“LED性能表征及应用探索”精品实验课程的设计

基于"第四代LED照明光源"平台载体,按照"一纵三横"设计方案,构筑精品实验课程内容框架。课程内容涵盖LED产业链的上中下游过程,包括LED芯片、荧光粉、灯珠、组件、灯具的光色电性能表征,LED灯具频闪、配光特性测试以及LED驱动、显示屏、LED调光等设计内容,实验类型包括验证型、综合型和设计型。设计了Flash课件辅助预习、PPT理论讲座、交叉实验、开放设计以及课程点评等具体的课程实施环节,既保证有效课时,又保证了课程的深度和广度,促进了不同学院之间的学科交叉融合,提升了学生的科学素养和综合设计能力,效果良好。

Synthesis and optophysical properties of blue-emitting iridium (Ⅲ) complex bearing oxadiazole-based picolinic acid derivative

An iridium （Ⅲ） bis[（4,6-difluorophenyl）pyridinato-N, C^2][6-（6＇-（4＂-（ 5＂-phenyl- 1＂, 3＂, 4＂-oxadiazole-2＂-yl） phenoxy） hexyloxy picolinate） was synthesized and characterized by IH NMR and elementary analysis in order to study the effect of ancillary ligand of the oxadiazole-based picolinic acid derivative on optophysical properties of its iridium complex, and further to obtain an iridium complex with highly-efficient blue emission. The thermal stability, UV absorption and photoluminescent properties of this iridium complex were investigated. Compared with iridium （Ⅲ） bis[（4,6-difluorophenyl）pyridinato-N, C^2]（picolinate） reported as a highly-efficient blue electroluminescent material, this iridium complex bearing an oxadiazole-based picolinic acid derivative presents higher thermal stability, more intense UV absorption at 291 nm and similar photoluminescent spectrum peaked at 469 nm. This indicates that tuning ancillary ligand of picolinic acid with an oxadiazole unit can improve the optophysical properties of its iridium complex.

Comparison of Structures and Properties between Wool and Ramie Fibers Treated by Atmospheric Pressure Ar and Ar/O_2 Plasma

The technique of atmospheric pressure plasma is of value in textile industry.In this paper,argon(Ar)and argon/oxygen(Ar/O2)atmospheric pressure plasma were used to treat wool and ramie fibers.The structures and properties of treated fibers were investigated by means of SEM,XPS,single fiber tensile tester and so on.The results proved that the effects of plasma treatments depended on structural characteristics of fibers to a great extent,besides conditions of plasma treatment.By atmospheric pressure plasma treatment,wool fiber had significant changes in morphology structure,surface chemical component,mechanic properties and dyeability,while ramie fiber just showed a little change.In additional,Ar/O2 plasma showed more effective action than argon.And at the beginning of treatment,plasma brought about remarkable effects,which did not increase with prolonging of treat time.

Barrier effects on the optoelectronic properties of GaN-based irregular multiple quantum wells for dichromatic white LEDs

The GaN-based irregular multiple quantum well (IMQW) structures for dichromatic white light-emitting diodes (LEDs) are assembled by two different types of QWs emitting complementary blue and yellow light. The electronic and optical properties of the designed GaN-based IMQW structures are investigated in details by fully considering the effects of strain,well-coupling,valence band-mixing and polarization effect by employing a newly modified theoretical model based on the k·p theory. The influences of the height and thickness of the barrier between blue QWs and yellow QWs together with the polarization effect on the optoelectronic properties of GaN-based IMQW structure are analyzed. Numerical results show that the ratio of the two color lights emmited from the IMQW structure for dichromatic white LED can be tuned by changing the height and thickness of the barrier between two types of QWs.

Molecular engineering tuning optoelectronic properties of thieno[3,2-b]thiophenes-based electrochromic polymers

Thieno[3,2-b]thiophene(TT)monomers end-capped with 3,4-ethylenedioxythiophene(EDOT)moieties are electropolymerized to formπ-conjugated polymers with distinct electrochromic(EC)properties.Steric and electronic factors(electron donor and acceptor substituents)in the side groups of the TT core,as well as the structure of the polymer backbone strongly affect the electrochemical and optical properties of the polymers and their electrochromic characteristics.The studied polymers show low oxidation potentials,tunable from-0.78 to+0.30 V(vs.Fc/Fc^+)and the band gaps from 1.46 to 1.92 eV and demonstrate wide variety of color palettes in polymer films in different states,finely tunable by structural variations in the polymer backbone and the side chains.EC materials of different colors in their doped/dedoped states have been developed(violet,deep blue,light blue,green,brown,purple-red,pinkish-red,orange-red,light gray,cyan and colorless transparent).High optical contrast(up to 79%),short response time(0.57-0.80 s),good cycling stability(up to 91%at 2000 cycles)and high coloration efficiency(up to 234.6 cm2C^(-1))have been demonstrated and the influence of different factors on the above parameters of EC polymers have been discussed.