A robust oxygen‐related electrocatalyst,composed of spinel iron‐cobalt oxide and nitrogen‐dopedordered mesoporous carbon(NOMC),was developed for rechargeable metal‐air batteries.Electrochemicaltests revealed that ...A robust oxygen‐related electrocatalyst,composed of spinel iron‐cobalt oxide and nitrogen‐dopedordered mesoporous carbon(NOMC),was developed for rechargeable metal‐air batteries.Electrochemicaltests revealed that the optimal catalyst Fe_(0.5)Co/NOMC exhibits superior activity with ahalf‐wave potential of 0.89 V(vs.reversible hydrogen electrode)for the oxygen reduction reactionand an overpotential of 0.31 V at 10 mA cm^(−2)for the oxygen evolution reaction.For demonstration,the catalyst was used in the assembly of a rechargeable zinc‐air battery,which exhibited an exceptionallyhigh energy density of 820 Wh kg−1 at 100 mA cm^(−2),a high power density of 153 mW cm^(−2)at1.0 V,and superior cycling stability up to 432 cycles(144 h)under ambient air.展开更多
A new algorithm namely the interval sampling method, applicable to the analysisof steady-state simulation output is proposed. This algorithm uses the time series analysisto carry out conrrelation analysis of the stead...A new algorithm namely the interval sampling method, applicable to the analysisof steady-state simulation output is proposed. This algorithm uses the time series analysisto carry out conrrelation analysis of the steady-state simulation output so as to obtain theobservation data which are actually uncorrelated in nature. On the basis of theseuncorrelated data gathered, some satisfactory deductions cam be made on the data under re search. A comparison between batch means method and the interval sampling method hasbeen performed by taking the M/M/l queuing system as an example. The results attestedthat the interval sampling method is mere accurate than the batch means method.展开更多
文摘A robust oxygen‐related electrocatalyst,composed of spinel iron‐cobalt oxide and nitrogen‐dopedordered mesoporous carbon(NOMC),was developed for rechargeable metal‐air batteries.Electrochemicaltests revealed that the optimal catalyst Fe_(0.5)Co/NOMC exhibits superior activity with ahalf‐wave potential of 0.89 V(vs.reversible hydrogen electrode)for the oxygen reduction reactionand an overpotential of 0.31 V at 10 mA cm^(−2)for the oxygen evolution reaction.For demonstration,the catalyst was used in the assembly of a rechargeable zinc‐air battery,which exhibited an exceptionallyhigh energy density of 820 Wh kg−1 at 100 mA cm^(−2),a high power density of 153 mW cm^(−2)at1.0 V,and superior cycling stability up to 432 cycles(144 h)under ambient air.
文摘A new algorithm namely the interval sampling method, applicable to the analysisof steady-state simulation output is proposed. This algorithm uses the time series analysisto carry out conrrelation analysis of the steady-state simulation output so as to obtain theobservation data which are actually uncorrelated in nature. On the basis of theseuncorrelated data gathered, some satisfactory deductions cam be made on the data under re search. A comparison between batch means method and the interval sampling method hasbeen performed by taking the M/M/l queuing system as an example. The results attestedthat the interval sampling method is mere accurate than the batch means method.