Gas chromatographymass spectrometry (GC-MS) coupled with chemometric resolution upon two- dimensional data was employed to analyze the constituents of essential oils of Angelica sinensis. Constituents in essential oil...Gas chromatographymass spectrometry (GC-MS) coupled with chemometric resolution upon two- dimensional data was employed to analyze the constituents of essential oils of Angelica sinensis. Constituents in essential oils of Angelica sinensis root were identified by GC-MS with the help of subwindow factor analysis (SFA) method resolving two-dimensional original data into mass spectra and chromatograms. 76 of 97 separated constituents in essential oil of Angelica sinensis root were identified and quantified, and they account for about 91.36% of the total content. The results show that ligustilide, butylene phthalide, 2-methoxy-4-vinylphenol, carvacrol, allo-ocimene,2,6,6-trimethylbicyclo-[3,1,1]hept-2-ene are the main constituents in essential oil of Angelica sinensis root.展开更多
Modern opticai theory has shown that the far field or Fraunbofer diffraction equipment is identical to the Fourier spectral analyzer. In the Fourier speetral analyzer the Fourier spectra or the Fraunhofer diffaction p...Modern opticai theory has shown that the far field or Fraunbofer diffraction equipment is identical to the Fourier spectral analyzer. In the Fourier speetral analyzer the Fourier spectra or the Fraunhofer diffaction pattern of a graph is formed on the back focal plane when a laser beam is directed on the graph lying on the front foeal plane ; the Fourier spectra of the graph is also subjected to change during the deformation of the graph. Through analyzing the change of Fourier spectra the deformation of the graph can be obtained. A few years ago,based on the above principles the authors proposed a new technique of strain measurement by laser spectral analysis. Demonstration and discussion will be made in detail in this paper.展开更多
Single-walled carbon nanotubes （SWCNTs） illuminated by white light should appear colored due to resonance Rayleigh scattering. However, true-color imaging of SWCNTs on substrates has not been reported, because of th...Single-walled carbon nanotubes （SWCNTs） illuminated by white light should appear colored due to resonance Rayleigh scattering. However, true-color imaging of SWCNTs on substrates has not been reported, because of the extremely low scattering intensity of SWCNTs and the strong substrate scattering. Here we show that Rayleigh scattering can be greatly enhanced by the interface dipole enhancement effect. Consequently colorful SWCNTs on substrates can be directly imaged under an optical microscope by wide field supercontinuum laser illumination, which facilitates high throughput chirality assignment of individual SWCNTs. This approach, termed ＂Rayleigh imaging microscopy＂, is not restricted to SWCNTs, but widely applicable to a variety of nanomaterials, which enables the colorful nanoworld to be explored under optical microscopes.展开更多
文摘Gas chromatographymass spectrometry (GC-MS) coupled with chemometric resolution upon two- dimensional data was employed to analyze the constituents of essential oils of Angelica sinensis. Constituents in essential oils of Angelica sinensis root were identified by GC-MS with the help of subwindow factor analysis (SFA) method resolving two-dimensional original data into mass spectra and chromatograms. 76 of 97 separated constituents in essential oil of Angelica sinensis root were identified and quantified, and they account for about 91.36% of the total content. The results show that ligustilide, butylene phthalide, 2-methoxy-4-vinylphenol, carvacrol, allo-ocimene,2,6,6-trimethylbicyclo-[3,1,1]hept-2-ene are the main constituents in essential oil of Angelica sinensis root.
文摘Modern opticai theory has shown that the far field or Fraunbofer diffraction equipment is identical to the Fourier spectral analyzer. In the Fourier speetral analyzer the Fourier spectra or the Fraunhofer diffaction pattern of a graph is formed on the back focal plane when a laser beam is directed on the graph lying on the front foeal plane ; the Fourier spectra of the graph is also subjected to change during the deformation of the graph. Through analyzing the change of Fourier spectra the deformation of the graph can be obtained. A few years ago,based on the above principles the authors proposed a new technique of strain measurement by laser spectral analysis. Demonstration and discussion will be made in detail in this paper.
基金The authors would like to thank Prof. Feng Wang, Prof. Xuedong Bai, and Prof. Kaihui Liu for helpful discussions. This work was supported by the National Basic Research Program of China （No. 2012CB932301） and the National Natural Science Foundation of China （Nos. 90921012, 11321091, 51102144, 11274190, and 51102147）.
文摘Single-walled carbon nanotubes （SWCNTs） illuminated by white light should appear colored due to resonance Rayleigh scattering. However, true-color imaging of SWCNTs on substrates has not been reported, because of the extremely low scattering intensity of SWCNTs and the strong substrate scattering. Here we show that Rayleigh scattering can be greatly enhanced by the interface dipole enhancement effect. Consequently colorful SWCNTs on substrates can be directly imaged under an optical microscope by wide field supercontinuum laser illumination, which facilitates high throughput chirality assignment of individual SWCNTs. This approach, termed ＂Rayleigh imaging microscopy＂, is not restricted to SWCNTs, but widely applicable to a variety of nanomaterials, which enables the colorful nanoworld to be explored under optical microscopes.
