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六氟化硒中同位素丰度质谱分析
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作者 窦秀英 李胡平 薛永珍 《质谱学报》 EI CAS CSCD 2004年第B10期195-196,共2页
Natural Se element have six kinds of isotope ^74Se, ^76Se, ^77Se, ^78Se, ^80Se and ^82Se,and the natural content of ^74Se is 0. 87%. After being shot by neutron, ^78Se isotope can be changed to be short decayed period... Natural Se element have six kinds of isotope ^74Se, ^76Se, ^77Se, ^78Se, ^80Se and ^82Se,and the natural content of ^74Se is 0. 87%. After being shot by neutron, ^78Se isotope can be changed to be short decayed period to radioisotope. The radiation source made up fro mhigh density ^75Se isotope, which content is more than 90%, is quite valuable for application of agriculture and nuclear medical science and such aspect. This study mainly presents experimental research on gas mass spectrograph, establishes the analysis method for isotope content of Se F6, gives best temperature needed to eradicate impurity from sample,relative strength of Se F6 fragment ion summit under the best electron energy, characteristic summit and data processing technique etc. Using this method, the measuring accuracy of ^74Se isotope content of natural Se F6 is 0.4%. The technique can also be applied to examine products. 展开更多
关键词 六氟化硒 同位素丰度 质谱分析 绝对测量法
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六氟化硒的制备及参数优化
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作者 仝庆 《低温与特气》 CAS 2018年第2期25-27,共3页
应用提纯过的氟气和经过处理后的硒粉反应制备六氟化硒粗品,并根据不同的气化温度对六氟化硒粗品进行了初步提纯。与此同时,考察不同反应温度条件及投料量对反应收率的影响,优化了工艺参数。
关键词 氟气 六氟化硒 初步提纯 反应温度 投料量
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