Methanol oxidation reaction (MOR) at Pt and Pt electrode surface deposited with various amounts of Ru (denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML) in 0.1 mol/L HClO4+0.5 mol/L MeOH has been ...Methanol oxidation reaction (MOR) at Pt and Pt electrode surface deposited with various amounts of Ru (denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML) in 0.1 mol/L HClO4+0.5 mol/L MeOH has been studied under potentiostatic conditions by in situ FTIR spectroscopy in attenuated-total-reflection con guration and di erential electro-chemical mass spectrometry under controlled flow conditions. Results reveal that (i) CO is the only methanol-related adsorbate observed by IR spectroscopy at all the Pt and PtRu electrodes examined at potentials from 0.3 V to 0.6 V (vs. RHE); (ii) at Pt0.56Ru0.44, two IR bands, one from CO adsorbed at Ru islands and the other from COL at Pt substrate are detected, while at other electrodes, only a single band for COL adsorbed at Pt is observed; (iii) MOR activity decreases in the order of Pt0.73Ru0.27〉Pt0.56Ru0.44〉Pt0.83Ru0.17〉Pt; (iv) at 0.5 V, MOR at Pt0.73Ru0.27 reaches a current e ciency of 50% for CO2 production, the turn-over frequency from CH3OH to CO2 is ca. 0.1 molecule/(site sec). Suggestions for further improving of PtRu catalysts for MOR are provided.展开更多
Global Positioning System technique is widely used to monitor the deformations of all kinds of buildings and constructions. According to the characteristics of the high precise GPS deformation monitoring, the theory a...Global Positioning System technique is widely used to monitor the deformations of all kinds of buildings and constructions. According to the characteristics of the high precise GPS deformation monitoring, the theory and practice of the SSDM (Similar Single-Difference Methodology) for GPS deformation monitoring are introduced synthetically from the background, the essential mathematic model,the error sources and control measures, the monitoring schemes and the software development. Some arguments are also given in the form of reference literatures. Based on the first period observation results of the GPS monitor network, SSDM solves the monitoring points' deformation values at a single epoch from carder phases directly, without needing to solve baseline vectors and network adjustment. The SSDM avoids the troublesome problem of detecting and repairing cycle slips, and can be used in static and dynamic deformation monitoring. In the SSDM, the unknown parameters have no relation to the numbers of satellites. If the number of synchronous satellites between stations is not less than two, the monitoring point's deformation information can be solved easily.展开更多
Based on a coupled ocean-atmosphere model, the response of the Indian Ocean Dipole (IOD) mode to global warming is investigated with a six member ensemble of simulations for the period 1850-2100. The model can simulat...Based on a coupled ocean-atmosphere model, the response of the Indian Ocean Dipole (IOD) mode to global warming is investigated with a six member ensemble of simulations for the period 1850-2100. The model can simulate the IOD features rea-listically, including the east-west dipole pattern and the phase locking in boreal autumn. The ensemble analysis suppresses internal variability and isolates the radiative forced response. In response to increasing greenhouse gases, a weakening of the Walker circula-tion leads to the easterly wind anomalies in the equatorial Indian Ocean and the shoaling thermocline in the eastern equatorial Indian Ocean (EEIO), and sea surface temperature and precipitation changes show an IOD-like pattern in the equatorial Indian Ocean. Al-though the thermocline feedback intensifies with shoaling, the interannual variability of the IOD mode surprisingly weakens under global warming. The zonal wind feedback of IOD is found to weaken as well, due to decreased precipitation in the EEIO. Therefore, the atmospheric feedback decreases much more than the oceanic feedback increases, causing the decreased IOD variance in this model.展开更多
As one of the most severe typhoons in the year 2005,Typhoon Longwang is chosen as a case study in this article.Throughout its life,two surveillance flights are carried out on it.Different from previous studies,GPS(glo...As one of the most severe typhoons in the year 2005,Typhoon Longwang is chosen as a case study in this article.Throughout its life,two surveillance flights are carried out on it.Different from previous studies,GPS(global positioning system)Dropwinsonde data collected from the Dropwinsonde Observations for Typhoon Surveillance near the Taiwan Region is chosen to present the thermodynamic and kinetic structure at its two different stages of development.This study suggests that not only kinetic structure but also thermodynamic structure of Longwang are more robust in the second surveillance than the first surveillance,with stronger and larger circulation and a warmer core.Further research shows that the environmental vertical wind shear mainly contributes to the asymmetric structure of the typhoon.The strong vertical wind shear not only results in the distinct asymmetric structure,but also restrains the development of the typhoon.展开更多
