针对高光谱图像存在的光谱域噪声提出了基于经验模态分解的光谱域滤波方法(emp irical mode decomposi-tion based filter(EMDF)).首先基于光谱曲线二阶导数给出了光谱曲线噪声大小的判定,然后用EMDF方法进行逐像元滤波.在容易引入空间...针对高光谱图像存在的光谱域噪声提出了基于经验模态分解的光谱域滤波方法(emp irical mode decomposi-tion based filter(EMDF)).首先基于光谱曲线二阶导数给出了光谱曲线噪声大小的判定,然后用EMDF方法进行逐像元滤波.在容易引入空间域噪声的光谱区间,以基于光谱导数的Savitzky-Golay滤波方法(derivative based savitz-ky-Golay filter(DSGF))进行替代,这样既抑制了空间域噪声的产生,也取得了较好的光谱域滤波效果.展开更多
Geometry optimization of p-C_(6)H_(4)-connected cyclo[20]carbon(p-C_(6)H_(4)-C_(20))was carried out at M062X/6-311G(d,p)level,three kinds of bond orders(Mayer,Laplacian,and Wiberg),electron-hole distributions,localize...Geometry optimization of p-C_(6)H_(4)-connected cyclo[20]carbon(p-C_(6)H_(4)-C_(20))was carried out at M062X/6-311G(d,p)level,three kinds of bond orders(Mayer,Laplacian,and Wiberg),electron-hole distributions,localized orbital locators(LOL),and infrared(IR)spectrum were also performed at the same level.Based on TD-DFT M062X/6-311G(d,p)method,the first 20 excited states and ultraviolet(UV)spectra of p-C_(6)H_(4)-C_(20) were calculated.Calculation results of π-electron delocalization analyses prove thatπ-electron delocalization of p-C_(6)H_(4)-C_(20) is more likely to occur on shorter C-C bonds rather than longer C-C bonds,and inside/outside of the ring plane rather than above/below the ring plane.Two absorption peaks of p-C_(6)H_(4)-C_(20) locate at about 319 nm and 236 nm,respectively.展开更多
[Objective] The aim was to explore the application of terahertz (THz) technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides (butachlor and ...[Objective] The aim was to explore the application of terahertz (THz) technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides (butachlor and metolachlor) were measured by THz time-domain spectroscopy (THz-TDS) under conditions of room temperature and nitrogen,meanwhile their refractive index and absorption coefficient between 0.2 and 2.2 THz were calculated by using models based on Fresenl equations. [Result] The 2 pesticides both had a series of different characteristic absorption peaks between 0.2 and 2.2 THz,respectively. Their molecular structures were similar,but there were great difference in absorption and refractive index spectrum between them. [Conclusion] THz-TDS technique is feasible to detect pesticide residues,especially there is a greater advantage in identifying the structure of similar substances.展开更多
We measured the water content (0.01% 0.25% w/w) in crude oil emulsions using terahertz time-domain spectroscopy (THz-TDS). To improve the precision and range of the measurements, we used 1 and 10 mm thick quartz c...We measured the water content (0.01% 0.25% w/w) in crude oil emulsions using terahertz time-domain spectroscopy (THz-TDS). To improve the precision and range of the measurements, we used 1 and 10 mm thick quartz cells. The experiments were performed at 20 ℃ and the THz wave was transmitted vertically to the samples and detected on the other side. The experimental results suggest linear relation for the THz absorption coefficient and the water content of the crude oil emulsions in the observed range. The linear dependence facilitates high-precision measurements of the water content of crude oil. This suggests the potential of THz-TDS in determining the water concentration in crude oil and borehole fluid identification.展开更多
In order to deal with the unclear absorption peak caused by the absorption peak overlap of traditional Chinese medicine(TCM)and other mixtures,a method of three unsupervised clustering algorithms as K-means,K-medoids ...In order to deal with the unclear absorption peak caused by the absorption peak overlap of traditional Chinese medicine(TCM)and other mixtures,a method of three unsupervised clustering algorithms as K-means,K-medoids and Fuzzy C-means(FCM)combined with the first derivative characteristics of terahertz absorption spectrum,is proposed to perform the terahertz spectra clustering of Sanchi and other three kinds of TCM compared with their easily-confused products(ECPs).These three unsupervised clustering methods complement the scope of the supervised learning classification method.The first derivative of the spectrum could amplify the difference in the absorption coefficient with different substances,so that the obvious absorption peak can be revealed.Experiments shows that these three clustering algorithms can achieve good results by combining the origin absorption coefficient with its first-order derivative as the characteristic data,and among which K-means does the best with the accuracy of95.32%.Compared with pure absorption coefficient data clustering,the accuracy in this study has been significantly improved,especially for the non-absorption-peak TCM classification.And the accuracy of K-means algorithm is improved by5.38%.Besides,clustering algorithms in this study have strong anti-interference ability to the error data.展开更多
