湘南桂阳六合土话的否定词

桂阳六合土话的否定词主要有五个:唔[■45]、唔曾[■45 t■hi■13]、冇得[mo45 ti■42]、冇[mo45]和莫[mo45]。否定名词性成分通常用“冇得”和“冇”;否定谓词性成分用“唔”和“唔曾”;对主观意愿、某种习惯或某种状态的否定,通常用“唔”;对完成体的否定,则说成“唔曾”;表禁止否定用“莫”。

桂阳六合土话的“AX了”式状态形容词

具有丰富的"AX了"式状态形容词是桂阳六合土话鲜明特色之一,如"红绯了、酸共了、东了、亻松怪了"。详尽搜集考察了六合土话"AX了"式状态形容词,并对其进行了详细的描述。"A"多为形容词性语素。"X"为后缀,大多数语源不清楚了,只起记音作用。"了"也是后缀,跟六合土话表动作完成或变化已经实现动态助词的读音相同。并通过调查和已有文献了解到"AX了"式状态形容词在湘南土话、西南官话、湘语中均有分布,但数量不一。结论:在同一方言中不同的"AX了"有些是词,有些是短语。

安徽“合六巢”区域旅游资源整合与开发

区域旅游整合开发是现代旅游业发展的必然趋势。全面整合旅游资源,联合开发出一个特色鲜明、文化深厚、可游性强的区域性旅游圈,对提高区域旅游竞争力,实现旅游经济可持续发展具有重要意义。在分析了安徽"合六巢"区域旅游资源整合可行性的基础上,提出了安徽"合六巢"区域旅游资源整合的具体措施。

“合六巢”区域旅游资源整合开发研究

区域旅游整合开发是现代旅游业发展的必然趋势。全面整合旅游资源,联合开发出一个特色鲜明、文化深厚、可游性强的区域性旅游圈,对提高区域旅游竞争力,实现旅游经济可持续发展具有重要意义。本文首先分析了"合六巢"区域旅游资源整合可行性的基础上,提出了"合六巢"区域旅游资源整合的具体措施。

Environmentally benign and economic synthesis of covalent triazine-based frameworks

Covalent triazine-based frameworks（CTFs） are important microporous materials with a wide range of applications.Here,we demonstrate an environmentally benign and economic synthetic pathway to CTFs.The monomers used for CTFs,aromatic nitriles,were obtained by cyanation using nontoxic potassium hexacyanoferrate（Ⅱ） in place of commonly used toxic cyanides.Then,the CTFs were synthesized by trimerization of the corresponding cyano monomers in molten zinc chloride.A series of CTFs was synthesized,and the highest Brunauer-Emmett-Teller surface area measured in this series was 2404 m^2/g.Among the synthesized CTFs,CTF_（DCP） exhibited excellent CO_2 adsorption properties,with a CO_2 uptake of 225 mg/g at 0℃.

小型水库高产养鱼技术

介绍了小型水库高产养鱼应做到六"合":清野消毒时间要合适;鱼种放养要合理;肥料施用要配合;"三网搭配"要适合;养殖模式要综合;鱼病预防与治疗结合。

Synthesis and characterization of porous cobalt oxide/copper oxide nanoplate as novel electrode material for supercapacitors

A promising Co3O4/Cu O composite electrode material was successfully synthesized through a facile hydrothermal and calcination process. Effects of the surfactants hexadecyltrimethyl ammonium bromide（CTAB） and polyvinylpyrrolidone（PVP） on the morphology and electrochemical performance of the composite were investigated. Powder X-ray diffraction（XRD）, scanning electron microscopy（SEM）, transmission electron microscopy（TEM） and nitrogen adsorption-desorption experiment were employed to characterize the microstructures and morphologies of the composite. Meanwhile, the electrochemical performances of the samples were studied using cyclic voltammetry（CV）, galvanostatic charge-discharge test and electrochemical impedance spectroscopy（EIS）. The results show that the porous Co3O4/Cu O-CTAB nanoplates own the best performance and exhibits a high specific capacitance of 398 F/g at 1 A/g with almost 100% capacitance retention over 2000 cycles, and it retains 90% of capacitance at 10 A/g.

