废次钛白粉硫酸法再制备TiO_2工艺条件的研究

研究了废次钛白粉硫酸法再制备锐钛型TiO2的工艺条件。通过试验确定了最佳的工艺条件，为在现有硫酸法钛白生产线上进行工业化生产提供依据，也为废次钛白再生产找到了可行的途径。比较了本工艺与硫酸法钛白生产的工艺条件得知，本工艺可省去絮凝净化。冷冻结晶两工序，洗涤、过滤的时间也大大缩短。

锂离子电池正极材料的回收及再制备

通过湿化学法从废旧锂离子电池中回收得到Li+、Co2+的硝酸溶液,以此为钴源,与Ni(NO3)2.6H2O、Mn(NO3)2按化学计量比混合,用草酸盐共沉淀法制备草酸盐前驱体,然后按Li过量5%加入Li2CO3混合,在空气中于800～950°C煅烧15 h得LiCo1/3Mn1/3Ni1/3O2,研究了煅烧温度对材料结构、形貌以及电化学性能的影响。结果表明,900℃保温15 h制备的LiCo1/3Mn1/3Ni1/3O2正极材料,为理想的(α-NaFeO2层状结构,颗粒为大小均匀的球形,在2.5～4.3 V的电压范围内,以0.1 C的恒定电流进行充放电,其首次充放电比容量分别为194.3和150.9 mAh/g,10次循环之后的容量保持率为89.9%,放电比容量为135.0 mAh/g。

废旧聚丙烯再制备用于新型建筑模板的研究进展

综述了国内外废旧聚丙烯再制备技术及新型建筑模板的研究进展。新型聚丙烯(PP)建筑模板是一类绿色高效的环保型模板产品,与常用的其他建筑模板相比,其具有生产能耗较低,可循环利用次数高,脱模容易、劳动强度低等显著优势。因此,新型PP系列化建筑模板具有很强的竞争优势,发展前景和应用范围极为广阔。

一种智能轮胎柔性应变传感器及其制备方法

由广东粤港澳大湾区黄埔材料研究院申请的专利(公布号CN 115682913A,公布日期2023-02-03)“一种智能轮胎柔性应变传感器及其制备方法”,公开了一种智能轮胎柔性应变传感器及其制备方法。本发明智能轮胎柔性应变传感器的下基底层为轮胎内胎面,在制备轮胎内胎面时,通过模具压印出智能轮胎柔性应变传感器的内嵌凹槽,再制备电阻层、加装电极以及封装层。

Research on Protoplast Preparation and Regeneration Conditions of Tremella aurantialba

[Objective] This study aimed to explore the protoplast preparation and re- generation conditions of Tremella aurantialba. [Method] Optimal combination of five factors affecting the protoplast preparation and regeneration of Tremella aurantialba was selected by using orthogonal experiment, including enzyme system, culture age, enzymolysis temperature, enzymolysis duration and osmotic stabilizer. [Result] The results showed that there were three release modes of Tremella aurantialba proto- plasts： release from top in the early period of enzymolysis, release from the side and release in situ. The optimal protoplast preparation condition was selecting mycelium cultured in liquid medium for 3 d, for enzymolysis in mixed enzyme solu- tion containing 1% of cellulase ＋1% of snailase ＋1% of lywallzyme at 36 ℃; for 4 h, with 0.6 mol/L sucrose as osmotic stabilizer, and the obtained preparation rate had reached 1.76 ×10^7 protoplasts/ml. The optimal regeneration condition was using mycelium cultured in liquid medium for 5 d, for enzymolysis in enzyme solution con- taining 1.5% of lywallzyme at 33 ℃ for 3 h, with 0.6 mol/L sucrose as osmotic sta- bilizer, and the regeneration rate had reached 0.22%. [Conclusion] This study provid- ed valuable support for protoplast fusion, ultraviolet mutation breeding and genetic engineering research.

Preparation and characteristics of a recycled cement-based superhydrophobic coating with dirt pickup resistance

We introduce a low-cost and effective technique that can transform waste cement-based dust into a superhydrophobic coating with dirt pickup resistance. An organic-inorganic hybrid superhydrophobic coating is prepared by the sol-gel method using methyltriethoxysilane as a precursor and waste cement-based dust as a film-forming material. Orthogonal experiments and a comprehensive scoring method were used to optimize the composition and production technologies. Our results show that this superhydrophobic organic-inorganic hybrid coating has an average static contact angle of 151.65° and low water adhesion. Related tests reveal that the dirt pickup resistance, washing resistance and film-substrate cohesion of this coating are also outstanding. The multi-scale physical and chemical mechanisms behind the properties of the coating are investigated. This recycled cement-based coating can be used as the external cover of engineering structures to protect them from corrosion.

Fabrication and Properties of Poly(vinylalcohol)-glycosaminoglycantype I Collagen Composite Membrane as Tissue Regeneration Scaffolds

The objective of this paper is to design a based on composite membrane with certain mechanical porous polyvinyl alcohol （PVA） strength and biocompatibilities serving as tissue regenerative scaffolds. PVA-glycosaminoglycan （GAG）-type I collagen （COL） composite membrane was fabricated by PVA with different molecular weight （Mw） and alcoholysis degree （AD） being blended with certain amounts of GAG and COL and dried at 38~C for 24 h. The water content of the composite membranes were from 61.9% to 95.1% and swelling ratio ranged from 123.6% to 621.7%. Scanning electron micro- scope （SEM） analysis proved that PVA-GAG-COL composite membrane has porous and homogenous structure. Biocompatibility test results showed that the composite membrane was nontoxic, which could promote adhesion and proliferation of fibroblasts on the com- posite membrane. In conclusion, PVA-GAG-COL composite membrane with high water content and swelling ratio, suitable mechanical strength and good biocompatibility, has potential in tissue engineering and regenerative medicine.

Utilizing biodegradable alloys as guided bone regeneration(GBR)membrane:Feasibility and challenges

Guided bone regeneration(GBR)is a therapeutic procedure used to enhance alveolar bone volume before dental implants.Commercial non-absorbable membranes(i.e.,titanium membranes)typically require a second surgery to remove,whereas absorbable membranes(i.e.,collagen membranes)will fail when put over extensive bone lesions due to their low mechanical strength.The GBR membrane that has been sought is still being developed.Biodegradable metals(BMs),particularly Mg and Zn,have recently been postulated as promising barrier membrane candidates.Herein,the goal of this research is to evaluate the mechanical and biological feasibility of using BMs as GBR membranes.It shows that BMs have a wide range of potential applications as GBR membranes,owing to their benign biocompatibility,sufficient mechanical support,tunable degradation rate,good osteogenic capabilities,broad-spectrum antibacterial behavior,and improved wound healing ability.The rapid degradation rate,hydrogen evolution impact,and stress corrosion cracking behavior all pose obstacles to the use of Mg-based membranes,which can be improved by surface modifications,heat treatment,alloying,etc.Due to its acceptable degradation rate and lack of gas production,Zn appears to be a better candidate for usage as a GBR membrane.In general,advances in the development of BMs have paved the door for BMs to be used as GBR membranes in oral clinical trials.