Nowadays, tourism has become an increasingly significant driving force of modern urbanization in China. However, it has caused varieties of problems, such as resource unreasonable utilization, society unfair play, and...Nowadays, tourism has become an increasingly significant driving force of modern urbanization in China. However, it has caused varieties of problems, such as resource unreasonable utilization, society unfair play, and environment pollution, etc. Thus, the establishment of an efficient and sustainable space partition model for tourism urbanization, from the geographical perspective, is highly necessary and urgent. Herein, a new evaluation model of tourist town space, referred to as Tourism Sectorization Opportunity Spectrum(TSOS), is established on the relationships between productionliving-ecology spaces. TSOS is a kind of quantitative evaluation model involving such factors as urban living area, ecological conservation area and the tourism industry. Furthermore, the analysis of quantitative production-living-ecology spatial overlap has been utilized for space division in a tourism urbanization area. This paper, using both the TSOS model and GIS technology, analyzes the spatial restructure of the Mayangxi ecotourism area. Theresult demonstrates that tourism industrial space takes the Shanchong Village as a core which shows a pattern of local regional agglomeration and a fuzzy edge extending along the entire Mayangxi River. The urban living area should be consolidated in the Shili village with the supporting facilities and living space for tourism. In addition, Tianzhu Mountain forest park should be the key environmental protection area. The case study on the Mayangxi ecotourism area verifies that the TSOS model has strong operability. Therefore, TSOS model provides a scientific foundation for the space reconstruction of new urbanization area, and an effective tool for optimizing the space partition of a tourism urbanization area.展开更多
The main features of SST interannual and long term variations in the Western Pacific Warm Pool area were studied by using regression analysis, running t test and spectral analysis methods based on monthly mean SST dat...The main features of SST interannual and long term variations in the Western Pacific Warm Pool area were studied by using regression analysis, running t test and spectral analysis methods based on monthly mean SST data in the Pacific during 1950-1998. The results showed that the SST inter annual and long term variations in the Western Pacific Warm Pool area had evident regional features. There were significant differences in variation range, phase, period, occurrence time of abrupt variation between SST in the eastern area (east of 160°E) and SST in the western area (west of 160°E).展开更多
Spectral index methodology has been widely used in Leaf Area Index(LAI) retrieval at different spatial scales. There are differences in the spectral response of different remote sensors and thus spectral scale effect ...Spectral index methodology has been widely used in Leaf Area Index(LAI) retrieval at different spatial scales. There are differences in the spectral response of different remote sensors and thus spectral scale effect generated during the use of spectral indices to retrieve LAI. In this study, PROSPECT, leaf optical properties model and Scattering by Arbitrarily Inclined Layers(SAIL) model, were used to simulate canopy spectral reflectance with a bandwidth of 5 nm and a Gaussian spectral response function was employed to simulate the spectral data at six bandwidths ranging from 10 to 35 nm. Additionally, for bandwidths from 5 to 35 nm, the correlation between the spectral index and LAI, and the sensitivities of the spectral index to changes in LAI and bandwidth were analyzed. Finally, the reflectance data at six bandwidths ranging from 40 to 65 nm were used to verify the spectral scale effect generated during the use of the spectral index to retrieve LAI. Results indicate that Vegetation Index of the Universal Pattern Decomposition(VIUPD) had the highest accuracy during LAI retrieval. Followed by Normalized Difference Vegetation Index(NDVI), Modified Simple Ratio Indices(MSRI) and Triangle Vegetation Index(TVI), although the coefficient of determination R^2 was higher than 0.96, the retrieved LAI values were less than the actual value and thus lacked validity. Other spectral indices were significantly affected by the spectral scale effect with poor retrieval results. In this study, VIUPD, which exhibited a relatively good correlation and sensitivity to LAI, was less affected by the spectral scale effect and had a relatively good retrieval capability. This conclusion supports a purported feature independent of the sensor of this model and also confirms the great potential of VIUPD for retrieval of physicochemical parameters of vegetation using multi-source remote sensing data.展开更多