Cu(Ⅱ),Ni(Ⅱ)Complexation with Acid Alizarine Blue B in the Presence of Cetyltrimethylammonium Bromide

The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral correction technique （MSASC）. The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu（Ⅱ） or Ni（Ⅱ）and AABB. The binding ratio of AABB to CTAB was 1：2.5, and monomeric aggregate, AABB2CTAB5, was formed with an adsorption constant of 5.95×10^5 at 20 ℃ or 2.48×10^5 at 40 ℃. In the ternary complexation, the ratio of AABB：Cu and AABB：Ni were 1：1 and 1：2.5, respectively. Two types of aggregates, Cu2.AABB2·CTAB80 and Ni5.AABB2.CTAB80, were formed.

Protection behavior of fluorine-containing cover gases on molten magnesium alloys

The sulphur hexa-fluoride gas（SF6）, which is commonly used as the cover gas of molten magnesium alloys in the magnesium industry today, has an extremely high global warming potential（GWP）. The protection mechanism of SF6 containing cover gases on molten magnesium alloys was presented. The cover gas protects the melt by reacting with the melt to form a coherent protective film on the melt surface. The film contains MgO and MgF2. Particles containing MgF2 form on the interface between the oxide film and the bulk magnesium alloy, which correspond to the concave areas from the surface observation. These particles increase the Pilling and Bedworth ratio of surface film and enhance the protective capability of the films. Based on the understanding of the mechanism of SF6, a melting technology in a sealed furnace was proposed, and the protection behavior of magnesium alloys in the sealed melting furnace was investigated under the protective atmosphere containing HFC-134a. The morphology and composition of the surface film were also studied. Experiments to evaluate the protective effect of two other fluorine containing gases with low GWPs on AZglD alloy in the sealed furnace were also carried out, and the results show that the new gases are potential substitutes for SF6.

High efficient removal and mineralization of Cr(VI)from water by functionalized magnetic fungus nanocomposites

A hydroxyl-functionalized magnetic fungus nanocomposite(MFH@GO)was prepared by a simple one-pot method for the removal of Cr(VI)from wastewater.The adsorption behavior of MFH@GO to Cr(VI)in wastewater was discussed in detail.At pH of 5.0 and temperature of 323.15 K,MFH@GO had higher adsorption capacity to Cr(VI)(58.4 mg/g)than the unmodified fungus and GO.Fourier transform infrared spectroscopy(FTIR),X-ray diffraction(XRD),thermogravimetry and differential thermal analysis(TG-DTA),scanning electron microscopy and energy dispersive X-Ray spectroscopy(SEM-EDX)were employed to determine the characteristics of MFH@GO.Results showed that magnetic graphene oxide nanoparticles significantly enhanced the physiochemical properties of the fungi.In addition,the adsorption mechanisms analyses show that Cr(VI)could be reduced and mineralized into ferric chromate in residues.These results suggested that MFH@GO could be used as an promising and alternative biosorbent for removal of Cr(VI)from industrial wastewater.

Optical Properties of CdS.Nanobelts and Nanosaws Synthesized by Thermal Evaporation Method

By a simple one-step H2-assisted thermal evaporation method, high quality CdS nanos- tructures have been successfully fabricated on Au coated Si substrates in large scale. The as-synthesized CdS nanostructures consisted of sword-like nanobelts and toothed nanosaws with a single-crystal hexagonal wurtzite structure. The deposition temperature played an important role in determining the size and morphology of the CdS nanostruetures. A combination of vapor-liquid-solid and vapor-solid growth mechanisms were proposed to interpret the formation of CdS nanostructures. Photoluminescence measurement indicated that the nanobelts and nanosaws have a prominent green emission at about 512 nm, which is the band-to-band emission of CdS. The waveguide characteristics of both types of CdS nanos-truetures were observed and discussed.

Superlattice Patterns in Coupled Turing Systems

In this paper, superlattice patterns have been investigated by using a two linearly coupled Brusselator model. It is found that superlattice patterns can only be induced in the sub-system with the short wavelength. Three different coupling methods have been used in order to investigate the mode interaction between the two Turing modes. It is proved in the simulations that interaction between activators in the two sub-systems leads to spontaneous formation of black eye pattern and/or white eye patterns while interaction between inhibitors leads to spontaneous formation of super-hexagonal pattern. It is also demonstrated that the same symmetries of the two modes and suitable wavelength ratio of the two modes should also be satisfied to form superlattice patterns.

