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氯盐-硫酸盐共存环境中阳离子类型对氯离子结合能力的影响 被引量:7
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作者 潘从玲 储洪强 +3 位作者 蒋林华 朱正宇 王婷婷 刘涛 《混凝土》 CAS 北大核心 2019年第4期28-32,36,共6页
选用KCl、Na Cl、CaCl_2、Mg Cl_2四种氯盐,对预埋钢筋的水泥砂浆圆柱体试件进行浸烘循环试验,研究氯盐-硫酸盐共存环境中阳离子类型对氯离子结合能力的影响。采用电位滴定法进行氯离子浓度测试,X射线衍射仪用于定性分析胶凝材料的水化... 选用KCl、Na Cl、CaCl_2、Mg Cl_2四种氯盐,对预埋钢筋的水泥砂浆圆柱体试件进行浸烘循环试验,研究氯盐-硫酸盐共存环境中阳离子类型对氯离子结合能力的影响。采用电位滴定法进行氯离子浓度测试,X射线衍射仪用于定性分析胶凝材料的水化产物,同时利用综合热分析仪进行微分热重法定量分析水化产物。研究结果表明,在氯盐-硫酸盐共存环境中,阳离子类型对孔溶液的p H值和氯离子结合能力有显著影响,其影响能力大小为Mg^(2+)>Ca^(2+)>K^+>Na^+;K^+、Na^+均会导致孔溶液的p H值升高,使Friedel′s盐中结合氯离子被重新释放,从而降低氯离子结合能力;Mg^(2+)、Ca^(2+)、SO_4^(2-)共存时,会生成石膏、钙矾石等膨胀性产物,导致结构内部形成微裂缝,加速了氯离子的渗透,导致自由氯离子含量迅速升高;但Mg^(2+)、Ca^(2+)的存在能够产生较多的M-S-H、C-S-H凝胶,从而增加了物理吸附氯离子含量,氯离子结合能力随之提高。 展开更多
关键词 水泥砂浆 浸烘循环 氯盐-硫酸盐共存环境 阳离子类型 氯离子 结合能力
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人机共存环境下巡检机器人自主移动与避障方法 被引量:5
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作者 李敬业 高学山 +2 位作者 高锐 梁鹏 兰冰青 《兵工自动化》 2020年第7期83-88,共6页
为提高人机混杂环境中移动机器人自主巡检效率,提出一种基于模糊逻辑理论的避障方法。通过分析人类的社会行为规则,结合机器人的运动特性,建立移动机器人系统的数学模型,将人机距离、人的行为模式和人与机器人间的相对速度参数进行模糊... 为提高人机混杂环境中移动机器人自主巡检效率,提出一种基于模糊逻辑理论的避障方法。通过分析人类的社会行为规则,结合机器人的运动特性,建立移动机器人系统的数学模型,将人机距离、人的行为模式和人与机器人间的相对速度参数进行模糊化处理,得出基于模糊推理方法的机器人速度变化决策,利用模糊控制规则,实现模糊逻辑控制,并通过穿越和相遇2种运动行为进行了实验验证。仿真结果验证了该方法具有抗干扰性和良好的避障性能。 展开更多
关键词 人机共存环境 巡检机器人 社会力模型 运动行为 模糊逻辑
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20钢在油气田中CO_(2)与H_(2)S共存环境下的腐蚀行为及机理
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作者 宋成立 宋晓俊 +3 位作者 陈庆国 李坤 贾海东 李广山 《机械工程材料》 CAS CSCD 北大核心 2023年第3期60-65,共6页
利用高温高压动态反应釜模拟油气田CO_(2)和H_(2)S共存环境的实际工况,通过腐蚀试验分析了20钢在不同CO_(2)分压(0.01,0.05,0.21,0.50 MPa)和H_(2)S分压(0.0003,0.003,0.01,0.05 MPa)下的腐蚀行为以及CO_(2)和H_(2)S分压对均匀腐蚀和点... 利用高温高压动态反应釜模拟油气田CO_(2)和H_(2)S共存环境的实际工况,通过腐蚀试验分析了20钢在不同CO_(2)分压(0.01,0.05,0.21,0.50 MPa)和H_(2)S分压(0.0003,0.003,0.01,0.05 MPa)下的腐蚀行为以及CO_(2)和H_(2)S分压对均匀腐蚀和点蚀的影响程度。结果表明:在H_(2)S分压为0.003 MPa条件下,当CO_(2)分压为0.01,0.05 MPa时,20钢主要发生均匀腐蚀,随着CO_(2)分压的继续增大,点蚀越来越严重;在CO_(2)分压为0.05 MPa条件下,当H_(2)S分压为0.0003 MPa时,20钢表面腐蚀轻微,随着H_(2)S分压的增大,腐蚀加剧,但仍主要发生均匀腐蚀;H_(2)S和CO_(2)分压对20钢的均匀腐蚀速率和点蚀速率均具有十分显著的影响,H_(2)S分压对均匀腐蚀的影响程度较大,而CO_(2)分压对点蚀的影响程度较大。 展开更多
关键词 CO_(2)和H_(2)S共存环境 均匀腐蚀 点蚀 分压 20钢
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H_(2)S/CO_(2)共存环境中X65钢点腐蚀形成机理及预测方法
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作者 闫伟 刘琬晴 +3 位作者 李光聪 张晨 邹子琛 Srdjan Nesic 《天然气工业》 EI CAS 2024年第11期161-169,共9页