In recent decades,materials science has experienced rapid development and posed increasingly high requirements for the characterizations of structures,properties,and performances.Herein,we report on our recent establi...In recent decades,materials science has experienced rapid development and posed increasingly high requirements for the characterizations of structures,properties,and performances.Herein,we report on our recent establishment of a multi-domain(energy,space,time)highresolution platform for integrated spectroscopy and microscopy characterizations,offering an unprecedented way to analyze materials in terms of spectral(energy)and spatial mapping as well as temporal evolution.We present several proof-of-principle results collected on this platform,including in-situ Raman imaging(high-resolution Raman,polarization Raman,low-wavenumber Raman),time-resolved photoluminescence imaging,and photoelectrical performance imaging.It can be envisioned that our newly established platform would be very powerful and effective in the multi-domain high-resolution characterizations of various materials of photoelectrochemical importance in the near future.展开更多
Objective To provide novel spectral domain optical coherence tomography (SD OCT) findings of Vogt-Koyanagi-Harada (VKH) disease as well as new insights into the pathogenesis of this disease. Methods Detailed SD OCT an...Objective To provide novel spectral domain optical coherence tomography (SD OCT) findings of Vogt-Koyanagi-Harada (VKH) disease as well as new insights into the pathogenesis of this disease. Methods Detailed SD OCT and fluorescein angiography (FA) findings of 18 consecutive VKH patients (11 women and 7 men) from December 2007 to April 2009 who were in acute uveitic stage at presentation were reviewed. All the patients had been followed up for at least 6 months with reevaluation(s) of SD OCT performed in 10 patients. Results Intraretinal cysts were found to be located in various layers of the outer retina. In addition to the photoreceptor layer, they could also be found between the outer plexiform layer and the outer nuclear layer, or spanning the external limiting membrane. On FA, intraretinal cysts could be hypofluorescent, normofluorescent, or hyperfluorescent. Some intraretinal cysts had a characteristic FA pattern, in which a small round hypofluorescent area was surrounded by a ring of hyperfluorescence (donut-shaped dye pooling). Subretinal fibrinoid deposit appeared in acute uveitic stage in two severe VKH patients and seemed to develop from subretinal exudates and evolved into typical subretinal fibrosis. Gradual transfiguration/migration and progressive proliferation/pigmentation of the subretinal fibrinoid deposit/subretinal fibrosis was observed in one patient. Conclusions Intraretinal cysts could form in various layers of the outer retina and may result from extension of choroidal inflammation. Subretinal fibrosis may develop from subretinal exudates in VKH patients and may cause substantial visual impairment.展开更多
The parallel spectral-domain optical coherence tomography(PSDOCT) is described for highspeed optical coherence tomography(OCT) without lateral scanning. In this setup, the self-elimination of auto-correlation(AC...The parallel spectral-domain optical coherence tomography(PSDOCT) is described for highspeed optical coherence tomography(OCT) without lateral scanning. In this setup, the self-elimination of auto-correlation(AC) interference algorithm was used for eradicating the AC interference and ghost images. However, when performed in free space OCT, this algorithm still generated a weak DC component. The algorithm was improved by adding the background intensity part to compensate for the mutual interference between object and reference arms. The results demonstrate that the DC component can be eradicated. Compared with conventional QCT and complex Fourier-domain optical coherence to- mography, the advantages of PSDOCT with the improved algorithm in free space are that it has no moving parts to generate consecutive phase shift, the structure of the object can be reconstructed immediately and automatically, and the speed is approximately 16 times faster than those of the other two in the same case.展开更多
文摘针对高光谱图像存在的光谱域噪声提出了基于经验模态分解的光谱域滤波方法(emp irical mode decomposi-tion based filter(EMDF)).首先基于光谱曲线二阶导数给出了光谱曲线噪声大小的判定,然后用EMDF方法进行逐像元滤波.在容易引入空间域噪声的光谱区间,以基于光谱导数的Savitzky-Golay滤波方法(derivative based savitz-ky-Golay filter(DSGF))进行替代,这样既抑制了空间域噪声的产生,也取得了较好的光谱域滤波效果.
