For the compromise of mechanical properties and product cost, the end-chilled sand casting technique was applied to studying the microstructure evolution of A356 Al alloy with cooling rate and the effect of different ...For the compromise of mechanical properties and product cost, the end-chilled sand casting technique was applied to studying the microstructure evolution of A356 Al alloy with cooling rate and the effect of different as-cast microstructures on the subsequent solution-treatment process. The experimental results show that the secondary dendrite arm spacing (SDAS) of primaryα(Al), the size of eutectic Si and the volume fraction of Al?Si eutectic are reduced with increasing the cooling rate. Eutectic Si, subjected to solution treatment at 540 °C for 1 h followed by water quenching to room temperature, is completely spheroidized at cooling rate of 2.6 K/s; is partially spheroidized atcooling rate of 0.6 K/s; and is only edge-rounded at cooling rates of 0.22 and 0.12 K /s. Whilst the microhardness is also the maximum at cooling rate of 2.6 K/s. It consequently suggests that subjected to modification by high cooling rate, the eutectic Si is more readily modified, thus shortening the necessary solution time at given solution temperature, i.e., reducing the product cost.展开更多
Trace amount of Sr(0.05 wt.%)was added into the hypoeutectic Al−Si(3−12 wt.%Si)alloys to modify their microstructure and improve thermal conductivity.The results showed that the thermal conductivity of hypoeutectic Al...Trace amount of Sr(0.05 wt.%)was added into the hypoeutectic Al−Si(3−12 wt.%Si)alloys to modify their microstructure and improve thermal conductivity.The results showed that the thermal conductivity of hypoeutectic Al−Si alloys was improved by Sr modification,and the increment and increasing rate of the thermal conductivity gradually increased with Si content increasing.The improvement of thermal conductivity was primarily related to the morphology variation of eutectic Si phases.In Sr-modified Al−Si alloys,the morphology of eutectic Si phases was a mixed morphology of fiber structure and fine flaky structure,and the proportion of the fine flaky eutectic Si phases gradually decreased with Si content increasing.Under the Si content reaching 9 wt.%,the proportion of fine flaky eutectic Si phases was nearly negligible in Sr-modified alloys.Correspondingly,the increment and increasing rate of thermal conductivity of Sr-modified alloys reached the maximum and tended to be stable.展开更多
Eutectic modification of A356 alloy with Li addition was investigated with scanning electron microscopy （SEM） and differential scanning calorimetry （DSC）. SEM micrograph results indicate that the transition of eut...Eutectic modification of A356 alloy with Li addition was investigated with scanning electron microscopy （SEM） and differential scanning calorimetry （DSC）. SEM micrograph results indicate that the transition of eutectic morphology, which is changed from flake-like to fibrous, is dramatically induced with the addition of 0.3% （mass fraction） Li. The larger microhardness corresponds to the modification morphology of the eutectic phase for A356 alloy with 0.3% Li addition. The modification effect is increased with increasing the cooling rate and degraded with prolonging the holding time of temperature. DSC results show that the eutectic solidification temperature of A356 alloy with Li addition is decreased and the eutectic temperature depression with 0.3% Li addition is decreased by 2.9 °C in cast-iron mold. The mixing enthalpies of Li with Si and Al in A356 alloy, which were calculated by the Miedema model, were used to study the mechanism of modification and ascertained its restricted growth theory.展开更多
The solidification microstructure,fracture morphologies,and mechanical properties of an Al-18Si alloy and alloys modified with Al-5Ti and Al-3P master alloys were investigated using an optical microscope,scanning elec...The solidification microstructure,fracture morphologies,and mechanical properties of an Al-18Si alloy and alloys modified with Al-5Ti and Al-3P master alloys were investigated using an optical microscope,scanning electron microscope,and an electronic universal testing machine.The results show that additions of Al-5Ti and Al-3P have significant effects on the size and area fraction of the primary Si and the mechanical properties of the Al-18Si alloy.Compared to the Al-18Si alloy modified with 0.6 wt%Al-5Ti at 850°C,when the Al-18Si alloy was modified with 0.3 wt%Al-5Ti and 0.5 wt%Al-3P at the same temperature,the average size of the primary Si decreased from 39 to 14μm and the area fraction increased from 9.5%to 11.6%.The biggest influencing factor on the tensile strength and elongation of the Al-18Si alloy is the addition of Al-3P,followed by the modification temperature and the addition of Al-5Ti.At a modification temperature of 850°C,the tensile strength and elongation of the Al-18Si alloy modified with 0.3 wt%Al-5Ti+0.5 wt%Al-3P increased by 19.6%and 88.6%,respectively compared to that of the Al-18Si alloy modified with 0.6 wt%Al-5Ti.展开更多
基金Project(2011CB610403)support by the National Basic Research Program of ChinaProjects(51134011,51431008)supported by the National Natural Science Foundation of China+1 种基金Project(JC20120223)supported by the Fundamental Research Fund of Northwestern Polytechnical University,ChinaProject(51125002)supported by the National Funds for Distinguished Young Scientists of China
文摘For the compromise of mechanical properties and product cost, the end-chilled sand casting technique was applied to studying the microstructure evolution of A356 Al alloy with cooling rate and the effect of different as-cast microstructures on the subsequent solution-treatment process. The experimental results show that the secondary dendrite arm spacing (SDAS) of primaryα(Al), the size of eutectic Si and the volume fraction of Al?Si eutectic are reduced with increasing the cooling rate. Eutectic Si, subjected to solution treatment at 540 °C for 1 h followed by water quenching to room temperature, is completely spheroidized at cooling rate of 2.6 K/s; is partially spheroidized atcooling rate of 0.6 K/s; and is only edge-rounded at cooling rates of 0.22 and 0.12 K /s. Whilst the microhardness is also the maximum at cooling rate of 2.6 K/s. It consequently suggests that subjected to modification by high cooling rate, the eutectic Si is more readily modified, thus shortening the necessary solution time at given solution temperature, i.e., reducing the product cost.