碳钢管材广泛应用于油气生产系统,在含CO_(2)、H_(2)S、氯离子等多种腐蚀介质共存的多相流环境中,容易发生腐蚀穿孔泄漏,可能造成管道和设备的失效,进而带来安全隐患和经济损失。目前针对H_(2)S/CO_(2)共存环境下金属腐蚀的研究主要集... 碳钢管材广泛应用于油气生产系统,在含CO_(2)、H_(2)S、氯离子等多种腐蚀介质共存的多相流环境中,容易发生腐蚀穿孔泄漏,可能造成管道和设备的失效,进而带来安全隐患和经济损失。目前针对H_(2)S/CO_(2)共存环境下金属腐蚀的研究主要集中在较高H_(2)S分压下,多种形式FeS产物的生成规律、产物膜保护特性和点蚀形成机理,很少研究极微量H_(2)S诱发点腐蚀的可能性和发生条件。为此,以X65钢为例,利用大型H_(2)S多相流腐蚀环路实验系统完成了4组测试实验和2组验证实验,研究了40℃、恒定CO_(2)分压环境下,不同H_(2)S分压对低碳钢点腐蚀行为的影响规律,并提出了一种基于热力学理论的预测方法。研究结果表明:①当H_(2)S分压高于50 Pa时,X65钢的腐蚀速率低且表现为全面腐蚀;而当H_(2)S分压低于24 Pa时,随着H_(2)S分压的逐步降低,X65钢的点腐蚀加剧,H_(2)S为2.4 Pa时的点腐蚀速率超过11 mm/a。②当H_(2)S分压极低且马基诺型FeS的过饱和度低于1时,快速形成的FeS膜不能完整覆盖金属表面,暴露表面会在电偶腐蚀的作用下,被饱和CO_(2)溶液快速腐蚀,最终导致低碳钢发生局部点腐蚀。③建立不同H_(2)S分压下低碳钢表面马基诺型FeS过饱和度边界控制曲线,可以准确预测不同条件下碳钢的点腐蚀行为。结论认为,在相关行业标准规定的H_(2)S分压下限以内,H_(2)S/CO_(2)共存环境中极微量的H_(2)S仍然可能会诱发碳钢发生点腐蚀,该认识对于H_(2)S/CO_(2)共存环境下油气管道的局部点腐蚀预测和防腐防护研发具有重要理论和现实意义。 展开更多
关键词 H_(2)S CO_(2) 共存环境 低碳钢 点腐蚀 腐蚀机理 预测方法
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高含H2S/CO2环境中套管钢腐蚀行为与腐蚀产物膜关系 被引量:17
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作者 李春福 邓洪达 王斌 《材料热处理学报》 EI CAS CSCD 北大核心 2008年第1期89-93,共5页
研究了在高含H2S/CO2环境中腐蚀产物膜在套管钢腐蚀过程中作用。通过模拟某气田井下腐蚀环境,采用失重腐蚀方法研究了NT80ss和L80钢钢在1.5MPa、30~120℃环境中腐蚀规律,并采用电化学交流阻抗(EIS)技术和扫描电镜(SEM)分析了... 研究了在高含H2S/CO2环境中腐蚀产物膜在套管钢腐蚀过程中作用。通过模拟某气田井下腐蚀环境,采用失重腐蚀方法研究了NT80ss和L80钢钢在1.5MPa、30~120℃环境中腐蚀规律,并采用电化学交流阻抗(EIS)技术和扫描电镜(SEM)分析了腐蚀产物膜和腐蚀行为的关系。结果表明:60℃为NT80ss和L80钢腐蚀的临界温度,低于60℃时,随温度增加,腐蚀速率降低,高于60℃时,腐蚀速率随温度增加而增大;与其它温度相比,在60℃环境中NT80ss和L80钢腐蚀产物膜的阻抗能力最强、膜的致密性最好,相应腐蚀速率最低。 展开更多
关键词 套管钢 H2S/CO2共存环境 腐蚀行为 腐蚀产物膜
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NT80SS钢在高含H2S/CO2环境中的腐蚀行为 被引量:3
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作者 李春福 邓洪达 崔世华 《中国腐蚀与防护学报》 CAS CSCD 北大核心 2009年第3期225-229,共5页
模拟罗家寨气田高含H_2S/CO_2腐蚀环境,研究NT80SS套管钢的腐蚀规律及环境因素(总压、温度、腐蚀时间、Cl^-、流速)对其腐蚀的影响;并采用动电位扫描、电化学交流阻抗谱(EIS)和扫描电镜(ESM)等手段分析了腐蚀产物膜的电化学特性和形貌... 模拟罗家寨气田高含H_2S/CO_2腐蚀环境,研究NT80SS套管钢的腐蚀规律及环境因素(总压、温度、腐蚀时间、Cl^-、流速)对其腐蚀的影响;并采用动电位扫描、电化学交流阻抗谱(EIS)和扫描电镜(ESM)等手段分析了腐蚀产物膜的电化学特性和形貌。结果表明,在所研究的温度范围内,NT80SS钢在60℃腐蚀速率最低;当总压≥9MPa时,在120℃下的腐蚀速率比90℃的小,而总压<9MPa时,情况则相反;腐蚀速率随时间的延长而降低;Cl^-能促进钢的腐蚀;介质流速增加,钢的腐蚀速率增大.电化学实验结果指出,在30℃~120℃的温度范围内,60℃时钢腐蚀产物膜的阻抗能力强、阳极极化率高,腐蚀产物膜的致密性最好,因而NT80SS钢在60℃时腐蚀速率最低。 展开更多
关键词 NT80SS H2S/CO2共存环境 腐蚀行为 腐蚀影响因素
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温度对S135钢和G105钢在CO_(2)/H_(2)S共存体系中腐蚀行为的影响