ABSTRACT The multipath has long been considered a major error source in GPS applications .The characteristics 0f the GPS signal multipath effects are analyzed. based on which an experiment that considers the characte...ABSTRACT The multipath has long been considered a major error source in GPS applications .The characteristics 0f the GPS signal multipath effects are analyzed. based on which an experiment that considers the characteristics of dynamic deformation monitoring has been carried out. The solution results of observation data in two successive days are processed by a method,which combines the wavelet filtering and the differential correction betweentwo successive days. The research demonstrates that the multipath errors have stronger repeatability on successive days;after significantly mitigating the influence of multipath effects,the accuracy of three-dimensional positioning for GPS dynamic deformation monitoring can attain the mm level,an obvious accuracy improving particularly invertical component.The characteristics of GPS signal multipath,th eexperimental scheme and the qualitative and quantitative analysis of results are detailed.展开更多
Resonance due to critical slope makes the internal wave generation more effectively than that due to supercritical or subcritical slopes(Zhang et al., 2008). Submarine ridges make a greater contribution to ocean mixin...Resonance due to critical slope makes the internal wave generation more effectively than that due to supercritical or subcritical slopes(Zhang et al., 2008). Submarine ridges make a greater contribution to ocean mixing than continental margins in global oceans(Müller, 1977; Bell, 1975; Baines, 1982; Morozov, 1995). In this paper, internal wave generation driven by tidal flow over critical topography is examined in laboratory using Particle Image Velocimetry(PIV) and synthetic schlieren methods in synchrony. Non-tidal baroclinic velocities and vertical isopycnal displacements are observed in three representative regions, i.e., critical, outward-propagating, and reflection regions. Temporal and spatial distributions of internal wave rays are analyzed using the time variations of baroclinic velocities and vertical isopycnal displacement, and the results are consistent with those by the linear internal wave theory. Besides, the width of wave beam changes with the outward propagation of internal waves. Finally, through monitoring the uniformly-spaced 14 vertical profiles in the x-z plane, the internal wave fields of density and velocity fields are constructed. Thus, available potential energy, kinetic energy and energy fluxes are determined quantitatively. The distributions of baroclinic energy and energy fluxes are confined along the internal wave rays. The total depth averaged energy and energy flux of vertical profiles away from a ridge are both larger than those near the ridge.展开更多
Using GPS observation data for the middle segment of the Fenwei seismic zone during the time period of 1996 ~ 2001, the velocity field of crustal movement is calculated. Thus, the vectors of relative horizontal movem...Using GPS observation data for the middle segment of the Fenwei seismic zone during the time period of 1996 ~ 2001, the velocity field of crustal movement is calculated. Thus, the vectors of relative horizontal movement between measuring points in the region are also obtained. Adopting a deformation model of homogeneous elastic body, the principal strain rate parameters of deformation units are calculated. A method is introduced to calculate the rate of seismic moment accumulation due to crustal deformation. The problems of using this rate to analyze the tendency of seismicity in the zone, and to estimate the recurrence interval of large earthquakes in the potential seismic source areas(PSSA) are discussed. The results show that the rate of seismic moment accumulation in the middle segment of the Fenwei zone is 4.22 x 1017 Nm/a, which is much higher than the average release rate of seismic moment in the current activity period. This means that the belt is now in a stage of seismic strain accumulation and that the seismicity would become stronger in the future than now. The results of estimation of the recurrence interval of large earthquakes in the Dingxiang and Huozhou PSSA are close to the results obtained from studying active faults. This implies that the use of the proposed estimation method is worthy of further investigation. In particular, it is of greater practical significance for those regions that have shorter history of earthquake records or lower degree of active structure study.展开更多
The Zhangjiakou-Bohai Sea fault zone located in the northern part of the North China region is a seismotectonic zone controlling the present-day strong earthquake activities. Under the effect of regional principal com...The Zhangjiakou-Bohai Sea fault zone located in the northern part of the North China region is a seismotectonic zone controlling the present-day strong earthquake activities. Under the effect of regional principal compressive stress with the direction of NEE-SWW, a series of NE-trending active tectonic zones have developed, which form a group of conjugated shear fracturing systems and control the occurrence of the present-day strong earthquakes. The feature of crustal deformation around this fault zone is studied in the paper. The long-term crustal deformation pattern from GPS measurements exhibits a relatively complete left-lateral strike-slip movement along the active fault zone. However, studies on crustal deformation by stages indicate that a series of NE-trending large-scale anomalous gradient zones have appeared along the Zhangjiakou-Bohai Sea fault zone before moderately strong earthquakes. They are represented respectively by the activities of the Tangshan-Hejian, the Sanhe-Laishui and the Yanhuai-Shanxi seismotectonic zones. This may indicate the occurrence of med-term precursors to moderately strong earthquakes along Zhangjiakou-Bohai Sea zone. The results in the paper show that the crustal deformation pattern before strong earthquake reveals the information of strain status in the deep seismogenic zone, while the chaotic pattern after the occurrence of strong earthquake represents the adjustment of the covering strata.展开更多
