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兰钨球磨对纳米钨粉团聚的影响 被引量:4
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作者 林涛 李会谦 +3 位作者 邵慧萍 刘祥庆 郭志猛 吴成义 《粉末冶金技术》 EI CAS CSCD 北大核心 2008年第2期126-129,共4页
采用超声喷雾干燥制备的前驱体为原料,经过两阶段低温还原和球磨工艺的结合使用制备了纳米钨粉。通过还原前后粉末形貌的对比,分析了钨粉还原过程中的形貌特征。采用第一段低温还原后得到的兰钨为原料,对比了在不同阶段球磨对还原后钨... 采用超声喷雾干燥制备的前驱体为原料,经过两阶段低温还原和球磨工艺的结合使用制备了纳米钨粉。通过还原前后粉末形貌的对比,分析了钨粉还原过程中的形貌特征。采用第一段低温还原后得到的兰钨为原料,对比了在不同阶段球磨对还原后钨粉团聚状态的影响。对所制备的纳米钨粉进行了SAXS粒度表征。结果表明:钨粉的形貌和结构具有"遗传性";兰钨阶段的球磨有效地打碎了颗粒之间的团聚,有利于颗粒之间的分散;钨粉的球磨不能打碎纳米颗粒之间的硬团聚。SAXS检测结果表明,使用两阶段还原和球磨相结合的工艺制备的纳米钨粉平均粒径为35nm。 展开更多
关键词 纳米 兰钨 球磨 团聚
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The effect of hydrogen on the recombination of Frenkel pair in tungsten: A theoretical insight
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作者 ShiYao Qin Shuo Jin +3 位作者 LiangLiang Niu JianNan Hao HongBo Zhou GuangHong Lu 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2017年第6期80-83,共4页
Tungsten (W), with its primary advantages, is considered as the most promising candidate for plasma facing materials (PFMs) for the next generation of fusion devices such as ITER. However, continuous bombardment with ... Tungsten (W), with its primary advantages, is considered as the most promising candidate for plasma facing materials (PFMs) for the next generation of fusion devices such as ITER. However, continuous bombardment with 14.1 MeV neutron introduces Frenkel defects as the primary damage in W [1]. The Frenkel defects, composed of self-interstitial atoms (SIAs) and vacancies, can develop to extended defects such as voids and interstitial clusters, resulting in hardening, swelling and embrittlement of W, thus degrading the properties of W [2]. The recombination of SIAs and vacancies is an effective way to reduce the Frenkel defects in bulk W, which enhances the radiation resistance of W based on recent theoretical calculations [3,4]. The moving of the SIA to the vacancy could finish the recombination process through instantaneous or thermally activated way [3]. The instantaneous recombination region is an ellipse with the semi-minor axis of 5.4 ? and semi-major axis of 18 ? according to the molecular dynamics calculation [4]. 展开更多
关键词 Frenkel recombination tungsten interstitial insight degrading defects thermally swelling instantaneous
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