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作者 高科超 尚锁贵 +3 位作者 张智 高强勇 马金鑫 刘婉颖 《机械工程材料》 CAS CSCD 北大核心 2023年第3期24-30,共7页
在气体分压分别为20,0.1 MPa的CO_(2)/H_(2)S共存模拟油田地层水中,利用高温高压釜在不同温度(室温、100℃、180℃)下对S135钢和G105钢进行腐蚀试验,研究了温度对2种钢腐蚀行为的影响。结果表明:100℃下S135钢和G105钢的腐蚀速率最大,... 在气体分压分别为20,0.1 MPa的CO_(2)/H_(2)S共存模拟油田地层水中,利用高温高压釜在不同温度(室温、100℃、180℃)下对S135钢和G105钢进行腐蚀试验,研究了温度对2种钢腐蚀行为的影响。结果表明:100℃下S135钢和G105钢的腐蚀速率最大,分别为0.8463 mm·a^(-1)和0.8500 mm·a^(-1),180℃下的腐蚀速率最小,分别为0.2291 mm·a^(-1)和0.2309 mm·a^(-1);100℃下钢表面腐蚀产物主要为FeCO3和FeS,此温度下CO_(2)为腐蚀主控因素,室温和180℃下的腐蚀产物主要为FeS,H_(2)S为腐蚀主控因素。 展开更多
关键词 温度 S135钢 G105钢 CO_(2)/H_(2)S共存环境 地层水 腐蚀行为
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SSI:一种IPv6/IPv4多址同源识别模型
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作者 王轩 王振兴 +1 位作者 王禹 张连成 《计算机科学》 CSCD 北大核心 2014年第8期139-143,共5页
IPv6/IPv4共存环境下多址同源识别是共存网络管理与拓扑发现的一个关键问题。现有研究主要集中于子网内部的双栈发现及单一IP协议栈中的别名解析,难以识别远程IPv6/IPv4共存网络中的多址同源。通过分析同源地址间的本质联系,提出一种IPv... IPv6/IPv4共存环境下多址同源识别是共存网络管理与拓扑发现的一个关键问题。现有研究主要集中于子网内部的双栈发现及单一IP协议栈中的别名解析,难以识别远程IPv6/IPv4共存网络中的多址同源。通过分析同源地址间的本质联系,提出一种IPv6/IPv4多址同源识别模型(SSI),该模型综合利用特殊地址格式匹配、TCP时钟指纹比对和上层协议短时致瘫等多种方式来提高同源地址的识别能力。实验结果表明,上述方法均可有效识别IPv6/IPv4多址同源;SSI模型具有较理想的识别率和正确率。 展开更多
关键词 IPV6 共存环境 多址同源 格式匹配 时钟指纹 短时致瘫
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Effect of nitrite intercalated Mg-Al layered double hydroxides on mortar durability under Cl−and SO_(4)^(2-) coexisting environment 被引量:4
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作者 WANG Xu-hui XU Jin-xia TAN Qi-ping 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第2期546-560,共15页
The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-... The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion. 展开更多
关键词 layered double hydroxides mortar durability SO_(4)^(2-)attack steel corrosion Cl−and SO_(4)^(2-)coexisting environment
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Man, City, and Nature in The Woman Warrior and Ballad of Eternal Sorrow
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作者 QIU Shi-cun JIANG Deng-ke 《Sino-US English Teaching》 2014年第7期547-552,共6页
