蒸发气(Boil Off Gas,缩写为BOG)的处理是LNG接收站必须考虑的关键问题之一,关系着LNG接收站的能耗及安全、平稳运行。为此,介绍了LNG接收站BOG处理的4种工艺:①BOG直接压缩工艺;②BOG再冷凝液化工艺;③BOG间接热交换再液化工艺;④蓄冷...蒸发气(Boil Off Gas,缩写为BOG)的处理是LNG接收站必须考虑的关键问题之一,关系着LNG接收站的能耗及安全、平稳运行。为此,介绍了LNG接收站BOG处理的4种工艺:①BOG直接压缩工艺;②BOG再冷凝液化工艺;③BOG间接热交换再液化工艺;④蓄冷式BOG再液化工艺。运用HYSYS软件建立了采用不同BOG处理工艺的LNG接收站模型,对比了目前主要采用的BOG直接压缩工艺和再冷凝液化工艺在工艺流程及能耗方面的差异,并分析了外输量、外输压力及再冷凝器压力对BOG处理工艺节能效果的影响,在此基础上提出了BOG再冷凝液化工艺的改进措施——BOG进入再冷凝器前进行预冷,可比原工艺节约18.2%的能耗。同时还针对青岛LNG接收站提出了BOG再冷凝液化及直接压缩工艺混合使用的优化运行方案,可使进入再冷凝器的LNG流量保持恒定,没被冷凝的BOG经过高压压缩机提压到外输压力,与完成气化的LNG混合后外输,可避免BOG进入火炬系统而造成的能源浪费,同时减小再冷凝器入口流量的波动,使装置运行更稳定、更经济。展开更多
A carbon-based sulfonated catalyst was prepared by direct sulfonation and carbonization (in moderate conditions:200 °C, 12 h) of red liquor solids, a by-product of paper-making process. The prepared sulfonate...A carbon-based sulfonated catalyst was prepared by direct sulfonation and carbonization (in moderate conditions:200 °C, 12 h) of red liquor solids, a by-product of paper-making process. The prepared sulfonated cata-lyst (SC) had aromatic structure, composed of carbon enriched inner core, and oxygen-containing (SO3H, COOH, OH) groups enriched surface. The SO3H, COOH, OH groups amounted to 0.74 mmol·g^-1, 0.78 mmol·g^-1, 2.18 mmol·g^-1, respectively. The fresh SC showed much higher catalytic activity than that of the traditional solid acid catalysts (strong-acid 732 cation exchange resin, hydrogen type zeolite socony mobile-five (HZSM-5), sulfated zir-conia) in esterification of oleic acid. SC was deactivated during the reactions, through the mechanisms of leaching of sulfonated species and formation of sulfonate esters. Two regeneration methods were developed, and the catalytic activity can be mostly regenerated by regeneration Method 1 and be fully regenerated by regeneration Method 2, respectively.展开更多
A sequential three-step programming method is proposed for determining the minimum flowrate of fresh water and corresponding regenerated water in water-using system of single contaminant with regeneration reuse. In st...A sequential three-step programming method is proposed for determining the minimum flowrate of fresh water and corresponding regenerated water in water-using system of single contaminant with regeneration reuse. In step 1, a programming with the objective of min fws is used to determine the minimum flowrate of fresh water, in which the mathematical representation is a mixed integer nonlinear programming (MINLP1). Then under the same constraints with step 1, a programming with the objective of min freg in step 2 and a programming with the objective of min Cr in step 3 are subsequently used to determine the minimum flowrate of regenerated water and the minimum inlet concentration to regeneration process corresponding to the minimum flowrate of fresh water based on step 1. The method is easy to apply because we only need to change the objective function but keep the constraints constant to go along the following steps after step 1. In addition, the relationship between the fresh water flowrate required, fws and inlet concentration to regeneration process, Cr, is investigated. It is found that there exist three relationships between fws and Cr, which indicate three possibilities for C\>: below the pinch, above the pinch or at the pinch. Therefore, a new conclusion is drawn, which differs from that 'regeneration of water at pinch minimizes fresh water flowrate' derived in literature and indicates that in some cases, regeneration at other point also minimizes fresh water flowrate.展开更多
A carbon-based sulfonated catalyst was prepared by direct sulfonation and carbonization (in moderate conditions:200 °C, 12 h) of red liquor solids, a by-product of paper-making process. The prepared sulfonate...A carbon-based sulfonated catalyst was prepared by direct sulfonation and carbonization (in moderate conditions:200 °C, 12 h) of red liquor solids, a by-product of paper-making process. The prepared sulfonated cata-lyst (SC) had aromatic structure, composed of carbon enriched inner core, and oxygen-containing (SO3H, COOH, OH) groups enriched surface. The SO3H, COOH, OH groups amounted to 0.74 mmol·g^-1, 0.78 mmol·g^-1, 2.18 mmol·g^-1, respectively. The fresh SC showed much higher catalytic activity than that of the traditional solid acid catalysts (strong^-acid 732 cation exchange resin, hydrogen type zeolite socony mobile-five (HZSM-5), sulfated zir-conia) in esterification of oleic acid. SC was deactivated during the reactions, through the mechanisms of leaching of sulfonated species and formation of sulfonate esters. Two regeneration methods were developed, and the catalytic activity can be mostly regenerated by regeneration Method 1 and be fully regenerated by regeneration Method 2, respectively.展开更多