The height changes of tide gauges directly influence sea level observation. For research of sea level variation in large region or globe, the land vertical displacement must be considered. Two sessions of GPS and abso...The height changes of tide gauges directly influence sea level observation. For research of sea level variation in large region or globe, the land vertical displacement must be considered. Two sessions of GPS and absolute gravity observations in 2001 and 2003 are used to determine the horizontal and vertical motion of China coast in ITRF2000 and Eurasia frame. The difference between results of continuous observation and periodic observation is discussed.展开更多
In order to achieve high precision measurement of inductance in a wide frequency range,a method of inductance measurement based on double-excitation auto-balancing bridge is proposed.In this method,the direct digital ...In order to achieve high precision measurement of inductance in a wide frequency range,a method of inductance measurement based on double-excitation auto-balancing bridge is proposed.In this method,the direct digital synthesizer(DDS)as signal generator is used as the bridge excitation source,and the bridge is automatically balanced by adjusting and measuring the voltage ratio.Using standard resistors,the system can achieve high precision measurement of four-terminal pair inductors in the frequency range of 100Hz-100kHz.Aiming at the low efficiency of bridge balancing,an iterative balancing algorithm based on the steepest descent method is proposed.In order to suppress the interference caused by the initial phase change and non-integer periodic sampling,the high-precision measurement of the complex impedance of inductance is realized based on the all-phase fast Fourier transform(apFFT).Finally,the corresponding measurement system is built and the inductance measurement experiment is carried out.The experimental results show that the relative error of the system for inductance measurement can be as low as 0.009%,and the optimal relative measurement uncertainty of the system can reach 9.89×10^(-4)compared with 5×10^(-5)of commercial impedance analyzer.展开更多
A continuous online in situ attenuated total reflection Fourier-transform infrared(ATR-FTIR)spectroscopic technique was used to investigate the adsorption and desorption kinetics of heptyl xanthate(KHX)on the surface ...A continuous online in situ attenuated total reflection Fourier-transform infrared(ATR-FTIR)spectroscopic technique was used to investigate the adsorption and desorption kinetics of heptyl xanthate(KHX)on the surface of ZnO and Cu(Ⅱ)activated ZnO.The results showed that Cu(Ⅱ)facilitated the xanthate adsorption process on the surface,and led to the formation of cuprous xanthate(CuX),dixanthogen(X_(2))and xanthate aggregates.The adsorption of xanthate on the surface of ZnO and Cu(Ⅱ)activated ZnO was found to both follow the pseudo-first-order kinetic model.When the NaOH solution was used as a desorption agent,the adsorbed xanthate can largely be removed due to the competition between OH^(−)and HX−.However,for Cu(Ⅱ)activated ZnO,the peak intensities at 1197 and 1082 cm^(−1) had no obvious weakening,and the absorption intensities at 1261 and 1026 cm^(−1) increased in the first 5 min,indicating an ion-exchange reaction between OH^(−)and surface zinc bonded xanthate HX−and the reorganization of adsorbed xanthate.展开更多
Measurements of non-tidal variations of gravity (Ag), which were obtained from 1992 to 2012 at the Talaya seismic station (located in the south-western part of the Baikal region), are interpreted together with GPS...Measurements of non-tidal variations of gravity (Ag), which were obtained from 1992 to 2012 at the Talaya seismic station (located in the south-western part of the Baikal region), are interpreted together with GPS (Global Position System) observation data, which were obtained from 2000 to 2013 at the same station. An absolute gravimeter was used for gravity observation. The strongest precision requirements concern tidal gravity prediction. It is the reason why we investigated tidal effect by LCR (LaCoste & Romberg) gravimeter from 1996 to 1997 at the same station. We use tested tidal model for correction of gravity change. The linear component of gravity variations corresponds to changes in the elevation of the site. The correlation coefficient is close to the normal value of the vertical gradient of gravity. At this site, coseismic gravity variations at the time of the Kultuk earthquake (August 27, 2008, Mw = 6.5) were caused by a combined effect of the change of the site's elevation and deformation of the crust. Our estimations of the coseismic effects are consistent with results obtained by modeling based on the available seismic data.展开更多