In a time of the global market economy, if one wants to live harmoniously together with nature or living environment, he should not think with a theoretical mode of dualist contradiction but that of harmony and coexis... In a time of the global market economy, if one wants to live harmoniously together with nature or living environment, he should not think with a theoretical mode of dualist contradiction but that of harmony and coexistence such as "wholeness of man and nature". To illustrate this point, this paper thinks The Woman Warrior and Ballad of Eternal Sorrow are two significant texts: Ballad of Eternal Sorrow tells an ordinary, self-respecting, and life-respecting story of WANG Qi-yao and the girls like her as well as the city Shanghai. They blend into one harmonious whole: The city is like the girls and the girls match the city. Likewise, The Woman Warrior highlights the significance of naturc on the girl narrator's epiphany and healthy growth. The narrator comes to understand that paradoxes are the basic existent condition of human beings and so what she needs to do is to be magnanimous and balanceable in accepting these paradoxes. 展开更多
关键词 "wholeness of man and nature" The Woman Warrior Ballad of Eternal Sorrow Orientalism
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Coexistence in a mutualistic model with cross-diffusion in a heterogeneous environment 被引量:2
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作者 Badradeen Adam Zhigui Lin Abdelrazig K. Tarboush 《International Journal of Biomathematics》 SCIE 2018年第6期59-75,共17页
To understand the impact of environmental heterogeneity and mutualistic interaction of species, we consider a mutualistic model with cross-diffusion in a heterogeneous environ- ment. Semi-coexistence states have been ... To understand the impact of environmental heterogeneity and mutualistic interaction of species, we consider a mutualistic model with cross-diffusion in a heterogeneous environ- ment. Semi-coexistence states have been studied by using the corresponding eigenvalue problems, and sufficient conditions for the existence and non-existence of coexistence states are given. Our results show that the model possesses at least one coexistence solution if the intrinsic populations growth rates are big or free-diffusion and cross-diffusion coefficients are weak. Otherwise, the model have no coexistence solution. The true solutions are obtained by utilizing the monotone iterative schemes. In order to illustrate our analytical results, some numerical simulations are given. 展开更多
关键词 Mutualistic model strongly-coupled CROSS-DIFFUSION coexistence.
