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New atom movement mechanism for tracking path on disordering AuCuI(A_8^(Au)A_4^(Cu)) compound 被引量:3
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作者 谢佑卿 彭红建 +2 位作者 刘心笔 李小波 聂耀庄 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第10期3221-3256,共36页
Taking experimental path on disordering AuCuI(AAuCu8A4)composed of A Au8 and ACu4 stem alloy genes as an example, three discoveries and a method were presented. The ability of Au Cu I(AAu Cu8 A4)to keep structure ... Taking experimental path on disordering AuCuI(AAuCu8A4)composed of A Au8 and ACu4 stem alloy genes as an example, three discoveries and a method were presented. The ability of Au Cu I(AAu Cu8 A4)to keep structure stabilization against changing temperature is attributed to the fact that the AAu8 and ACu4 potential well depths greatly surpass their vibration energies, which leads to the subequilibrium of experimental path. A new atom movement mechanism of AuCuI(AAuACu84)to change structure for suiting variation in temperature is the resonance activating-synchro alternating of alloy genes, which leads to heterogeneous and successive subequilibrium transitions. There exists jumping order degree, which leads to the existence of jumping Tj-temperature and an unexpected so-called "retro-effect" about jumping temperature retrograde shift to lower temperatures upon the increasing heating rate. A set of subequilibrium holographic network path charts were obtained by the experimental mixed enthalpy path method. 展开更多
关键词 INTERMETALLICS alloy gene order/disorder transformation resonance activating-synchro alternating mechanism thermodynamic properties equilibrium and subequilibrium holographic network path charts
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乘法噪声系数对双稳锯齿系统逃逸率的影响 被引量:1
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作者 游敬云 曹力 +1 位作者 吴大进 柯圣志 《华中理工大学学报》 EI CAS CSCD 北大核心 2001年第2期108-110,共3页
在不同乘法噪声系数情况下 ,计算了关联噪声驱动的双稳锯齿系统的逃逸率 .计算结果表明 ,乘法噪声系数对相对逃逸率有极大的影响 ,改变乘法噪声系数 ,系统的相对逃逸率既可出现抑制平台 。
关键词 乘法噪声系数 逃逸率 关联白噪声 双稳锯齿系统 抑制平台 激活共振 噪声互关联强度
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多共振热激活延迟荧光过程的理论研究 被引量:1
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作者 张少秦 李美清 +1 位作者 周中军 曲泽星 《化学学报》 SCIE CAS CSCD 北大核心 2023年第2期124-130,共7页
本工作借助第一性原理和动力学演化,系统地研究了四个叔丁基-咔唑及吩噻嗪取代的硼-氮化合物(BCz-BN、2PTZ-BN、Cz-PTZ-BN和2Cz-PTZ-BN)的多共振热激活延迟荧光的高效发光机制.结果表明上述分子T_(1)与T_(2)间的内转换速率远大于其它辐... 本工作借助第一性原理和动力学演化,系统地研究了四个叔丁基-咔唑及吩噻嗪取代的硼-氮化合物(BCz-BN、2PTZ-BN、Cz-PTZ-BN和2Cz-PTZ-BN)的多共振热激活延迟荧光的高效发光机制.结果表明上述分子T_(1)与T_(2)间的内转换速率远大于其它辐射与非辐射速率,同时T_(2)到S_(1)的反向系间窜越速率也高于T_(1)到S_(1)的反向系间窜越速率,因此其多共振热激活延迟荧光过程应遵循T_(1)→T_(2)→S_(1)→S_(0)的路径.进一步动力学演化表明,T_(1)与T_(2)之间的内转换主要发生在演化初期,随着时间的推移,能量逐渐由T_(2)向S_(1)转移,并最终在S_(1)完成荧光发射.上述研究揭示了多共振延迟荧光的微观本质,为未来设计及合成新的多共振热激活延迟荧光分子提供了理论依据. 展开更多
关键词 光致发光 共振激活延迟荧光 密度泛函理论 激发态 旋轨耦合 反向系间窜越
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Fluctuating Potential Barrier System with Correlated Spatial Noises
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作者 LIJing-Hui 《Communications in Theoretical Physics》 SCIE CAS CSCD 2004年第6期899-902,共4页
In this paper, we study a fluctuating potential barrier system with correlated spatial noises. Study shows that for this system, there is the resonant activation over the fluctuating potential barrier, and that the co... In this paper, we study a fluctuating potential barrier system with correlated spatial noises. Study shows that for this system, there is the resonant activation over the fluctuating potential barrier, and that the correlation between the different spatial noises can enhance (or weaken) the resonant activation. 展开更多
关键词 spatial noise resonant activation
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Multi-Resonant-Activation for a System Only Driven by Multi-State Noise
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作者 李静辉 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第3期517-524,共8页
We consider the escape of the particles multi-state noise. It is shown that, the noise can make over fluctuating potential barrier for a system only driven by a the particles escape over the fluctuating potential barr... We consider the escape of the particles multi-state noise. It is shown that, the noise can make over fluctuating potential barrier for a system only driven by a the particles escape over the fluctuating potential barrier in some circumstances; but in other circumstances, it can not. If the noise can make the particle escape over the fluctuating potential barrier, the mean first passage time (MFPT) can display the phenomenon of multi-resonant-activation. For this phenomenon, there are two kinds of resonant activation to appear. One is resonant activation for the MFPTs as the function of the flipping rates of the fluctuating potential barrier; the other is that for the MFPTs as the functions of the transition rates of the multi-state noise. 展开更多
关键词 resonant activation noise mean first passage time
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Entropic Resonant Activation and Stochastic Resonance Driven by Non-Gaussian Noise
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作者 曾春华 王华 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第11期877-884,共8页
The transition rate and stochastic resonance (SR) of a Brownian particle moving in a confined system under the presence of entropic barriers are investigated when the system is driven by non-Gaussian noise. The expl... The transition rate and stochastic resonance (SR) of a Brownian particle moving in a confined system under the presence of entropic barriers are investigated when the system is driven by non-Gaussian noise. The explicit expressions of the transition rate and the speetrai power amplification (SPA) are obtained, respectively. The effects of the parameter q indicating the departure from the Ganssian noise and the correlation time T of the non-Gaussian noise on the transition rate and the SPA are discussed. Research results show that: (i) The transition rate as a function of the noise strength exhibits a maximum. This maximum for transition rate identifies the phenomenon of entropie resonant activation (ERA), the parameter q and the noise correlation time T weaken the ERA of the system; (ii) The curves of SPA appear a transition from one peak to double-peak, and then to one peak again as the noise correlation time T of non-Gaussian noise increases. 展开更多
关键词 non-Gaussian noise confined system entropic resonant activation stochastic resonance
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