Using GPS observations of horizontal movement from 2001 to 2003 and the cross-fault mobile short-levelling data of 1988~2003, and with the aid of the improved negative dislocation model and the time-varying curve of ...Using GPS observations of horizontal movement from 2001 to 2003 and the cross-fault mobile short-levelling data of 1988~2003, and with the aid of the improved negative dislocation model and the time-varying curve of strain intensity ratio of fault deformation, the regional tectonic deformation background and medium- and short-term precursors related to the preparation of the Minle-Shandan earthquakes of M S6.1 and M S5.8 on October 25, 2003 are investigated. The results reveal that, under the background of the wide-range deformation adjustment, short-term relaxation and recovery caused by the Kunlun Mountains earthquake of M S8.1, the hypocenters of the earthquakes are located on the north edge of the shear stress enhancement zone between the compressional locked segments of block boundary fault, a place which may represent an accelerated strain accumulation. An obvious anomaly of strain intensity ratio appeared in short-levelling measurements crossing over the fault at the Shihuiyaokou site, the closest to the epicenters, 3 months before the occurrence of the earthquakes. In addition, the variation in number of anomalies from 10-odd days to months before the earthquakes in the entire monitoring area and the anomaly concentration and local enhancement relative to near source in the 3 months before the earthquakes are regarded to be precursors to the two events.展开更多
Construction progress of long-span bridge is complicated and the quality control is strict. Any disadvantage during construction may potentially affect the internal forces and deck alignments after it is open to traff...Construction progress of long-span bridge is complicated and the quality control is strict. Any disadvantage during construction may potentially affect the internal forces and deck alignments after it is open to traffic. To exactly evaluate the periodic alignments, internal forces and safety, geometrical and physical monitoring are needed during construction. This study aims at the requirement of dynamic geometric monitoring during Sutong Bridge construction, and introduces the realization and observing schemes of the self-developed GPS real-time dynamic geometrical deformation monitoring system. Affected by wind load and construction circumstance, GPS (global positioning system) monitoring signal contains a variety of noise. And the useful signal can be extracted from the signal after de-noising the noises. A de-noising method based on EMD (empirical mode decomposition) model is introduced here to process the bridge dynamic monitoring data, and with the wavelet threshold de-noising method are compared. The result shows that the EMD method has good adaptability, is free from the choice of wavelet bases and the number of decomposition layer. The method is an effective de-noising method for dynamic deformation monitoring to large-span bridges.展开更多
Carbonate deposition is a main inorganic carbon sink in lakes, which varies depending on climate change and internal lake dynamics. Research on the relationship between lake carbonate and climate will help to understa...Carbonate deposition is a main inorganic carbon sink in lakes, which varies depending on climate change and internal lake dynamics. Research on the relationship between lake carbonate and climate will help to understand mechanisms of carbon cycle in lacustrine systems. The approach of this study is to explicitly link carbonate formation with Holocene long-term climate change and lake evolution in a paleo-lake (Zhuye Lake), which is a terminal lake of a typical inland drainage basin in arid China. This paper presents analysis on grain-size, carbonate content and mineralogical composition of sediment samples from different locations of Zhuye Lake. The results show that calcite and aragonite are two main components for the lake carbonate, and the carbonate enrichment is associated with lake expansion during the Late Glacial and early to middle Holocene. Holocene lake expansion in arid regions of China is usually connected with high basin-wide precipitation that can strengthen the basin-wide surface carbonate accumulation in the terminal lake. For this reason, Zhuye Lake plays a role of carbon sinks during the wet periods of the Holocene.展开更多
The importance of water vapor in research of global climate change and weather forecast cannot be over emphasized; therefore substantial efforts have been made in exploring the optimal methods to measure water vapor. ...The importance of water vapor in research of global climate change and weather forecast cannot be over emphasized; therefore substantial efforts have been made in exploring the optimal methods to measure water vapor. It is well-established that with a conversion factor, zenith wet delays can be mapped onto precipitable water vapor (PWV). However, the determination of the exact conversion factor depends heavily on the accurate calculation of a key variable, weighted mean temperature of the trop- osphere (Tin). AS a critical parameter in Global Positioning System (GPS) meteorology, Tm has recently been modeled into a global grid known as GWMT. The GWMT model only requires the location and the day of year to calculate Tm. Despite the advantages that the GWMT model offers, anomalies still exist in oceanic areas due to low sampling resolution. In this study, we refine the GWMT model by incorporating the global Tm grid from Global Geodetic Observing System (GGOS) and obtain an improved model, GWMT-G. The results indicate that the GWMT-G model successfully addresses the anomaly in oceanic areas in the GWMT model and significantly improves the accuracy of Tm in other regions.展开更多