文摘Geometry optimization of p-C_(6)H_(4)-connected cyclo[20]carbon(p-C_(6)H_(4)-C_(20))was carried out at M062X/6-311G(d,p)level,three kinds of bond orders(Mayer,Laplacian,and Wiberg),electron-hole distributions,localized orbital locators(LOL),and infrared(IR)spectrum were also performed at the same level.Based on TD-DFT M062X/6-311G(d,p)method,the first 20 excited states and ultraviolet(UV)spectra of p-C_(6)H_(4)-C_(20) were calculated.Calculation results of π-electron delocalization analyses prove thatπ-electron delocalization of p-C_(6)H_(4)-C_(20) is more likely to occur on shorter C-C bonds rather than longer C-C bonds,and inside/outside of the ring plane rather than above/below the ring plane.Two absorption peaks of p-C_(6)H_(4)-C_(20) locate at about 319 nm and 236 nm,respectively.
基金Supported by Special Fund for Scientific Research on Public Welfare by China Quality Monitoring Bureau (200910181)National Natural Science Foundation of China (60902095)~~
文摘[Objective] The aim was to explore the application of terahertz (THz) technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides (butachlor and metolachlor) were measured by THz time-domain spectroscopy (THz-TDS) under conditions of room temperature and nitrogen,meanwhile their refractive index and absorption coefficient between 0.2 and 2.2 THz were calculated by using models based on Fresenl equations. [Result] The 2 pesticides both had a series of different characteristic absorption peaks between 0.2 and 2.2 THz,respectively. Their molecular structures were similar,but there were great difference in absorption and refractive index spectrum between them. [Conclusion] THz-TDS technique is feasible to detect pesticide residues,especially there is a greater advantage in identifying the structure of similar substances.
基金sponsored jointly by the National Key Basic Research Program of China(No.2013CB328706)the Special-funded Program on National Key Scientific Instruments and Equipment Development(No.2012YQ140005)+1 种基金the Beijing National Science Foundation(No.4122064)the Science Foundation of China University of Petroleum(Beijing)(No.QZDX-2010-01 and KYJJ2012-06-27)
文摘We measured the water content (0.01% 0.25% w/w) in crude oil emulsions using terahertz time-domain spectroscopy (THz-TDS). To improve the precision and range of the measurements, we used 1 and 10 mm thick quartz cells. The experiments were performed at 20 ℃ and the THz wave was transmitted vertically to the samples and detected on the other side. The experimental results suggest linear relation for the THz absorption coefficient and the water content of the crude oil emulsions in the observed range. The linear dependence facilitates high-precision measurements of the water content of crude oil. This suggests the potential of THz-TDS in determining the water concentration in crude oil and borehole fluid identification.
