双束分步激光光解方法的建立及应用

建立了双束激光激发分子的方法 ,即通过第一束激光把分子激发到激发三线态 ,以第二束共振激光再把三线态分子激发到更高的激发态 ,甚至使其电离的方法。利用这种研究方法对二苯甲酮分子进行了研究 ,结果发现 ,高激发三线态的二苯甲酮分子与异丙醇分子进行的抽氢反应要比低激发三线态分子快得多 ,这为研究处于高激发态分子的电子转移反应提供了新的途径。同时 。

高效薄层析进行农药吸附态光解的研究

研究了绿麦隆和消草醚２种除草剂在硅胶Ｇ高效薄层上的光稳定性，提出应用高效薄层析技术作为农药吸附态光解的一种试验方法。在高效薄层上直接点样，同一薄层上包括照光、黑暗对照和定量曲线样品，原始剂量４００—８００ｎｇ·１×５ｍｍ斑点－１，照光后直接展开和扫描定量测定，最低检测量可达２０ｎｇ·斑点－１。本方法无须对样品进行提取、净化等处理，具有快速高效、重复性好，且可直观光解产物等优点。

Linearity optimization of edge filter demodulators in FBG_s

A kind of electric circuit is improved to optimize the linearity of edge filter demodulators in FBG .By using a logarithm amplifier and an extraction operation, the linear range of optimized edge filter demodulators has been broadened effectively, and the requirement of optical filter＇s linear range has been reduced. Theoretical analyses and the simulation results indi-cated that the linear range of optimized edge fdter demodulator＇s covers the whole transition region of the edge filter, while a strict linearity of the optical filter is not necessary.

Soliton Solutions for Nonisospectral AKNS Equation by Hirota＇s Method

Bilinear form of the nonisospectral AKNS equation is given. The N-soliton solutions are obtained through Hirota＇s method.

N-Soliton Solutions of(2+1)-Dimensional Non-isospectral AKNS System

The bilinear form of the （2＋1）-dimensional non-isospectral AKNS system is derived. Its N-soliton solutions are obtained by using the Hirota method. As a reduction, a （2＋1）-dimensional non-isospectral Schrodinger equation and its N-soliton solutions are constructed.

Pseudo-spectral Approximations for a Class of the Kdv-Burgers Type Equation

In this paper, the pseudo-spectral approximations for a class of the Kdv-Burgers type equation is presented. Convergence and stability of the approximation have been proved by Sobolev's inequalities and the bounded extensive method of the nonlinear function. Finally, the numerical examples are proposed.

Decomposition Method for Complex 3D Problems in Electron Optics

The decomposition method was successfully used in solving of 3D problems with complex geometry shape in electron optics for the FDM （Finite Difference Method） and FEM （Finite Element Method） mostly to implement fast and robust parallel algorithms and computer codes. We suggest a new version of similar approach for the BEM （Boundary Element Method） based on the alternating method by Schwartz. This approach substantially reduce the dimension of dense global matrix of algebraic system produced by BEM algorithm to solve a complex problem on as single CPU （Central Processor Unit） desktop computer. New algorithm is iterative one, but exponential convergence for the Schwatlz＇s algorithm creates the fast numerical procedures. We describe the results of numerical simulation for a multi electrode ion transport system. The algorithms were implemented in the computer code ＂POISSON-3＂.

Photolysis and Rate Constant of 2,3-butanedione with OH Radicals in the Aqueous Phase under Tropospheric Conditions

Photolysis rate （J1） and reaction rate constants （kl） for the biacetyl （butane-2,3-dione） were evaluated in aqueous phase using a continuous photolysis system with a conventional Xe-Hg arc lamp as a light source. The OH radicals was generated by H2OE/UV process and biacetyl （CH3C（O）C（O）CH3） concentrations were monitored using 2,4-DNPH derivatization method. 2,3-butanedione molecule is widely present in the atmosphere, it have been detected in hydrometeors （fogs, rain, and clouds） and at a significant yield （up to 10μmolar）. The measurements were performed at 294 K and with free pH values. Our results lead to the following obtained values： J1= 3×10^-4 S^-1 and k1 = （6.17±0.95）×10^8 M^-1·s^-1.The uncertainty listed above is ±15%.

A second order finite difference-spectral method for space fractional diffusion equations

A high order finite difference-spectral method is derived for solving space fractional diffusion equations,by combining the second order finite difference method in time and the spectral Galerkin method in space.The stability and error estimates of the temporal semidiscrete scheme are rigorously discussed,and the convergence order of the proposed method is proved to be O(τ2+Nα-m)in L2-norm,whereτ,N,αand m are the time step size,polynomial degree,fractional derivative index and regularity of the exact solution,respectively.Numerical experiments are carried out to demonstrate the theoretical analysis.

The Expansion of a Wedge of Gas into Vacuum with Small Angle in Two-Dimensional Isothermal Flow

In this paper, the authors consider the expansion problem of a wedge of gas into vacuum for the two-dimensional Euler equations in isothermal flow. By the bootstrapping argument, they prove the global existence of the smooth solution through the direct method in the case 0 〈 θ 〈 -θ=arctan 1/（√2＋√5）, where θ is the half angle of the wedge. Furthermore, they get the uniform C^1,1 estimates of the solution to the expansion problem.

Direct visualization of the charge transfer in conjugated polymers

Ion-induced charge-transfer states in conjugated polyelectrolytes were experimentally investigated by Justin M.Hodgkiss and his co-workers [J Am Chem Soc,2009,131(25):8913].In this work,charged and neutral conjugated polyelectrolytes were further studied with quantum chemistry methods.The calculation result shows that the absorption spectra are roughly in visible and ultraviolet light regions,and the two absorption peaks are located in the wavelength span 300-400 nm for charged polyelectrolytes.However,in neutral conjugated polyelectrolytes,the peaks of the absorption spectra showed a blue shift compared with those of the charged polyelectrolytes.Charge transfer (CT) properties of the studied compounds were also investigated with both the three-dimensional real-space analysis method of transition and charge difference densities,and the two-dimensional real-space analysis method of transition density matrices based on the simulated absorption spectra.The calculation results revealed the charge transfer in conjugated polyelectrolytes on the excitation states.