In this Paper, the continuous electroregeneration of ion exchange resin is investegated. The mixed resin is inserted between a canon exchange membrane and an auto n exchange membrane. The effuent water of fresh water ...In this Paper, the continuous electroregeneration of ion exchange resin is investegated. The mixed resin is inserted between a canon exchange membrane and an auto n exchange membrane. The effuent water of fresh water room meets the demand for power plant on water treatment. The B_2 that is the cumulative formation constant of the metal complexes of resin is very differente with or without electric fied. It indicates that the dissociation degree of metal complexes of resin is greater hath electric field than that without electric field.展开更多
A fluctuating flow was used to investigate the thermo-fluid characteristic of a regenerative heat exchanger assembly designed, modelled, built and constructed for the used in Stifling engines applications. Vibration o...A fluctuating flow was used to investigate the thermo-fluid characteristic of a regenerative heat exchanger assembly designed, modelled, built and constructed for the used in Stifling engines applications. Vibration of the regenerative heat exchanger assembly was a problem to deal with during the experimental investigation. Hence, a dynamic analysis of the regenerative heat exchanger assembly was undertaken. The main sources of excitation in vibrations of the regenerative heat exchanger assembly were investigated and calculated based initially on the empirical correlations provided in the literature. Thereafter, a mathematical model of the regenerative heat exchanger assembly was developed based on the energy equations for each moving part of the assembly. The kinetic and potential energy equations were formulated for each moving part of the regenerative heat exchanger assembly. From the kinetic and potential equations, the Lag, range operator was defined, and then the Lagrange formulations were used to derive the differential equations representing the dynamic behavior of each moving part of the assembly. The differential equations were integrated to determine the system natural frequencies. These were then compared to the frequency on excitation in vibrations in order to predict the regenerative heat exchanger working conditions despite the existence of vibration in the system.展开更多
文摘蒸发气(Boil Off Gas,缩写为BOG)的处理是LNG接收站必须考虑的关键问题之一,关系着LNG接收站的能耗及安全、平稳运行。为此,介绍了LNG接收站BOG处理的4种工艺:①BOG直接压缩工艺;②BOG再冷凝液化工艺;③BOG间接热交换再液化工艺;④蓄冷式BOG再液化工艺。运用HYSYS软件建立了采用不同BOG处理工艺的LNG接收站模型,对比了目前主要采用的BOG直接压缩工艺和再冷凝液化工艺在工艺流程及能耗方面的差异,并分析了外输量、外输压力及再冷凝器压力对BOG处理工艺节能效果的影响,在此基础上提出了BOG再冷凝液化工艺的改进措施——BOG进入再冷凝器前进行预冷,可比原工艺节约18.2%的能耗。同时还针对青岛LNG接收站提出了BOG再冷凝液化及直接压缩工艺混合使用的优化运行方案,可使进入再冷凝器的LNG流量保持恒定,没被冷凝的BOG经过高压压缩机提压到外输压力,与完成气化的LNG混合后外输,可避免BOG进入火炬系统而造成的能源浪费,同时减小再冷凝器入口流量的波动,使装置运行更稳定、更经济。
基金Supported by the National Natural Science Foundation of China(21276076)the Fundamental Research Funds for the Central Universities of China(WA1014003)State Key Laboratory of Chemical Engineering(SKL-ChE-10C06)
文摘A carbon-based sulfonated catalyst was prepared by direct sulfonation and carbonization (in moderate conditions:200 °C, 12 h) of red liquor solids, a by-product of paper-making process. The prepared sulfonated cata-lyst (SC) had aromatic structure, composed of carbon enriched inner core, and oxygen-containing (SO3H, COOH, OH) groups enriched surface. The SO3H, COOH, OH groups amounted to 0.74 mmol·g^-1, 0.78 mmol·g^-1, 2.18 mmol·g^-1, respectively. The fresh SC showed much higher catalytic activity than that of the traditional solid acid catalysts (strong-acid 732 cation exchange resin, hydrogen type zeolite socony mobile-five (HZSM-5), sulfated zir-conia) in esterification of oleic acid. SC was deactivated during the reactions, through the mechanisms of leaching of sulfonated species and formation of sulfonate esters. Two regeneration methods were developed, and the catalytic activity can be mostly regenerated by regeneration Method 1 and be fully regenerated by regeneration Method 2, respectively.
