期刊文献+
共找到4篇文章
< 1 >
每页显示 20 50 100
多孔催化剂颗粒的内扩散效应对伴有失活的二级反应动力学的影响 被引量:2
1
作者 王庆祺 张国泰 吴指南 《化工学报》 EI CAS CSCD 北大核心 1992年第1期82-90,共9页
采用正交配置等数学方法,研究在均匀独立失活的催化反应系统中,内扩散效应对等温球形催化剂失活速率的影响,建立适用于任何内扩散区域的二级反应、m级失活系统的失活有效因子和失活西勒模数的定量关系,对n级反应、m级失活系统也作了相... 采用正交配置等数学方法,研究在均匀独立失活的催化反应系统中,内扩散效应对等温球形催化剂失活速率的影响,建立适用于任何内扩散区域的二级反应、m级失活系统的失活有效因子和失活西勒模数的定量关系,对n级反应、m级失活系统也作了相应地推广.运用加压微反-色谱-数据处理机联合装置,通过分析在原颗粒丝光沸石催化剂上进行的临氢甲苯歧化反应的失活数据,研究了内扩散对二级反应失活动力学的影响规律.同时,在实验范围内,建立了一套内扩散存在下的甲苯歧化失活动力学模型. 展开更多
关键词 内扩散效应 催化剂 失活 动力学
下载PDF
自絮凝颗粒酵母表观生长动力学 被引量:2
2
作者 尹冬丽 刘晨光 +2 位作者 李凡 葛旭萌 白凤武 《化工学报》 EI CAS CSCD 北大核心 2011年第11期3149-3155,共7页
首先利用激光聚焦反射颗粒测量系统在线监测了自絮凝颗粒酵母粒径分布,通过提高发酵罐搅拌速率减小了颗粒粒径,消除了内扩散影响,获得了本征动力学模型。进而基于颗粒内部薄壳物料衡算理论,建立了表观动力学模型,并通过不同底物浓度和... 首先利用激光聚焦反射颗粒测量系统在线监测了自絮凝颗粒酵母粒径分布,通过提高发酵罐搅拌速率减小了颗粒粒径,消除了内扩散影响,获得了本征动力学模型。进而基于颗粒内部薄壳物料衡算理论,建立了表观动力学模型,并通过不同底物浓度和自絮凝酵母颗粒粒径分布条件下发酵实验数据拟合,获得了模型的参数。在此基础上,分析了内扩散效应导致颗粒内部可能出现死区的影响,绘制了发酵培养基初始糖和自絮凝颗粒酵母粒径影响的操作图,分析了这一发酵体系的性能。结果表明对于工业生产中普遍采用的多级串联连续乙醇发酵系统,主发酵罐和后发酵罐由于残糖水平差别较大,使颗粒内部因底物枯竭而导致内扩散效应的可能性显著不同:主发酵罐适宜于较大粒径自絮凝颗粒酵母体系,以利于固定化,提高发酵罐中细胞密度和生产强度;而后发酵罐适宜于较小粒径自絮凝颗粒酵母,以减轻底物内扩散影响,保持所需的发酵活性。因此需要综合考虑工程操作和动力学行为,对自絮凝颗粒酵母粒径分布进行优化控制。 展开更多
关键词 自絮凝颗粒酵母 本征与表观动力学 内扩散效应
下载PDF
Effect of Seed Coat on Drying Kinetics of Kidney Bean Seed
3
作者 杨俊红 郭锦棠 +3 位作者 段增宾 刘冰 褚治德 吴树民 《Transactions of Tianjin University》 EI CAS 2002年第4期273-276,共4页
Kidney bean seed was dried in a laboratory scale fixed bed. The effect of seed coat on drying dynamic characteristics and the changes of seed coat structure were investigated. A mathematical model was established to s... Kidney bean seed was dried in a laboratory scale fixed bed. The effect of seed coat on drying dynamic characteristics and the changes of seed coat structure were investigated. A mathematical model was established to simulate the drying process and determine the moisture diffusivity. Numerical results agree well with the experimental data. The average moisture diffusivity of the seed with separated coat is 1.67 times larger than that of the seed with coat, and the moisture diffusivity of seed cotyledon is 3.2 times larger than that of the seed coat. It is proved that the seed coat is the most main resistance of mass transfer and is also one of the key points of the optimization of heat and mass transfer for seed drying. 展开更多
关键词 seed drying seed coat effect internal moisture diffusion model moisture diffusivity
下载PDF
Diffusion and Reaction Model of Catalyst Pellets for Fischer-Tropsch Synthesis 被引量:1
4
作者 Wu Jianmin Sun Qiwen +1 位作者 Zhang Zongsen Pang Lifeng 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2013年第4期77-86,共10页
The diffusion and reaction phenomenon in a Fe-based catalyst pellet for Fischer-Tropsch synthesis was studied. It was considered that the pores of catalyst pellets were full of liquid wax under Fischer-Tropsch synthes... The diffusion and reaction phenomenon in a Fe-based catalyst pellet for Fischer-Tropsch synthesis was studied. It was considered that the pores of catalyst pellets were full of liquid wax under Fischer-Tropsch synthesis conditions. The re- actants diffused from the bulk gas phase to the external surface of the pellet, and then the reactants diffused through the wax inside the pellet and reacted on the internal surface formed along the pore passages of the pellet. On the basis of reaction kinetics and double a-ASF product distribution model, a diffusion and reaction model of catalyst pellet was established. The effects of diffusion and reaction interaction in a catalyst pellet, the bulk temperature, the reaction pressure and the pellet size on the reactivity were further investigated. The relationship between the internal diffusion effectiveness factor of spherical catalyst pellet and the Thiele modulus were also discussed. The bulk temperature and pellet size have significant effects on the reactivity, while the pressure shows only a slight influence on the reactivity. The internal diffusion effectiveness factor decreases with an increasing Thiele modulus. 展开更多
关键词 Fischer-Tropsch synthesis diffusion and reaction catalyst pellet internal diffusion effectiveness factor
下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部