温室气体引起的全球变暖、气候变化等问题已成为国际关注的热点,其中CO_2是重要的温室气体之一,CO_2的监测与控制已经成为各国关注的重点。结合CO_2在1.6μm处的光谱吸收结构,利用加权函数修正的差分吸收光谱技术(weighted function mod...温室气体引起的全球变暖、气候变化等问题已成为国际关注的热点,其中CO_2是重要的温室气体之一,CO_2的监测与控制已经成为各国关注的重点。结合CO_2在1.6μm处的光谱吸收结构,利用加权函数修正的差分吸收光谱技术(weighted function modified difference absorption spectroscopy,WFM-DOAS)研究大气中CO_2垂直柱浓度的反演方法。利用大气辐射传输模型仿真研究了不同参数对加权函数(weighted function,WF)计算灵敏度的影响,分别对观测高度、太阳天顶角、太阳方位角、地表反照率、光谱分辨率等参数对CO_2WF系数的影响进行了详细的计算分析。并以一整天测量的太阳光为例,对仪器的性能、CO_2的垂直柱浓度及干扰气体CH_4及H_2O的垂直柱浓度进行了分析,初步分析得到的反演误差优于1%。展开更多
The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral co...The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral correction technique （MSASC）. The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu（Ⅱ） or Ni（Ⅱ）and AABB. The binding ratio of AABB to CTAB was 1：2.5, and monomeric aggregate, AABB2CTAB5, was formed with an adsorption constant of 5.95×10^5 at 20 ℃ or 2.48×10^5 at 40 ℃. In the ternary complexation, the ratio of AABB：Cu and AABB：Ni were 1：1 and 1：2.5, respectively. Two types of aggregates, Cu2.AABB2·CTAB80 and Ni5.AABB2.CTAB80, were formed.展开更多
文摘The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral correction technique （MSASC）. The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu（Ⅱ） or Ni（Ⅱ）and AABB. The binding ratio of AABB to CTAB was 1：2.5, and monomeric aggregate, AABB2CTAB5, was formed with an adsorption constant of 5.95×10^5 at 20 ℃ or 2.48×10^5 at 40 ℃. In the ternary complexation, the ratio of AABB：Cu and AABB：Ni were 1：1 and 1：2.5, respectively. Two types of aggregates, Cu2.AABB2·CTAB80 and Ni5.AABB2.CTAB80, were formed.