基金Project(2013B090500091)supported by Industry-University-Research Combined Project of Guangdong Province,ChinaProject(20180358)supported by the Shenzhen Jiansheng Technology Inc.Cooperation Project,China。
文摘Trace amount of Sr(0.05 wt.%)was added into the hypoeutectic Al−Si(3−12 wt.%Si)alloys to modify their microstructure and improve thermal conductivity.The results showed that the thermal conductivity of hypoeutectic Al−Si alloys was improved by Sr modification,and the increment and increasing rate of the thermal conductivity gradually increased with Si content increasing.The improvement of thermal conductivity was primarily related to the morphology variation of eutectic Si phases.In Sr-modified Al−Si alloys,the morphology of eutectic Si phases was a mixed morphology of fiber structure and fine flaky structure,and the proportion of the fine flaky eutectic Si phases gradually decreased with Si content increasing.Under the Si content reaching 9 wt.%,the proportion of fine flaky eutectic Si phases was nearly negligible in Sr-modified alloys.Correspondingly,the increment and increasing rate of thermal conductivity of Sr-modified alloys reached the maximum and tended to be stable.
基金Project (42-QP-009) supported by the Research Fund of the State Key Laboratory of Solidification Processing, ChinaProject (JC200929) supported by the Fundamental Research Fund of Northwestern Polytechnical University, ChinaProject (B08040) supported by the 111 Project of China
文摘Eutectic modification of A356 alloy with Li addition was investigated with scanning electron microscopy （SEM） and differential scanning calorimetry （DSC）. SEM micrograph results indicate that the transition of eutectic morphology, which is changed from flake-like to fibrous, is dramatically induced with the addition of 0.3% （mass fraction） Li. The larger microhardness corresponds to the modification morphology of the eutectic phase for A356 alloy with 0.3% Li addition. The modification effect is increased with increasing the cooling rate and degraded with prolonging the holding time of temperature. DSC results show that the eutectic solidification temperature of A356 alloy with Li addition is decreased and the eutectic temperature depression with 0.3% Li addition is decreased by 2.9 °C in cast-iron mold. The mixing enthalpies of Li with Si and Al in A356 alloy, which were calculated by the Miedema model, were used to study the mechanism of modification and ascertained its restricted growth theory.
基金Project(51571039) supported by the National Natural Science Foundation of China
文摘The solidification microstructure,fracture morphologies,and mechanical properties of an Al-18Si alloy and alloys modified with Al-5Ti and Al-3P master alloys were investigated using an optical microscope,scanning electron microscope,and an electronic universal testing machine.The results show that additions of Al-5Ti and Al-3P have significant effects on the size and area fraction of the primary Si and the mechanical properties of the Al-18Si alloy.Compared to the Al-18Si alloy modified with 0.6 wt%Al-5Ti at 850°C,when the Al-18Si alloy was modified with 0.3 wt%Al-5Ti and 0.5 wt%Al-3P at the same temperature,the average size of the primary Si decreased from 39 to 14μm and the area fraction increased from 9.5%to 11.6%.The biggest influencing factor on the tensile strength and elongation of the Al-18Si alloy is the addition of Al-3P,followed by the modification temperature and the addition of Al-5Ti.At a modification temperature of 850°C,the tensile strength and elongation of the Al-18Si alloy modified with 0.3 wt%Al-5Ti+0.5 wt%Al-3P increased by 19.6%and 88.6%,respectively compared to that of the Al-18Si alloy modified with 0.6 wt%Al-5Ti.
