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Al_2O_3-ZrO_2复合纳米超微粉的制备及其特性研究 被引量:9
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作者 陈大明 彭应国 +3 位作者 李斌太 张晨 孟国文 康沫狂 《金属热处理学报》 EI CSCD 2000年第2期36-41,共6页
以高纯铝屑和氯氧化锆为主要原料 ,用化学共沉淀—凝胶工艺分别制备出平均粒径约10nm的纯ZrO2 、Al2 O3 50ZrO2 、Al2 O3 2 0ZrO2 三种纳米超微粉 ,其中ZrO2 基本以t相结构存在。在不同温度煅烧后 ,纯ZrO2 粉粒迅速长大而转变为单斜相 ,... 以高纯铝屑和氯氧化锆为主要原料 ,用化学共沉淀—凝胶工艺分别制备出平均粒径约10nm的纯ZrO2 、Al2 O3 50ZrO2 、Al2 O3 2 0ZrO2 三种纳米超微粉 ,其中ZrO2 基本以t相结构存在。在不同温度煅烧后 ,纯ZrO2 粉粒迅速长大而转变为单斜相 ,Al2 O3 ZrO2 复合粉粒长大困难 ,并使ZrO2 仍主要以四方相存在 ,Al2 O3以非晶态存在。表明ZrO2 纳米粉粒以四方相在室温下稳定存在的原因是尺寸效应造成的。 展开更多
关键词 AL2O3-ZRO2 纳米粉 共沉淀-凝胶法 相结构
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Target effects on electrical properties and laser induced voltages of La_(0.72)Ca_(0.28)MnO_3 thin films prepared by pulsed laser deposition
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作者 张辉 王文章 +4 位作者 崔琦 业冬 马吉 陈清明 刘翔 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第2期465-470,共6页
La0.72Ca0.28MnO3 thin films were deposited on untilted and 15° tilted LaAlO_3 (100) single crystalline substrates by pulsed laser deposition. The polycrystalline targets used in the deposition process were synt... La0.72Ca0.28MnO3 thin films were deposited on untilted and 15° tilted LaAlO_3 (100) single crystalline substrates by pulsed laser deposition. The polycrystalline targets used in the deposition process were synthesized by sol-gel and coprecipitation methods, respectively. The structure, electrical transport properties and surface morphology of the targets and films were studied. It is found that, compared with coprecipitation method, the sol-gel target has more homogeneous components and larger density and grain size, thus the higher insulator-metal transition temperature and larger temperature coefficient of resistivity. The thin film prepared by sol-gel target has a uniform grain size and higher quality. The metal-insulator transition temperature is higher and the laser induced voltage signal is larger. Preparing the target by sol-gel method can largely improve the properties of corresponding thin films in pulsed laser deposition process. 展开更多
关键词 La0.72Ca0.28MnO3 TARGET thin film sol-gel method coprecipitation method
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