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氟化镧电极再活化机理的讨论
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作者 石生勋 《化学传感器》 CAS 1997年第3期237-239,共3页
本文推断和验证了旧氟化镧电极在一定浓度的NaOH溶液中浸泡一定时间,使OH^-与LaF_3单晶膜发生作用,表面形成La(OH)_3,同时置换出F^-,然后取出电极,用二次去离子水洗掉LaF_3电极表面的NaOH,使OH与LaF_3单晶膜终止反应,再放入二次去离子... 本文推断和验证了旧氟化镧电极在一定浓度的NaOH溶液中浸泡一定时间,使OH^-与LaF_3单晶膜发生作用,表面形成La(OH)_3,同时置换出F^-,然后取出电极,用二次去离子水洗掉LaF_3电极表面的NaOH,使OH与LaF_3单晶膜终止反应,再放入二次去离子水中电磁搅拌清洗,洗掉LaF_3单晶膜表面所浮着的La(OH)_3,露出新的LaF_3单晶膜,从而使电极达到再活化。 展开更多
关键词 氟化镧电极 再活化机理 电化学分析 电极
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Influence of thermomechanical treatment on recrystallization and softening resistance of Cu-6.5Fe-0.3Mg alloy
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作者 Zhen-xia LIU Da-wei YUAN +5 位作者 Xin LUO Lan-hao WANG Jin-shui CHEN Hui-ming CHEN Xiang-peng XIAO Bin YANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期2900-2917,共18页
The recrystallization and softening resistance of a Cu-6.5Fe-0.3Mg(mass fraction,%)alloy prepared by Process 1(cold rolling heat treatment)and Process 2(hot/cold rolling heat treatment)were studied using Vickers hardn... The recrystallization and softening resistance of a Cu-6.5Fe-0.3Mg(mass fraction,%)alloy prepared by Process 1(cold rolling heat treatment)and Process 2(hot/cold rolling heat treatment)were studied using Vickers hardness tests,tensile tests,scanning electron microscopy and transmission electron microscopy.The softening temperature,hardness and tensile strength of the alloy prepared by Process 2 were 110°C,HV 15 and 114 MPa higher,respectively,than those of the alloy prepared by Process 1 after aging at 300°C.The recrystallization activation energy of the alloys prepared by Process 1 and Process 2 were 72.83 and 98.11 kJ/mol,respectively.The pinning effects of the precipitates of the two alloys on grain boundaries and dislocations were basically the same.The softening mechanism was mainly attributed to the loss of dislocation strengthening.The higher Fe fiber density inhibited the average free migration path of dislocations and grain boundary migration in the alloy,which was the main reason for higher softening temperature of the alloy prepared by Process 2. 展开更多
关键词 Cu−6.5Fe−0.3Mg alloy hot rolling recrystallization activation energy softening mechanism dislocation strengthening
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