Mie's scattering theory, the scale parameter of the particulate has a very important effect on its optical property. It is then seen that the number concentration and size distribution of cloud droplets play an important in the determination of the optical properties of cloud droplets.
文摘The authors synthesized very pure dimer phase of coroneae by simple heat-treatment and subsequent sublimation purification. It was confirmed by laser desorption/ionization mass spectroscopy measurements that pure dimer phase of coronenes can be obtained by controlling the fusing and sublimation temperatures. The crystal structure of the dimer phase was analyzed by synchrotron XRD (X-ray diffraction) experiments. It was also found that very bright red light is emitted by irradiating ultra violet light (λ = 350 nm) to the dimer phase. The external and internal quantum yields were determined to be 5.56% and 6.95%, respectively.
文摘A comparison is made of the intensity distribution of the horizontally and vertically polarized radiation sidescattered from small spherical particles in a cylindrical scattering volume.The incident radiation is a nearly collimated linearly polarized He-Ne laser beam.The scattering medium consists of various concentrations of particles which are either 0.22 μm or 0.494 μm in diameter and which were suspended in filtered,distilled water.In general,the effect of the diameter of the particle on depolari-zing the incident beam is more important than the particle concentration,detector depth,and so on.
文摘The objective of this work is to assess the radiation hazards associated gamma rays from building materials. Natural gamma rays activities of natural radionuclide represented mainly by three natural radioactive series ^238U, ^235U and ^232Th, and the primordial ^40K in the samples of building materials which consist of bricks, ceramics, marble and gypsum from different areas of eastern Algeria are measured using gamma ray spectrometry. The values of the activities of these radionuclides do not clearly reflect the radiation hazard associated with these materials. Therefore, the radium equivalent (Raeq) concentration is defined taking into account the effectiveness of these isotopes in creating the radiation hazard. Radium equivalent activities, external and internal hazard indices (Hex and Hin) are calculated from the activities of ^226Ra, ^232Th and ^40K for suitability of the materials.
基金Project No. 39970638 supported by the NSFC and also supported by the Science and Technology Bureau of Qingdao (No: 2001- 28- 50).
文摘We examined the effects of polypeptide from Chlamys farreri (PCF) on the amount of hy-droxyproline in guinea pig skin irradiated by chronic ultraviolet A (UVA) and ultraviolet B (UVB) radiation. PCF was applied locally before repeated exposure of guinea pig to UVA and UVB. The contents of hy-droxyproline and other amino acids in guinea pig skin were determined by automatic amino acid analyzer. Our results showed that: (1) long-time UVA and UVB radiation can reduce dramatically the amounts of hy-droxyproline, aspartic acid, threonine, glycine, phenylalanine and lysine in guinea pig skin in comparison with the control group (P < 0.05); (2) Compared with model group, pre-treatment with 5 % and 20 % PCF prior to UVA and UVB radiation can inhibit the decline of amino acids content in guinea pig skin in a dose-dependent manner (P < 0.05). As the decrease of hydroxyproline, glycine and lysine contents in the skin directly reflexes type I collagen degeneration, our results indicated that the chronic application of PCF can protect skin type I collagen against UV radiation, and thus protect skin from photoaging.
文摘充满辐射,大气
PSR B1257+12星系是人们最先发现的系外行星星系之一。据悉,该星系对于已知生物来说,就像是一个墓地。来自超新星的巨大冲击波,剥离了该星系的所有大气。行星被暴露在致命的宇宙辐射之下,致使该星系与生命无缘。就算曾经有生物一度生活在这个星系中,也已走向覆灭。现在,星球上只留下众多阴森恐怖的岩石,并不时地发出强辐射光线。
文摘X-ray emission from metal cathodes in glow discharge (current is up to 300 mA, voltage is 1,500-4,300 V) experiments in the spectral range from 700 eV to 6 keV has been observed. The effect has been seen with a variety of different metal cathodes (including AI, Sc, Ti, V, Ni, Nb, Zr, Mo, Pd, Ta, W, and Pt), as well as with different gasses (including D2, H2, Kr, Ar, and Xe) at low pressure (3-10 Torr). We present results from a variety of diagnostics, including: pinhole camera imaging; thermo luminescent detector measurements; time-resolved scintillator measurements; and a curved mica spectrometer to register X-ray spectra. Both diffuse and collimated X-ray emission have been observed.. Diffuse emission occurs in bursts of X-rays; with up to 10^5 bursts per second, with up to 10^6 photons per burst during the discharge. Collimated X-ray emission appears in the form of beamlets directed normal to the cathodes surface with a very small angular divergence; with up to 104 bursts per second, and up to 1013 photons overall up to 20 h after discharge switch off. Based on these experimental results we propose a phenomenological model of processes.
文摘A research was carried out to determine the period of time during which it is possible to reduce the radiation damage in mice by means of laser radiation (650 nm) after gamma irradiation. First, the mice were exposed to γ- radiation (whole body irradiation), then after 2 h or 24 h they were irradiated with laser radiation. The results of these studies have shown that the use of laser irradiation to reduce radiation damage in mice is effective 24 h after the exposure to 5 Gy ionizing radiation which leads to the bone-marrow clinical form of the ARS (Acute radiation sickness). In case of the lethal dose of ionizing radiation 7 Gy (the transitional clinical form of the ARS), the increase in life expectancy of mice is observed using laser radiation both 2 and 24 h after the exposure to γ- radiation, but the effectiveness of the laser used 2 h after the ionizing radiation is significantly more efficient.
基金supported by the National Natural Science Foundation of China(No.91544105,No.U1532137,No.275127,No.U1232130,No.U1232209,and No.U11575178)the Supercomputing Center of USTC is also acknowledged
文摘The photoionization and dissociation of 2-methyl-2-propen-1-ol(MPO)have been investigated by using molecular beam experimental apparatus with tunable vacuum ultraviolet synchrotron radiation in the photon energy region of 8.0-15.5 eV.The photoionization efficiency(PIE)curves for molecule ion and fragment ions:C4H8O^+,C4H7O^+,C3H5O^+,C4H7^+,C4H6^+,C4H5^+,C2H4O^+,C2H3O+,C3H6^+,C3H5^+,C3H3^+,CH3O^+,CHO^+have been measured,and the ionization energy(IE)and the appearance energies(AEs)of the fragment ions have been obtained.The stable species and the first order saddle points have been calculated on the CCSD(T)/cc-pvTZ//B3LYP/6-31+G(d,p)level.With combination of theoretical and experimental results,the dissociative photoionization pathways of 2-methyl-2-propen-1-ol are proposed.Hydrogen migrations within the molecule are the dominant processes in most of the fragmentation pathways of MPO.