基金National Natural Science Foundation of China(No.61675151)
文摘In order to deal with the unclear absorption peak caused by the absorption peak overlap of traditional Chinese medicine(TCM)and other mixtures,a method of three unsupervised clustering algorithms as K-means,K-medoids and Fuzzy C-means(FCM)combined with the first derivative characteristics of terahertz absorption spectrum,is proposed to perform the terahertz spectra clustering of Sanchi and other three kinds of TCM compared with their easily-confused products(ECPs).These three unsupervised clustering methods complement the scope of the supervised learning classification method.The first derivative of the spectrum could amplify the difference in the absorption coefficient with different substances,so that the obvious absorption peak can be revealed.Experiments shows that these three clustering algorithms can achieve good results by combining the origin absorption coefficient with its first-order derivative as the characteristic data,and among which K-means does the best with the accuracy of95.32%.Compared with pure absorption coefficient data clustering,the accuracy in this study has been significantly improved,especially for the non-absorption-peak TCM classification.And the accuracy of K-means algorithm is improved by5.38%.Besides,clustering algorithms in this study have strong anti-interference ability to the error data.
基金supported and funded by the National Natural Science Foundation of China(Grant No.41071110)the State Ethnic Affairs Youth Foundation of China(Grant No.2015-GM073)
文摘Nowadays, tourism has become an increasingly significant driving force of modern urbanization in China. However, it has caused varieties of problems, such as resource unreasonable utilization, society unfair play, and environment pollution, etc. Thus, the establishment of an efficient and sustainable space partition model for tourism urbanization, from the geographical perspective, is highly necessary and urgent. Herein, a new evaluation model of tourist town space, referred to as Tourism Sectorization Opportunity Spectrum(TSOS), is established on the relationships between productionliving-ecology spaces. TSOS is a kind of quantitative evaluation model involving such factors as urban living area, ecological conservation area and the tourism industry. Furthermore, the analysis of quantitative production-living-ecology spatial overlap has been utilized for space division in a tourism urbanization area. This paper, using both the TSOS model and GIS technology, analyzes the spatial restructure of the Mayangxi ecotourism area. Theresult demonstrates that tourism industrial space takes the Shanchong Village as a core which shows a pattern of local regional agglomeration and a fuzzy edge extending along the entire Mayangxi River. The urban living area should be consolidated in the Shili village with the supporting facilities and living space for tourism. In addition, Tianzhu Mountain forest park should be the key environmental protection area. The case study on the Mayangxi ecotourism area verifies that the TSOS model has strong operability. Therefore, TSOS model provides a scientific foundation for the space reconstruction of new urbanization area, and an effective tool for optimizing the space partition of a tourism urbanization area.
文摘The main features of SST interannual and long term variations in the Western Pacific Warm Pool area were studied by using regression analysis, running t test and spectral analysis methods based on monthly mean SST data in the Pacific during 1950-1998. The results showed that the SST inter annual and long term variations in the Western Pacific Warm Pool area had evident regional features. There were significant differences in variation range, phase, period, occurrence time of abrupt variation between SST in the eastern area (east of 160°E) and SST in the western area (west of 160°E).
基金National Natural Science Foundation of China(No.41401002)Jilin Province Science Foundation for Youths(No.20160520077JH)
文摘Spectral index methodology has been widely used in Leaf Area Index(LAI) retrieval at different spatial scales. There are differences in the spectral response of different remote sensors and thus spectral scale effect generated during the use of spectral indices to retrieve LAI. In this study, PROSPECT, leaf optical properties model and Scattering by Arbitrarily Inclined Layers(SAIL) model, were used to simulate canopy spectral reflectance with a bandwidth of 5 nm and a Gaussian spectral response function was employed to simulate the spectral data at six bandwidths ranging from 10 to 35 nm. Additionally, for bandwidths from 5 to 35 nm, the correlation between the spectral index and LAI, and the sensitivities of the spectral index to changes in LAI and bandwidth were analyzed. Finally, the reflectance data at six bandwidths ranging from 40 to 65 nm were used to verify the spectral scale effect generated during the use of the spectral index to retrieve LAI. Results indicate that Vegetation Index of the Universal Pattern Decomposition(VIUPD) had the highest accuracy during LAI retrieval. Followed by Normalized Difference Vegetation Index(NDVI), Modified Simple Ratio Indices(MSRI) and Triangle Vegetation Index(TVI), although the coefficient of determination R^2 was higher than 0.96, the retrieved LAI values were less than the actual value and thus lacked validity. Other spectral indices were significantly affected by the spectral scale effect with poor retrieval results. In this study, VIUPD, which exhibited a relatively good correlation and sensitivity to LAI, was less affected by the spectral scale effect and had a relatively good retrieval capability. This conclusion supports a purported feature independent of the sensor of this model and also confirms the great potential of VIUPD for retrieval of physicochemical parameters of vegetation using multi-source remote sensing data.