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Plasma perturbations in the coexisting environment of VLF transmitter emission, lightning strokes and seismic activity 被引量:4
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作者 TAO Dan LIU WenLong MA YuDuan 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2018年第5期678-686,共9页
We analyzed plasma perturbations occurring in the coexisting environment of powerful VLF transmitter emission, intense lightning strokes and strong seismic activity during pregnant period. The results suggest that ano... We analyzed plasma perturbations occurring in the coexisting environment of powerful VLF transmitter emission, intense lightning strokes and strong seismic activity during pregnant period. The results suggest that anomalous electron bursts with energy dispersion in the range of ~100–350 keV, forming the "wisp" signature, are due to cyclotron resonance of electrons with monochromatic waves from the powerful NWC VLF transmitters during nighttime. The intense broad band VLF emissions (up-going 0+ whistlers) are observed while the DEMETER satellite goes through the region of intense thunderstorm activities at mid-latitudes. However, the effects of intense lightning activity and pregnant earthquake have little impact on this kind of stable energy-dispersed electron structures, despite the fact that they are presumably two primary reasons for the particle precipitation in the ionosphere. The case studied here provides us a valuable opportunity to address the various sources triggering the anomalous plasma perturbations in the ionosphere. 展开更多
关键词 plasma perturbation electron precipitation cyclotron resonance VLF transmitter lightning seismic activity
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Changes in niche differentiation and environmental filtering over a hydric stress gradient
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作者 Alejandra Martínez-Blancas Carlos Martorell 《Journal of Plant Ecology》 SCIE CSCD 2020年第2期185-194,共10页
Aims Diversity in communities is determined by species’ability to coexist with each other and to overcome environmental stress that may act as an environmental filter.Niche differentiation(ND)results in stronger intr... Aims Diversity in communities is determined by species’ability to coexist with each other and to overcome environmental stress that may act as an environmental filter.Niche differentiation(ND)results in stronger intra-than interspecific competition and promotes coexistence.Because stress affects interactions,the strength of ND may change along stress gradients.A greater diversity of plant growth forms has been observed in stressful habitats,such as deserts and alpine regions,suggesting greater ND when stress is strong.We tested the hypothesis that niche differences and environmental filters become stronger with stress.Methods In a semiarid grassland in southern Mexico,we sowed six annual species in the field along a hydric stress gradient.Plants were grown alone(without interactions),with conspecific neighbors(intraspecific interactions)or with heterospecific neighbors(interspecific interactions).We analyzed how the ratio of intra-to interspecific competition changed along the gradient to assess how water availability determines the strength of ND.We also determined if hydric stress represented an environmental filter.Important Findings We observed stronger intra-than interspecific competition,especially where hydric stress was greater.Thus,we found ND in at least some portion of the gradient for all but one species.Some species were hindered by stress,but others were favored by it perhaps because it eliminates soil pathogens.Although strong ND was slightly more frequent with stress,our species sample was small and there were exceptions to the general pattern,so further research is needed to establish if this is a widespread phenomenon in nature. 展开更多
关键词 hydrological niche species interactions environmental constraints species coexistence stabilizing mechanisms equalizing mechanisms
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