文摘Methanol oxidation reaction (MOR) at Pt and Pt electrode surface deposited with various amounts of Ru (denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML) in 0.1 mol/L HClO4+0.5 mol/L MeOH has been studied under potentiostatic conditions by in situ FTIR spectroscopy in attenuated-total-reflection con guration and di erential electro-chemical mass spectrometry under controlled flow conditions. Results reveal that (i) CO is the only methanol-related adsorbate observed by IR spectroscopy at all the Pt and PtRu electrodes examined at potentials from 0.3 V to 0.6 V (vs. RHE); (ii) at Pt0.56Ru0.44, two IR bands, one from CO adsorbed at Ru islands and the other from COL at Pt substrate are detected, while at other electrodes, only a single band for COL adsorbed at Pt is observed; (iii) MOR activity decreases in the order of Pt0.73Ru0.27〉Pt0.56Ru0.44〉Pt0.83Ru0.17〉Pt; (iv) at 0.5 V, MOR at Pt0.73Ru0.27 reaches a current e ciency of 50% for CO2 production, the turn-over frequency from CH3OH to CO2 is ca. 0.1 molecule/(site sec). Suggestions for further improving of PtRu catalysts for MOR are provided.
基金Projects 2003031709 supported by National Land and Resource Bureau Science and Technology Foundation of China and 2004KJ113 by Natural ScienceResearch Project of Education Bureau of Anhui Province
文摘Global Positioning System technique is widely used to monitor the deformations of all kinds of buildings and constructions. According to the characteristics of the high precise GPS deformation monitoring, the theory and practice of the SSDM (Similar Single-Difference Methodology) for GPS deformation monitoring are introduced synthetically from the background, the essential mathematic model,the error sources and control measures, the monitoring schemes and the software development. Some arguments are also given in the form of reference literatures. Based on the first period observation results of the GPS monitor network, SSDM solves the monitoring points' deformation values at a single epoch from carder phases directly, without needing to solve baseline vectors and network adjustment. The SSDM avoids the troublesome problem of detecting and repairing cycle slips, and can be used in static and dynamic deformation monitoring. In the SSDM, the unknown parameters have no relation to the numbers of satellites. If the number of synchronous satellites between stations is not less than two, the monitoring point's deformation information can be solved easily.
基金supported by the National Basic Research Program of China(2012CB955603)the Natural Science Foundation of China(41106010,41176006)+1 种基金the 111 Project(B07036)the Qianren Program
文摘Based on a coupled ocean-atmosphere model, the response of the Indian Ocean Dipole (IOD) mode to global warming is investigated with a six member ensemble of simulations for the period 1850-2100. The model can simulate the IOD features rea-listically, including the east-west dipole pattern and the phase locking in boreal autumn. The ensemble analysis suppresses internal variability and isolates the radiative forced response. In response to increasing greenhouse gases, a weakening of the Walker circula-tion leads to the easterly wind anomalies in the equatorial Indian Ocean and the shoaling thermocline in the eastern equatorial Indian Ocean (EEIO), and sea surface temperature and precipitation changes show an IOD-like pattern in the equatorial Indian Ocean. Al-though the thermocline feedback intensifies with shoaling, the interannual variability of the IOD mode surprisingly weakens under global warming. The zonal wind feedback of IOD is found to weaken as well, due to decreased precipitation in the EEIO. Therefore, the atmospheric feedback decreases much more than the oceanic feedback increases, causing the decreased IOD variance in this model.
基金project of the National Science Foundation of China(40830958,40905020)project of National Basic Research Program of China(2009CB421502)+1 种基金project of the Special Scientific Research for Public Interest(GYHY201006007)project of the Specialized Research Fund for the Doctoral Program of Higher Education of China(20090091120038)
文摘As one of the most severe typhoons in the year 2005,Typhoon Longwang is chosen as a case study in this article.Throughout its life,two surveillance flights are carried out on it.Different from previous studies,GPS(global positioning system)Dropwinsonde data collected from the Dropwinsonde Observations for Typhoon Surveillance near the Taiwan Region is chosen to present the thermodynamic and kinetic structure at its two different stages of development.This study suggests that not only kinetic structure but also thermodynamic structure of Longwang are more robust in the second surveillance than the first surveillance,with stronger and larger circulation and a warmer core.Further research shows that the environmental vertical wind shear mainly contributes to the asymmetric structure of the typhoon.The strong vertical wind shear not only results in the distinct asymmetric structure,but also restrains the development of the typhoon.