Synthesis and Crystal Structure of Potassium Triethylenetetraaminehexaacetatodi [Oxo-vanadium(Ⅳ)] Hexahydrate, K_2[V_2O_2(ttha)]·6(H_2O)

The title complex, potassium triethylenetetraaminehexaacetatodi [oxo-vanadium (Ⅳ)] hexahydrate K2[V2O2(ttha)]6(H2O), was synthesized in aqueous solution and its crystal structure has been determined by X-ray diffraction. The complex belongs to a triclinic system, space group P?with a = 6.645(1), b = 9.870(2), c = 13.263(3) ? a = 70.68(3), b = 76.27(3), g = 71.66(3), V = 770.5(3) 3, Mr = 808.58, Dc = 1.743 g/cm3, Z = 1, m = 0.968 mm-1, l(MoKa) = 0.71073 and F(000) = 416. The final R = 0.0465 and wR = 0.1091 for 2974 observed diffractions with I ≥ 2s(I). In the complex, the V atom is octahedrally coordinated to the oxo ligand, two N and three O atoms of the triethylenetetraaminehexaacetic (TTHA) ligand. All of the ten chelating sites are coordinated to the two vanadium atoms, and the coordination octahedron is distorted. Each [V2O2(ttha)]2- ion is further connected by the K+ ions through carboxyl groups of TTHA6- ion, forming a two dimensional network structure.

Fully Quantized Theory of Six-Wave Mixing with Matter Waves

We show that Wu-Yang theory of fully quantized four-wave mixing can be generalized to the six-wave mixing and derive the analytical solution of the coupled equations describing the quantum dynamics of six-wave mixing.

Synthesis and Crystal Structure of a New Hexadentate Ligand N,N'-Bis(di(2-pyridyl)methyl)ethylenediamine

The reaction of di(2-pyridyl)ketone with ethylenediamine produced hexadentate Schiff base 1 which can be reduced to form a new ligand N,N-bis(di(2-pyridyl)-methyl)ethylene- diamine (BDPM) in ethanol solution. The two compounds were characterized by elemental analyses and spectroscopic methods. Their structures were determined by X-ray diffraction study. Crystal data for 1: C24H20N6, Mr = 392.5, monoclinic, P21/c, a = 13.871(3), b = 13.510(2), c = 12.153(2) ? b = 112.97(2)? Z = 4, V = 2094.1(6) ?, Dc = 1.245 g/cm3, m(MoKa) = 0.078 mm-1, F(000) = 824, the final R = 0.0545 and wR = 0.0557 for 2048 observed reflections (I > 2s(I)); for BDPM: C24H24N6, Mr = 396.49, monoclinic, C2/c, a = 21.411(3), b = 8.053(1), c = 11.868(1) ? b = 92.63(1)? Z = 4, V = 2044.2(4) 3, Dc = 1.288 g/cm3, m(MoKa) = 0.080 mm-1, F(000) = 840, the final R = 0.0401 and wR = 0.0939 for 1673 observed reflections (I > 2s(I)).

Hexanuclear ring cobalt complex for photochemical CO_(2) to CO conversion

Photosynthesis in nature has been deemed as the most significant biochemical reaction,which maintains a relatively stable content of O_(2) and CO_(2) in the atmosphere.Herein,for a deeper comprehension of natural photosynthesis,an artificial photosynthesis model reaction of photochemical CO_(2) to CO conversion(CO_(2)+2 H^(+)+2e^(-)→CO+H_(2)O)catalyzed by a homogeneous hexanuclear ring cobalt complex{K_(2)[CoO_(3)PCH_(2)N(CH_(2)CO_(2))_(2)]}_(6)(Co6 complex)is developed.Using the[Ru(bpy)_(3)]^(2+)as a photosensitizer and TEOA as a sacrificial electron donor,an optimal turnover frequency of 503.3 h^(‒1) and an apparent quantum efficiency of 0.81%are obtained.The good photocatalytic CO_(2) reduction performance is attributed to the efficient electron transfer between Co6 complex and[Ru(bpy)_(3)]^(2+),which boosts the photogenerated carriers separation of the photosensitizer.It is confirmed by the j‐V curves,light‐assisted UV‐vis curves,steady‐state photoluminescence spectra and real‐time laser flash photolysis experiments.In addition,the proposed catalytic mechanism for CO_(2) reduction reaction catalyzed by the Co6 complex is explored by the potassium thiocyanate poison experiment,Pourbaix diagram and density functional theory calculations.

