[Objective] This study aimed to solve the mulch plastic film pollution problems in Xinjiang, in order to provide reliable theoretical basis for the research on the degradation mechanism of biodegradable plastic films....[Objective] This study aimed to solve the mulch plastic film pollution problems in Xinjiang, in order to provide reliable theoretical basis for the research on the degradation mechanism of biodegradable plastic films. [Method] The effect of illumination intensity on the decomposition of decomposable mulching films was investigated through simulating the field condition in laboratory. Regression analysis was employed to fit the processes of film decompositions. [Result] The weight loss ratios of different types of plastic films were closely related with the illumination. There was no sundry produced during the degradation process, but the weight was reduced, indicating that degradation produced gas, thus, ultraviolet rays had destructive effect on mulch plastic films. Different types of plastic films showed significant differences in the degradation speeds, and under the same conditions, the degradation speed of S4# with the induction period of 30 d was the fastest. With the extension of uv illumination time, the degradation became cumulative degradation process. [Conclusion] Under the uv rays, the weight loss ratio and illumination hours is regarded as a positive correlation relationship. The significant inspection shows that the data fitted degradation model can be described by the logistic model of Y = a/（1＋b×e -ct）, and all the parameters show significant differences （P0.01）.展开更多
The mesoporous Ti O2 has been synthesized by evaporation induced self assembly(EISA) method. The thermogravimetric/differential scanning calorimetric(TG/DSC), X-ray diffraction(XRD), high-resolution transmission elect...The mesoporous Ti O2 has been synthesized by evaporation induced self assembly(EISA) method. The thermogravimetric/differential scanning calorimetric(TG/DSC), X-ray diffraction(XRD), high-resolution transmission electron microscopy(HR-TEM) and N2 adsorption desorption and adsorption are used to study the effects of the synthesized process condition on the microstructure of the as-synthesized mesoporous Ti O2. The photocatalytic performances of as-synthesized samples are evaluated by the degradation of the formaldehyde under ultraviolet light irradiations. The results demonstrate that the as-synthesized mesoporous Ti O2 are anatase with the uniform size about 20-40 nm. The sample is prepared using cetyltrimethyl ammonium bromide(CTAB) as the template with average pore size distribution of 8.12 nm, specific surface area of 68.47 m2/g and pore volume of 0.213 m L/g. The samples show decomposition of formaldehyde 95.8% under ultraviolet light irradiations for 90 min. These results provide a basic experimental process for preparation mesoporous Ti O2, which will posses a broad prospect in terms of the applications in improving indoor air quality.展开更多
基金Supported by the National Key Technology R&D Program (2007BAC20B01)the Fund for Postgraduate of Tarim University (TDZKSS06004)~~
文摘[Objective] This study aimed to solve the mulch plastic film pollution problems in Xinjiang, in order to provide reliable theoretical basis for the research on the degradation mechanism of biodegradable plastic films. [Method] The effect of illumination intensity on the decomposition of decomposable mulching films was investigated through simulating the field condition in laboratory. Regression analysis was employed to fit the processes of film decompositions. [Result] The weight loss ratios of different types of plastic films were closely related with the illumination. There was no sundry produced during the degradation process, but the weight was reduced, indicating that degradation produced gas, thus, ultraviolet rays had destructive effect on mulch plastic films. Different types of plastic films showed significant differences in the degradation speeds, and under the same conditions, the degradation speed of S4# with the induction period of 30 d was the fastest. With the extension of uv illumination time, the degradation became cumulative degradation process. [Conclusion] Under the uv rays, the weight loss ratio and illumination hours is regarded as a positive correlation relationship. The significant inspection shows that the data fitted degradation model can be described by the logistic model of Y = a/（1＋b×e -ct）, and all the parameters show significant differences （P0.01）.
基金Projects(51102026,51272032) supported by the Program for the National Natural Science Foundation of ChinaProject(11A014) supported by the Scientific Research Fund of Hunan Provincial Education DepartmentProject supported by the Aid Program for Science and Technology Innovative Research Team in Higher Educational Instituions of Hunan Province,China
文摘The mesoporous Ti O2 has been synthesized by evaporation induced self assembly(EISA) method. The thermogravimetric/differential scanning calorimetric(TG/DSC), X-ray diffraction(XRD), high-resolution transmission electron microscopy(HR-TEM) and N2 adsorption desorption and adsorption are used to study the effects of the synthesized process condition on the microstructure of the as-synthesized mesoporous Ti O2. The photocatalytic performances of as-synthesized samples are evaluated by the degradation of the formaldehyde under ultraviolet light irradiations. The results demonstrate that the as-synthesized mesoporous Ti O2 are anatase with the uniform size about 20-40 nm. The sample is prepared using cetyltrimethyl ammonium bromide(CTAB) as the template with average pore size distribution of 8.12 nm, specific surface area of 68.47 m2/g and pore volume of 0.213 m L/g. The samples show decomposition of formaldehyde 95.8% under ultraviolet light irradiations for 90 min. These results provide a basic experimental process for preparation mesoporous Ti O2, which will posses a broad prospect in terms of the applications in improving indoor air quality.
