A uniform Al-doped LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode material was prepared using a coprecipitation method to take advantage of the positive effect of Al on regenerated NCM(Ni,Co,Mn)cathode materials and ameliora...A uniform Al-doped LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode material was prepared using a coprecipitation method to take advantage of the positive effect of Al on regenerated NCM(Ni,Co,Mn)cathode materials and ameliorate cumbersome and high-cost impurity removal processes during lithium-ion battery recycling.When the Al^(3+) content in the leachate was 1 at.%with respect to the total amount of transition metals(Ni,Co,and Mn),the produced Al-doped NCM cathode material increased concentrations of lattice oxygen and Ni^(2+).The initial specific capacity at 0.1C was 167.4 mA·h/g,with a capacity retention of 79.1%after 400 cycles at 1C.Further,this Al-doped sample showed improved rate performance and a smaller electrochemical impedance.These findings provide a reference for developing industrial processes to resynthesize cathode materials with improved electrochemical performance by incorporating Al^(3+) impurities produced during lithium-ion battery recycling.展开更多
This study tries to reveal the carbonation behavior when recycled coarse aggregates(RCAs) are used to mix new concrete.Six series of tests including 22 groups of recycled aggregate concrete(RAC) specimens were carried...This study tries to reveal the carbonation behavior when recycled coarse aggregates(RCAs) are used to mix new concrete.Six series of tests including 22 groups of recycled aggregate concrete(RAC) specimens were carried out,in which the effects of the water/binder(w/b) ratios,the binder content,the types of mineral admixture,the quality of RCAs,the RCAs replacement and the loading levels on the carbonation behavior of RAC were evaluated,respectively.The results showed that the carbonation behavior of RAC was not only influenced by the quality of new mortar but also by the properties of RCAs.The admixture of mineral admixture influenced the carbonation,and the loading stress level might have a significant impact on the evolution of the carbonation.展开更多
基金supported by Anhui Province Research and Development Innovation Project for Automotive Power Battery Efficient Recycling System, China
文摘A uniform Al-doped LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode material was prepared using a coprecipitation method to take advantage of the positive effect of Al on regenerated NCM(Ni,Co,Mn)cathode materials and ameliorate cumbersome and high-cost impurity removal processes during lithium-ion battery recycling.When the Al^(3+) content in the leachate was 1 at.%with respect to the total amount of transition metals(Ni,Co,and Mn),the produced Al-doped NCM cathode material increased concentrations of lattice oxygen and Ni^(2+).The initial specific capacity at 0.1C was 167.4 mA·h/g,with a capacity retention of 79.1%after 400 cycles at 1C.Further,this Al-doped sample showed improved rate performance and a smaller electrochemical impedance.These findings provide a reference for developing industrial processes to resynthesize cathode materials with improved electrochemical performance by incorporating Al^(3+) impurities produced during lithium-ion battery recycling.
基金supported by the National Natural Science Foundation ofChina (Grant No. 51178340)the Shanghai Science and Technology Committee (Grant No. 10231202000)the New Century Excellent Talentsin China Ministry of Education Project (Grant No. NCET-06-0383)
文摘This study tries to reveal the carbonation behavior when recycled coarse aggregates(RCAs) are used to mix new concrete.Six series of tests including 22 groups of recycled aggregate concrete(RAC) specimens were carried out,in which the effects of the water/binder(w/b) ratios,the binder content,the types of mineral admixture,the quality of RCAs,the RCAs replacement and the loading levels on the carbonation behavior of RAC were evaluated,respectively.The results showed that the carbonation behavior of RAC was not only influenced by the quality of new mortar but also by the properties of RCAs.The admixture of mineral admixture influenced the carbonation,and the loading stress level might have a significant impact on the evolution of the carbonation.