文摘ABSTRACT The multipath has long been considered a major error source in GPS applications .The characteristics 0f the GPS signal multipath effects are analyzed. based on which an experiment that considers the characteristics of dynamic deformation monitoring has been carried out. The solution results of observation data in two successive days are processed by a method,which combines the wavelet filtering and the differential correction betweentwo successive days. The research demonstrates that the multipath errors have stronger repeatability on successive days;after significantly mitigating the influence of multipath effects,the accuracy of three-dimensional positioning for GPS dynamic deformation monitoring can attain the mm level,an obvious accuracy improving particularly invertical component.The characteristics of GPS signal multipath,th eexperimental scheme and the qualitative and quantitative analysis of results are detailed.
基金supported by the National Natural Science Foundation of China (Nos. 40906001 and 40906099)National 863 High-Tech Program (No. 2008AA09A402)Chinese National Science & Technology Supporting Program (No. 2011BAC03B02-03-02)
文摘Resonance due to critical slope makes the internal wave generation more effectively than that due to supercritical or subcritical slopes(Zhang et al., 2008). Submarine ridges make a greater contribution to ocean mixing than continental margins in global oceans(Müller, 1977; Bell, 1975; Baines, 1982; Morozov, 1995). In this paper, internal wave generation driven by tidal flow over critical topography is examined in laboratory using Particle Image Velocimetry(PIV) and synthetic schlieren methods in synchrony. Non-tidal baroclinic velocities and vertical isopycnal displacements are observed in three representative regions, i.e., critical, outward-propagating, and reflection regions. Temporal and spatial distributions of internal wave rays are analyzed using the time variations of baroclinic velocities and vertical isopycnal displacement, and the results are consistent with those by the linear internal wave theory. Besides, the width of wave beam changes with the outward propagation of internal waves. Finally, through monitoring the uniformly-spaced 14 vertical profiles in the x-z plane, the internal wave fields of density and velocity fields are constructed. Thus, available potential energy, kinetic energy and energy fluxes are determined quantitatively. The distributions of baroclinic energy and energy fluxes are confined along the internal wave rays. The total depth averaged energy and energy flux of vertical profiles away from a ridge are both larger than those near the ridge.
文摘Using GPS observation data for the middle segment of the Fenwei seismic zone during the time period of 1996 ~ 2001, the velocity field of crustal movement is calculated. Thus, the vectors of relative horizontal movement between measuring points in the region are also obtained. Adopting a deformation model of homogeneous elastic body, the principal strain rate parameters of deformation units are calculated. A method is introduced to calculate the rate of seismic moment accumulation due to crustal deformation. The problems of using this rate to analyze the tendency of seismicity in the zone, and to estimate the recurrence interval of large earthquakes in the potential seismic source areas(PSSA) are discussed. The results show that the rate of seismic moment accumulation in the middle segment of the Fenwei zone is 4.22 x 1017 Nm/a, which is much higher than the average release rate of seismic moment in the current activity period. This means that the belt is now in a stage of seismic strain accumulation and that the seismicity would become stronger in the future than now. The results of estimation of the recurrence interval of large earthquakes in the Dingxiang and Huozhou PSSA are close to the results obtained from studying active faults. This implies that the use of the proposed estimation method is worthy of further investigation. In particular, it is of greater practical significance for those regions that have shorter history of earthquake records or lower degree of active structure study.
文摘The Zhangjiakou-Bohai Sea fault zone located in the northern part of the North China region is a seismotectonic zone controlling the present-day strong earthquake activities. Under the effect of regional principal compressive stress with the direction of NEE-SWW, a series of NE-trending active tectonic zones have developed, which form a group of conjugated shear fracturing systems and control the occurrence of the present-day strong earthquakes. The feature of crustal deformation around this fault zone is studied in the paper. The long-term crustal deformation pattern from GPS measurements exhibits a relatively complete left-lateral strike-slip movement along the active fault zone. However, studies on crustal deformation by stages indicate that a series of NE-trending large-scale anomalous gradient zones have appeared along the Zhangjiakou-Bohai Sea fault zone before moderately strong earthquakes. They are represented respectively by the activities of the Tangshan-Hejian, the Sanhe-Laishui and the Yanhuai-Shanxi seismotectonic zones. This may indicate the occurrence of med-term precursors to moderately strong earthquakes along Zhangjiakou-Bohai Sea zone. The results in the paper show that the crustal deformation pattern before strong earthquake reveals the information of strain status in the deep seismogenic zone, while the chaotic pattern after the occurrence of strong earthquake represents the adjustment of the covering strata.