基金supported by the National Key Research and Development Program of China(No.2016YFA0200602,No.2017YFA0303500,and No.2018YFA0208702)the National Natural Science Foundation of China(No.21573211,No.21633007,No.21803067,and No.91950207)+1 种基金the Anhui Initiative in Quantum Information Technologies(AHY090200)the USTC-NSRL Joint Funds(UN2018LHJJ).
文摘In recent decades,materials science has experienced rapid development and posed increasingly high requirements for the characterizations of structures,properties,and performances.Herein,we report on our recent establishment of a multi-domain(energy,space,time)highresolution platform for integrated spectroscopy and microscopy characterizations,offering an unprecedented way to analyze materials in terms of spectral(energy)and spatial mapping as well as temporal evolution.We present several proof-of-principle results collected on this platform,including in-situ Raman imaging(high-resolution Raman,polarization Raman,low-wavenumber Raman),time-resolved photoluminescence imaging,and photoelectrical performance imaging.It can be envisioned that our newly established platform would be very powerful and effective in the multi-domain high-resolution characterizations of various materials of photoelectrochemical importance in the near future.
文摘Objective To provide novel spectral domain optical coherence tomography (SD OCT) findings of Vogt-Koyanagi-Harada (VKH) disease as well as new insights into the pathogenesis of this disease. Methods Detailed SD OCT and fluorescein angiography (FA) findings of 18 consecutive VKH patients (11 women and 7 men) from December 2007 to April 2009 who were in acute uveitic stage at presentation were reviewed. All the patients had been followed up for at least 6 months with reevaluation(s) of SD OCT performed in 10 patients. Results Intraretinal cysts were found to be located in various layers of the outer retina. In addition to the photoreceptor layer, they could also be found between the outer plexiform layer and the outer nuclear layer, or spanning the external limiting membrane. On FA, intraretinal cysts could be hypofluorescent, normofluorescent, or hyperfluorescent. Some intraretinal cysts had a characteristic FA pattern, in which a small round hypofluorescent area was surrounded by a ring of hyperfluorescence (donut-shaped dye pooling). Subretinal fibrinoid deposit appeared in acute uveitic stage in two severe VKH patients and seemed to develop from subretinal exudates and evolved into typical subretinal fibrosis. Gradual transfiguration/migration and progressive proliferation/pigmentation of the subretinal fibrinoid deposit/subretinal fibrosis was observed in one patient. Conclusions Intraretinal cysts could form in various layers of the outer retina and may result from extension of choroidal inflammation. Subretinal fibrosis may develop from subretinal exudates in VKH patients and may cause substantial visual impairment.
文摘The parallel spectral-domain optical coherence tomography(PSDOCT) is described for highspeed optical coherence tomography(OCT) without lateral scanning. In this setup, the self-elimination of auto-correlation(AC) interference algorithm was used for eradicating the AC interference and ghost images. However, when performed in free space OCT, this algorithm still generated a weak DC component. The algorithm was improved by adding the background intensity part to compensate for the mutual interference between object and reference arms. The results demonstrate that the DC component can be eradicated. Compared with conventional QCT and complex Fourier-domain optical coherence to- mography, the advantages of PSDOCT with the improved algorithm in free space are that it has no moving parts to generate consecutive phase shift, the structure of the object can be reconstructed immediately and automatically, and the speed is approximately 16 times faster than those of the other two in the same case.