Vacuum ultraviolet(VUV)photoionization and photodissociation of methylcyclohexane have been studied utilizing a reflectron time-of-flight mass spectrometer(RTOF-MS)with synchrotron radiation source.Photoionization eff...Vacuum ultraviolet(VUV)photoionization and photodissociation of methylcyclohexane have been studied utilizing a reflectron time-of-flight mass spectrometer(RTOF-MS)with synchrotron radiation source.Photoionization efficiency curves(PIEs)of molecule ion C7H14^+ and fragment ions C7H13^+,C6H11^+,C6H10+,C5H10^+,C5H9^+,C4H8^+,C4H7^+,and C3H5^+ were observed.The ionization energy of methylcyclohexane was measured to be(9.80±0.03)eV,and appearance energies of fragment ions were determined from the PIEs.Optimized structures of transitional states,intermediates and product ions were characterized at the B3LYP/6-31G(d)level and the energies were calculated using G3B3 method.Formation channels of dominating fragment ions were proposed.Intramolecular hydrogen migrations and carbon ring-opening were the foremost processes in fragmentation pathways of methylcyclohexane.展开更多
To enlarge the detection range of traditional fiber-optic spectrometer,two rotating parabolic mirrors were first used in the design of fiber-optic collector for spectrometer,which can extend the detection range of spe...To enlarge the detection range of traditional fiber-optic spectrometer,two rotating parabolic mirrors were first used in the design of fiber-optic collector for spectrometer,which can extend the detection range of spectrometer from centimeter-scale to50m,as a super-low altitude remote sensing detector under passive lighting conditions.According to the performance requirements of fiber-spectrometer for optical collector,this study deduced the calculation formulae of design size of parabolic optical collector applied to different sensitivity spectrometers,different detection targets,different detection ranges and different weathers.Based on the calculation results,the model of fiber-optic collector with a diameter of16mm and a height of7.8mm was designed by ZEMAX.And then,TracePro,a light simulation software,was applied to ray tracing.The simulation results of optical radiation magnification agrees well with theoretical value,and the relative error is less than0.78%.This optical collector can effectively extend the detection range of spectrometer and expand its application fields and scopes.Compared with traditional refractive optical collector,it has several advantages of compact structure,low weight and low cost.展开更多
The fraction of photosynthetically active radiation (FPAR) is a key variable in the assessment of vegetation productivity and land ecosystem carbon cycles. Based on ground-measured corn hyperspectral reflectance and...The fraction of photosynthetically active radiation (FPAR) is a key variable in the assessment of vegetation productivity and land ecosystem carbon cycles. Based on ground-measured corn hyperspectral reflectance and FPAR data over Northeast China, the correlations between corn-canopy FPAR and hyperspectral reflectance were analyzed, and the FPAR estimation performances using vegetation index (VI) and neural network (NN) methods with different two-band-combination hyperspectral reflectance were investigated. The results indicated that the corn-canopy FPAR retained almost a constant value in an entire day. The negative correlations between FPAR and visible and shortwave infrared reflectance (SWIR) bands are stronger than the positive correlations between FPAR and near-infrared band re- flectance (NIR). For the six VIs, the normalized difference vegetation index (NDVI) and simple ratio (SR) performed best for estimating corn FPAR (the maximum R2 of 0.8849 and 0.8852, respectively). However, the NN method esti- mated results (the maximum Rz is 0.9417) were obviously better than all of the VIs. For NN method, the two-band combinations showing the best corn FPAR estimation performances were from the NIR and visible bands; for VIs, however, they were from the SWIR and NIR bands. As for both the methods, the SWIR band performed exceptionally well for corn FPAR estimation. This may be attributable to the fact that the reflectance of the SWIR band were strongly controlled by leaf water content, which is a key component of corn photosynthesis and greatly affects the absorption of photosynthetically active radiation (APAR), and makes further impact on corn-canopy FPAR.展开更多
The development of cleaning optics and deposition-mitigating techniques is a key factor in the construction and operation of optical diagnostics in ITER. The cleaning of optical surface by pulsed radiation from a fibe...The development of cleaning optics and deposition-mitigating techniques is a key factor in the construction and operation of optical diagnostics in ITER. The cleaning of optical surface by pulsed radiation from a fiber laser is an effective method that can recover optical properties of the mirror surface. The possibility of cleaning metallic mirrors from films with complex composition by pulsed radiation from a fiber laser has been experimentally researched. It has been shown that the high initial reflection characteristics of optical elements can be recovered by choosing regimes of radiation effect on the deposited surface. Efficient cleaning is ensured by radiation with the power density of less than 107 W/cm2. At this relatively low power density, pollutions are removed in a solid phase and the thermal effect on the mirror is insignificant. Preliminary experiments of the metal mirrors cleaning by fiber laser radiation have demonstrated the possibility of hardware implementation techniques.展开更多
In this letter,a theoretical model of radiation-balanced double clad fiber laser is presented.The characteristic of the laser with Yb doped double clad fiber is analyzed numerically.It is concluded that high output la...In this letter,a theoretical model of radiation-balanced double clad fiber laser is presented.The characteristic of the laser with Yb doped double clad fiber is analyzed numerically.It is concluded that high output laser power can be obtained by selecting output coupling mirror with lower reflectivity,improving Yb doped concentration and choosing fiber length. This result can help us to design radiation balanced fiber laser.展开更多
基金supported by the National Natural Science Foundation of China(No.91544105,No.41275127,No.U1532137 and No.11575178)。
文摘Vacuum ultraviolet(VUV)photoionization and photodissociation of methylcyclohexane have been studied utilizing a reflectron time-of-flight mass spectrometer(RTOF-MS)with synchrotron radiation source.Photoionization efficiency curves(PIEs)of molecule ion C7H14^+ and fragment ions C7H13^+,C6H11^+,C6H10+,C5H10^+,C5H9^+,C4H8^+,C4H7^+,and C3H5^+ were observed.The ionization energy of methylcyclohexane was measured to be(9.80±0.03)eV,and appearance energies of fragment ions were determined from the PIEs.Optimized structures of transitional states,intermediates and product ions were characterized at the B3LYP/6-31G(d)level and the energies were calculated using G3B3 method.Formation channels of dominating fragment ions were proposed.Intramolecular hydrogen migrations and carbon ring-opening were the foremost processes in fragmentation pathways of methylcyclohexane.