文摘The height changes of tide gauges directly influence sea level observation. For research of sea level variation in large region or globe, the land vertical displacement must be considered. Two sessions of GPS and absolute gravity observations in 2001 and 2003 are used to determine the horizontal and vertical motion of China coast in ITRF2000 and Eurasia frame. The difference between results of continuous observation and periodic observation is discussed.
基金National Key Research and Development Plan Project(No.2020YFB2010800)National Natural Science Foundation of China(Nos.61905175,51775377,61971307)+4 种基金Fok Ying Tung Education Foundation(No.171055)China Postdoctoral Science Foundation(No.2020M680878)Guangdong Province Key Research and Development Plan Project(No.2020B0404030001)Tianjin Science and Technology Plan Project(No.20YDTPJC01660)Project of Foreign Affairs Committee of China Aviation Development Sichuan Gas Turbine Research Institute(Nos.GJCZ-2020-0040,GJCZ-2020-0041)。
文摘In order to achieve high precision measurement of inductance in a wide frequency range,a method of inductance measurement based on double-excitation auto-balancing bridge is proposed.In this method,the direct digital synthesizer(DDS)as signal generator is used as the bridge excitation source,and the bridge is automatically balanced by adjusting and measuring the voltage ratio.Using standard resistors,the system can achieve high precision measurement of four-terminal pair inductors in the frequency range of 100Hz-100kHz.Aiming at the low efficiency of bridge balancing,an iterative balancing algorithm based on the steepest descent method is proposed.In order to suppress the interference caused by the initial phase change and non-integer periodic sampling,the high-precision measurement of the complex impedance of inductance is realized based on the all-phase fast Fourier transform(apFFT).Finally,the corresponding measurement system is built and the inductance measurement experiment is carried out.The experimental results show that the relative error of the system for inductance measurement can be as low as 0.009%,and the optimal relative measurement uncertainty of the system can reach 9.89×10^(-4)compared with 5×10^(-5)of commercial impedance analyzer.
基金supported by the National Natural Science Foundation of China (Nos.51274104,50874052)the National Basic Research Program of China (No.2011CB933700)。
文摘A continuous online in situ attenuated total reflection Fourier-transform infrared(ATR-FTIR)spectroscopic technique was used to investigate the adsorption and desorption kinetics of heptyl xanthate(KHX)on the surface of ZnO and Cu(Ⅱ)activated ZnO.The results showed that Cu(Ⅱ)facilitated the xanthate adsorption process on the surface,and led to the formation of cuprous xanthate(CuX),dixanthogen(X_(2))and xanthate aggregates.The adsorption of xanthate on the surface of ZnO and Cu(Ⅱ)activated ZnO was found to both follow the pseudo-first-order kinetic model.When the NaOH solution was used as a desorption agent,the adsorbed xanthate can largely be removed due to the competition between OH^(−)and HX−.However,for Cu(Ⅱ)activated ZnO,the peak intensities at 1197 and 1082 cm^(−1) had no obvious weakening,and the absorption intensities at 1261 and 1026 cm^(−1) increased in the first 5 min,indicating an ion-exchange reaction between OH^(−)and surface zinc bonded xanthate HX−and the reorganization of adsorbed xanthate.
文摘Measurements of non-tidal variations of gravity (Ag), which were obtained from 1992 to 2012 at the Talaya seismic station (located in the south-western part of the Baikal region), are interpreted together with GPS (Global Position System) observation data, which were obtained from 2000 to 2013 at the same station. An absolute gravimeter was used for gravity observation. The strongest precision requirements concern tidal gravity prediction. It is the reason why we investigated tidal effect by LCR (LaCoste & Romberg) gravimeter from 1996 to 1997 at the same station. We use tested tidal model for correction of gravity change. The linear component of gravity variations corresponds to changes in the elevation of the site. The correlation coefficient is close to the normal value of the vertical gradient of gravity. At this site, coseismic gravity variations at the time of the Kultuk earthquake (August 27, 2008, Mw = 6.5) were caused by a combined effect of the change of the site's elevation and deformation of the crust. Our estimations of the coseismic effects are consistent with results obtained by modeling based on the available seismic data.
