This paper analyzes the possibility of applying binary nonazeotropic refrigerants in the jet refrigeration cycle. The thermodynamic cycle performance of two kinds of working pairs (R30/R142b, R30/R124) are calculated ...This paper analyzes the possibility of applying binary nonazeotropic refrigerants in the jet refrigeration cycle. The thermodynamic cycle performance of two kinds of working pairs (R30/R142b, R30/R124) are calculated using the EOS of PR equation of state, and the results are discussed. The theoretical calculations indicate that refrigerating quality can be improved if the binary mixtures evaporate just in the low temperature region. The character of the rejecter to compress two phase medium supports the possibility of this kind of cycle.展开更多
Three ionic liquids(ILs),1-ethyl-3-methylimidazolium bromine([EMIM]Br),1-butyl-3-methylimidazolium bromine([BMIM]Br),and 1-hexyl-3-methylimidazolium bromine([HMIM]Br),were used as the solvent for separation of {tert-b...Three ionic liquids(ILs),1-ethyl-3-methylimidazolium bromine([EMIM]Br),1-butyl-3-methylimidazolium bromine([BMIM]Br),and 1-hexyl-3-methylimidazolium bromine([HMIM]Br),were used as the solvent for separation of {tert-butyl alcohol(TBA)+ water} azeotrope.Vapor–liquid equilibrium(VLE)data for {TBA + water + IL}ternary systems were measured at 101.3 k Pa.The results indicate that all the three ILs produce an obvious effect on the VLE behavior of {TBA + water} system and eliminate the azeotropy in the whole concentration range.[EMIM]Br is the best solvent for the separation of {TBA + water} system by extractive distillation among the three ILs.The experimental VLE data for the ternary systems are correlated with the NRTL model equation with good correlations.Explanations are given with activity coefficients of water and TBA,and the experimental VLE-temperature data for {TBA or water + IL} binary systems.展开更多
With the energy parameters obtained from1H nuclear magnetic resonance(NMR)chemical shifts data by local composition model and coupled with azeotropic point,the low-pressure vapor-liquid equilibrium is satisfactorily p...With the energy parameters obtained from1H nuclear magnetic resonance(NMR)chemical shifts data by local composition model and coupled with azeotropic point,the low-pressure vapor-liquid equilibrium is satisfactorily predicted for alcohol+hexane,alcohol+cyclohexane,and alcohol+benzene binary systems at different temperatures.The relationship between the spectroscopic information and thermodynamic property is presented.展开更多
文摘This paper analyzes the possibility of applying binary nonazeotropic refrigerants in the jet refrigeration cycle. The thermodynamic cycle performance of two kinds of working pairs (R30/R142b, R30/R124) are calculated using the EOS of PR equation of state, and the results are discussed. The theoretical calculations indicate that refrigerating quality can be improved if the binary mixtures evaporate just in the low temperature region. The character of the rejecter to compress two phase medium supports the possibility of this kind of cycle.
基金Supported by the National Natural Science Foundation of China(21076126)the Program for Liaoning Excellent Talents in University(2012013)the Liaoning Province Science Foundation of China(2014020140)
文摘Three ionic liquids(ILs),1-ethyl-3-methylimidazolium bromine([EMIM]Br),1-butyl-3-methylimidazolium bromine([BMIM]Br),and 1-hexyl-3-methylimidazolium bromine([HMIM]Br),were used as the solvent for separation of {tert-butyl alcohol(TBA)+ water} azeotrope.Vapor–liquid equilibrium(VLE)data for {TBA + water + IL}ternary systems were measured at 101.3 k Pa.The results indicate that all the three ILs produce an obvious effect on the VLE behavior of {TBA + water} system and eliminate the azeotropy in the whole concentration range.[EMIM]Br is the best solvent for the separation of {TBA + water} system by extractive distillation among the three ILs.The experimental VLE data for the ternary systems are correlated with the NRTL model equation with good correlations.Explanations are given with activity coefficients of water and TBA,and the experimental VLE-temperature data for {TBA or water + IL} binary systems.
基金Supported by the Research Project Foundation of the Education Department of Zhejiang Province （20061157）, the Natural Science Foundation of Zhejiang Province （Y4090453）, and the Key Research Project Foundation of Shaoxing University.
文摘With the energy parameters obtained from1H nuclear magnetic resonance(NMR)chemical shifts data by local composition model and coupled with azeotropic point,the low-pressure vapor-liquid equilibrium is satisfactorily predicted for alcohol+hexane,alcohol+cyclohexane,and alcohol+benzene binary systems at different temperatures.The relationship between the spectroscopic information and thermodynamic property is presented.