Lubrication properties of silver-palladium alloy prepared by ion plating method for high temperature stud bolt

As a solid lubricant, silver-palladium (Ag-Pd) alloy coating was investigated for the application to high temperature stud bolt. A glue layer nickel (Ni) film was deposited on the surface of the hex bolt sample and then Ag-Pd alloy coating was performed on it using ion plating method. The friction coefficient of Ag-Pd alloy film coated bolt was lower than that of N-5000 oil coated bolt by the result of axial force measurement. The cyclic test of heat treatment was conducted to evaluate the durability of Ag-Pd alloy film coated bolt. In a cycle, sample was assembled into the block using torque wrench, followed by heating and disassembling. It was not successful to disassemble the N-5000 oil coated bolt from the block after only one cycle. However, the Ag-Pd alloy film coated bolt was able to be disassembled softly till 12 cycles.

Synthesis and Crystal Structure of［Na（DB18C6）（H_2O）_2］_2Mo_6O_（19）·3DMF·2CH_3OH

The title complex [Na (DB_18C_6) (H_2O)_2]_2Mo_6O_19·3DMF · 2CH_3OH (Ⅰ) , a new type of crown hexamolybdate supermolecule, has been synthesized. Its crystal structure has been determined by X-ray diffraction analysis. The crystal C_49H_32 Mo_6N_2Na_2O_40 is tetragonal, space group P4/mbm, a= 17.108(2), c= 28. 285 (6) A ,V=8279(2) A￣ 3, Z=4 , M_r= 1960. 8 , D_x=1. 573 g/cm￣3 , P=9. 51cm￣(-1). F(000)=3936. The final agreement factors R=0. 058 and R_w= 0. 062 for 1777 independent reflections with F>4σ(F). In contrast to what we have reported about [Na(DB_18C_6)(CH_3OH)]_2Mo_6O_19(Ⅱ) where the whole complex was linked together, the cation [Na (DB_18C_6 ) (H_2O)_2]￣ + , that has crystallographic D_2h symmetry, combines with the anion with the symmetry O_h by electronic interaction.

段玉裁的古音体系及其对方音的态度

段玉裁古音体系体大思精,《六书音均表》即是段氏潜心商订的古音学力作,形成了段氏古音学的完整体系,但是书中几乎不提方言,而是用合韵说解释异部相押。事实上,段氏并非没有方音观念,其拒斥方音完全是出于维护同质性理想化古音体系的考虑,"今韵古分十七部表"就是其同质性理想化古音体系的重要显现。然而,同质性理想化的语音体系会导致古音体系的严重缺陷,如:韵类关系古今无变、在今音中寻求古音音值、拒斥以个别字的流变审取古音的方音说。

Effects of h-BN content on properties of Ni-Cr/h-BN composite

Ni-Cr/h-BN self-lubricating composities were prepared by powder metallurgy (P/M) method.The effects of hexagonal boron nitride (h-BN) content on the mechanical and tribological properties of the Ni-Cr/h-BN composites were investigated.The corresponding frictional models were established to analyze the formation of the lubricant h-BN films on the surfaces of the Ni-Cr/h-BN composites.The results show that,when the content of h-BN increases from 5% to 15% (mass fraction),the bending strength of the Ni-Cr/h-BN composite decreases from 96.670 MPa to 17.319 MPa,and the hardness (HB) decreases from 33 to 14.The friction coefficient of the Ni-Cr/h-BN composite decreases firstly from 0.385 to 0.216,and then increases to 0.284,while the wear rate decreases firstly from 4.14×10-9 kg/(N·m) to 1.35×10-9 kg/(N·m),then increases to 2.36×10-9 kg/(N·m).The best comprehensive mechanical and tribological properties can be obtained between 10% and 12% h-BN addition.