文摘Using GPS observations of horizontal movement from 2001 to 2003 and the cross-fault mobile short-levelling data of 1988~2003, and with the aid of the improved negative dislocation model and the time-varying curve of strain intensity ratio of fault deformation, the regional tectonic deformation background and medium- and short-term precursors related to the preparation of the Minle-Shandan earthquakes of M S6.1 and M S5.8 on October 25, 2003 are investigated. The results reveal that, under the background of the wide-range deformation adjustment, short-term relaxation and recovery caused by the Kunlun Mountains earthquake of M S8.1, the hypocenters of the earthquakes are located on the north edge of the shear stress enhancement zone between the compressional locked segments of block boundary fault, a place which may represent an accelerated strain accumulation. An obvious anomaly of strain intensity ratio appeared in short-levelling measurements crossing over the fault at the Shihuiyaokou site, the closest to the epicenters, 3 months before the occurrence of the earthquakes. In addition, the variation in number of anomalies from 10-odd days to months before the earthquakes in the entire monitoring area and the anomaly concentration and local enhancement relative to near source in the 3 months before the earthquakes are regarded to be precursors to the two events.
文摘Construction progress of long-span bridge is complicated and the quality control is strict. Any disadvantage during construction may potentially affect the internal forces and deck alignments after it is open to traffic. To exactly evaluate the periodic alignments, internal forces and safety, geometrical and physical monitoring are needed during construction. This study aims at the requirement of dynamic geometric monitoring during Sutong Bridge construction, and introduces the realization and observing schemes of the self-developed GPS real-time dynamic geometrical deformation monitoring system. Affected by wind load and construction circumstance, GPS (global positioning system) monitoring signal contains a variety of noise. And the useful signal can be extracted from the signal after de-noising the noises. A de-noising method based on EMD (empirical mode decomposition) model is introduced here to process the bridge dynamic monitoring data, and with the wavelet threshold de-noising method are compared. The result shows that the EMD method has good adaptability, is free from the choice of wavelet bases and the number of decomposition layer. The method is an effective de-noising method for dynamic deformation monitoring to large-span bridges.
文摘Carbonate deposition is a main inorganic carbon sink in lakes, which varies depending on climate change and internal lake dynamics. Research on the relationship between lake carbonate and climate will help to understand mechanisms of carbon cycle in lacustrine systems. The approach of this study is to explicitly link carbonate formation with Holocene long-term climate change and lake evolution in a paleo-lake (Zhuye Lake), which is a terminal lake of a typical inland drainage basin in arid China. This paper presents analysis on grain-size, carbonate content and mineralogical composition of sediment samples from different locations of Zhuye Lake. The results show that calcite and aragonite are two main components for the lake carbonate, and the carbonate enrichment is associated with lake expansion during the Late Glacial and early to middle Holocene. Holocene lake expansion in arid regions of China is usually connected with high basin-wide precipitation that can strengthen the basin-wide surface carbonate accumulation in the terminal lake. For this reason, Zhuye Lake plays a role of carbon sinks during the wet periods of the Holocene.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41174012, 41274022)the National High Technology Research and Development Program of China (Grant No. 2013AA122502)the Open Foundation of Key Laboratory of Precise Engineering and Industry Surveying of National Administration of Surveying, Mapping and Geoinformation (Grant Nos. PF2012-14, PF2013-12)
文摘The importance of water vapor in research of global climate change and weather forecast cannot be over emphasized; therefore substantial efforts have been made in exploring the optimal methods to measure water vapor. It is well-established that with a conversion factor, zenith wet delays can be mapped onto precipitable water vapor (PWV). However, the determination of the exact conversion factor depends heavily on the accurate calculation of a key variable, weighted mean temperature of the trop- osphere (Tin). AS a critical parameter in Global Positioning System (GPS) meteorology, Tm has recently been modeled into a global grid known as GWMT. The GWMT model only requires the location and the day of year to calculate Tm. Despite the advantages that the GWMT model offers, anomalies still exist in oceanic areas due to low sampling resolution. In this study, we refine the GWMT model by incorporating the global Tm grid from Global Geodetic Observing System (GGOS) and obtain an improved model, GWMT-G. The results indicate that the GWMT-G model successfully addresses the anomaly in oceanic areas in the GWMT model and significantly improves the accuracy of Tm in other regions.