基金National Natural Science Foundation of China(No.61376052)State Key Laboratory Program(No.SKT1507)
文摘To enlarge the detection range of traditional fiber-optic spectrometer,two rotating parabolic mirrors were first used in the design of fiber-optic collector for spectrometer,which can extend the detection range of spectrometer from centimeter-scale to50m,as a super-low altitude remote sensing detector under passive lighting conditions.According to the performance requirements of fiber-spectrometer for optical collector,this study deduced the calculation formulae of design size of parabolic optical collector applied to different sensitivity spectrometers,different detection targets,different detection ranges and different weathers.Based on the calculation results,the model of fiber-optic collector with a diameter of16mm and a height of7.8mm was designed by ZEMAX.And then,TracePro,a light simulation software,was applied to ray tracing.The simulation results of optical radiation magnification agrees well with theoretical value,and the relative error is less than0.78%.This optical collector can effectively extend the detection range of spectrometer and expand its application fields and scopes.Compared with traditional refractive optical collector,it has several advantages of compact structure,low weight and low cost.
基金Under the auspices of National Key Research Program of Global Change Research (No.2010CB951302)National Natural Science Fundation of China (No.40771146)China Postdoctoral Science Foundation Funded Project (No.07Z7601MZ1)
文摘The fraction of photosynthetically active radiation (FPAR) is a key variable in the assessment of vegetation productivity and land ecosystem carbon cycles. Based on ground-measured corn hyperspectral reflectance and FPAR data over Northeast China, the correlations between corn-canopy FPAR and hyperspectral reflectance were analyzed, and the FPAR estimation performances using vegetation index (VI) and neural network (NN) methods with different two-band-combination hyperspectral reflectance were investigated. The results indicated that the corn-canopy FPAR retained almost a constant value in an entire day. The negative correlations between FPAR and visible and shortwave infrared reflectance (SWIR) bands are stronger than the positive correlations between FPAR and near-infrared band re- flectance (NIR). For the six VIs, the normalized difference vegetation index (NDVI) and simple ratio (SR) performed best for estimating corn FPAR (the maximum R2 of 0.8849 and 0.8852, respectively). However, the NN method esti- mated results (the maximum Rz is 0.9417) were obviously better than all of the VIs. For NN method, the two-band combinations showing the best corn FPAR estimation performances were from the NIR and visible bands; for VIs, however, they were from the SWIR and NIR bands. As for both the methods, the SWIR band performed exceptionally well for corn FPAR estimation. This may be attributable to the fact that the reflectance of the SWIR band were strongly controlled by leaf water content, which is a key component of corn photosynthesis and greatly affects the absorption of photosynthetically active radiation (APAR), and makes further impact on corn-canopy FPAR.
文摘The development of cleaning optics and deposition-mitigating techniques is a key factor in the construction and operation of optical diagnostics in ITER. The cleaning of optical surface by pulsed radiation from a fiber laser is an effective method that can recover optical properties of the mirror surface. The possibility of cleaning metallic mirrors from films with complex composition by pulsed radiation from a fiber laser has been experimentally researched. It has been shown that the high initial reflection characteristics of optical elements can be recovered by choosing regimes of radiation effect on the deposited surface. Efficient cleaning is ensured by radiation with the power density of less than 107 W/cm2. At this relatively low power density, pollutions are removed in a solid phase and the thermal effect on the mirror is insignificant. Preliminary experiments of the metal mirrors cleaning by fiber laser radiation have demonstrated the possibility of hardware implementation techniques.
基金This project was supported by Foundation of China Academy ofEngineering Physics under Grant NO.2004R0205 .
文摘In this letter,a theoretical model of radiation-balanced double clad fiber laser is presented.The characteristic of the laser with Yb doped double clad fiber is analyzed numerically.It is concluded that high output laser power can be obtained by selecting output coupling mirror with lower reflectivity,improving Yb doped concentration and choosing fiber length. This result can help us to design radiation balanced fiber laser.