基金Supported by the National Fundamental Research Development Program of China(No.2000026308).
文摘A sequential three-step programming method is proposed for determining the minimum flowrate of fresh water and corresponding regenerated water in water-using system of single contaminant with regeneration reuse. In step 1, a programming with the objective of min fws is used to determine the minimum flowrate of fresh water, in which the mathematical representation is a mixed integer nonlinear programming (MINLP1). Then under the same constraints with step 1, a programming with the objective of min freg in step 2 and a programming with the objective of min Cr in step 3 are subsequently used to determine the minimum flowrate of regenerated water and the minimum inlet concentration to regeneration process corresponding to the minimum flowrate of fresh water based on step 1. The method is easy to apply because we only need to change the objective function but keep the constraints constant to go along the following steps after step 1. In addition, the relationship between the fresh water flowrate required, fws and inlet concentration to regeneration process, Cr, is investigated. It is found that there exist three relationships between fws and Cr, which indicate three possibilities for C\>: below the pinch, above the pinch or at the pinch. Therefore, a new conclusion is drawn, which differs from that 'regeneration of water at pinch minimizes fresh water flowrate' derived in literature and indicates that in some cases, regeneration at other point also minimizes fresh water flowrate.
基金Supported by the State Key Development Program for Basic Research of China(2013CB228104,2010CB732205)Ph.D Programs Foundation of Ministry of Education of China(20120172110011)the National High Technology Research and Development Program of China(2012AA051801)
文摘A carbon-based sulfonated catalyst was prepared by direct sulfonation and carbonization (in moderate conditions:200 °C, 12 h) of red liquor solids, a by-product of paper-making process. The prepared sulfonated cata-lyst (SC) had aromatic structure, composed of carbon enriched inner core, and oxygen-containing (SO3H, COOH, OH) groups enriched surface. The SO3H, COOH, OH groups amounted to 0.74 mmol·g^-1, 0.78 mmol·g^-1, 2.18 mmol·g^-1, respectively. The fresh SC showed much higher catalytic activity than that of the traditional solid acid catalysts (strong^-acid 732 cation exchange resin, hydrogen type zeolite socony mobile-five (HZSM-5), sulfated zir-conia) in esterification of oleic acid. SC was deactivated during the reactions, through the mechanisms of leaching of sulfonated species and formation of sulfonate esters. Two regeneration methods were developed, and the catalytic activity can be mostly regenerated by regeneration Method 1 and be fully regenerated by regeneration Method 2, respectively.
文摘In this Paper, the continuous electroregeneration of ion exchange resin is investegated. The mixed resin is inserted between a canon exchange membrane and an auto n exchange membrane. The effuent water of fresh water room meets the demand for power plant on water treatment. The B_2 that is the cumulative formation constant of the metal complexes of resin is very differente with or without electric fied. It indicates that the dissociation degree of metal complexes of resin is greater hath electric field than that without electric field.
文摘A fluctuating flow was used to investigate the thermo-fluid characteristic of a regenerative heat exchanger assembly designed, modelled, built and constructed for the used in Stifling engines applications. Vibration of the regenerative heat exchanger assembly was a problem to deal with during the experimental investigation. Hence, a dynamic analysis of the regenerative heat exchanger assembly was undertaken. The main sources of excitation in vibrations of the regenerative heat exchanger assembly were investigated and calculated based initially on the empirical correlations provided in the literature. Thereafter, a mathematical model of the regenerative heat exchanger assembly was developed based on the energy equations for each moving part of the assembly. The kinetic and potential energy equations were formulated for each moving part of the regenerative heat exchanger assembly. From the kinetic and potential equations, the Lag, range operator was defined, and then the Lagrange formulations were used to derive the differential equations representing the dynamic behavior of each moving part of the assembly. The differential equations were integrated to determine the system natural frequencies. These were then compared to the frequency on excitation in vibrations in order to predict the regenerative heat exchanger working conditions despite the existence of vibration in the system.