Direct current pulsed metal inert-gas (DC-PMIG) welding was carried out on AZ31B magnesium alloy to obtain continuous welding joints of 3 mm and 8 mm thickness with 1.6 mm diameter of filler wire. The behavior and m...Direct current pulsed metal inert-gas (DC-PMIG) welding was carried out on AZ31B magnesium alloy to obtain continuous welding joints of 3 mm and 8 mm thickness with 1.6 mm diameter of filler wire. The behavior and mechanism of metal transfer, the parameter ranges of stable welding process, the microstructure and mechanical properties of magnesium alloy were investigated. The results show that the metal transfer form of magnesium alloy using DC-PMIG welding is realized in modes of globular transfer, projected transfer and spray transfer. Welding spatter with a large size will be produced in the mode of globular transfer, and high-quality joints with few spatters can be obtained in the mode of projected transfer and spray transfer when the linear energy of filler wire is 242-27l J/cm, droplet diameter is 1.6-0.9 mm tensile strength of weld beads is 94.2% of that of base metals. and transition frequency is 30-69 Hz. The average ultimate展开更多
The electric pulse modification (EP, EPM) of liquid metal is a novel method for grain refinement. The structure of EP-modified Al-5%Cu melt was characterized by high-temperature X-ray diffractometry. The results sho...The electric pulse modification (EP, EPM) of liquid metal is a novel method for grain refinement. The structure of EP-modified Al-5%Cu melt was characterized by high-temperature X-ray diffractometry. The results show that the Cu-containing Al clusters remarkably increase in the EP-modified melt, furthermore, these clusters in that case tend to contract due to the decrease of relevant atomic radius and the co-ordination number. This kind of liquid-phase structure leads to a more homogeneous Cu-rich phase distribution in the final solidification structure. Differential scanning calorimetry (DSC) tests indicate that the solidification super-cooling degree of the EP-modified liquid phase is 2.36 times that of the unmodified. These facts suggest that the atom cluster changes in EP-modified Al-5%Cu melt would disagree with that by EPM model previously proposed in liquid pure metal.展开更多
The aim of the work was the study of the effect of NEMP (nanosecond electromagnetic pulses) on steel properties. Steel treatment was performed under the workshop conditions. The mechanical properties and the microst...The aim of the work was the study of the effect of NEMP (nanosecond electromagnetic pulses) on steel properties. Steel treatment was performed under the workshop conditions. The mechanical properties and the microstructure of the experimental samples and samples prepared by usual way were analyzed. The treatment of metal melt with nanosecond electromagnetic pulses at the crystallization stage makes it possible to change mechanical properties of metal and its structure.展开更多
Particle erosion of C/C-SiC composites prepared by reactive melt infiltration with different Al addition was studied by gas-entrained solid particle impingement test.SEM,EDS and XRD were performed to analyze the compo...Particle erosion of C/C-SiC composites prepared by reactive melt infiltration with different Al addition was studied by gas-entrained solid particle impingement test.SEM,EDS and XRD were performed to analyze the composites before and after erosion.The results indicate that a U shape relationship curve presents between the erosion rates and Al content,and the lowest erosion rate occurs at 40 wt%Al.Except for the important influence of compactness,the increasing soft Al mixed with reactive SiC,namely the mixture located between carbon and residual Si also,plays a key role in the erosion of the C/C-SiC composites through crack deflection,plastic deformation and bonding cracked Si.展开更多
This article presents the evidence in support of the direct magma degassing as the principal mechanism of volatiles releasing into the hydrothermal fluids in the Okinawa Trough, as contrasted to the argument for the h...This article presents the evidence in support of the direct magma degassing as the principal mechanism of volatiles releasing into the hydrothermal fluids in the Okinawa Trough, as contrasted to the argument for the hydrothermal stripping of volatiles from the volcanic rocks.\ Laser Raman microprobe and stepped-heating techniques are employed to determine the compositions and contents of the volatiles in pumices in the middle Okinawa Trough. The results show that the volatiles are similar to the gases in the hydrothermal fluids and hydrothermal minerals in composition, the mean percent content of each component and variation trend. This indicates the direct influence of magma degassing on the hydrothermal fluids. In addition, the contents of volatiles in pumices are rather low and do not support the hydrothermal stripping as the main mechanism to enrich the fluids with gases. The results are consistent with the idea that the direct magma degassing is more important than hydrothermal stripping in supplying gases to the hydrothermal fluids in the Okinawa Trough.展开更多
Protoplasts from Candida tropicalis and Candida lipolytica were fused under an optimized electrofusion (electrical pulse strength 6 kV/cm, pulse duration time 40μs and pulse times 5) and then regenerated on YEPD me...Protoplasts from Candida tropicalis and Candida lipolytica were fused under an optimized electrofusion (electrical pulse strength 6 kV/cm, pulse duration time 40μs and pulse times 5) and then regenerated on YEPD media for achieving new genotypes with higher chromium loading capacity. A target fusant RHJ-004 was screened out by its chromium resistance and chromium-sorbing capacity tests for further research. The comparative study of applicability shows that the fusant has better performance than its parent strains in respect of solution pH, biomass concentration and chromium loading capacity. Especially for treating low concentration Cr(VI) (〈20 mg/L), above 80% chromium is sequestered from the aqueous phase at pH 1-9. Atomic force microscopy (AFM) visualizes the distribution of chromium on the binding sites of the cells, suggesting that the altered surface structure and intracellular constitutes of the fusant associate with its increased biosorption capacity. The rapid biosorption processes of chromium foUow the Langmuir model well.展开更多
The effects of a pulsed magnetic field on the solidified microstructure of pure Mg were investigated.The results show that microstructure of pure Mg is considerably refined via columnar-to-equiaxed growth under the pu...The effects of a pulsed magnetic field on the solidified microstructure of pure Mg were investigated.The results show that microstructure of pure Mg is considerably refined via columnar-to-equiaxed growth under the pulsed magnetic field and the average grain size is refined to 260?? under the optimal processing conditions.A mathematical model was built to describe the interaction of the electromagnetic-flow fields during solidification with ANSYS software.The pulsed electric circuit was first solved and then it is substituted into the magnetic field model.The fluid flow model was solved with the acquired electromagnetic force.The effects of pulse voltage frequency on the current wave and on the distribution of magnetic and flow fields were numerically studied.The pulsed magnetic field increases melt convection,which stirs and fractures the dendritic arms into pieces.These broken pieces are transported into the bulk liquid by the liquid flow and act as nuclei to enhance grain refinement.The Joule heat effect produced by the electric current also participates in the microstructural refinement.展开更多
High-temperature(HT, >850℃) metamorphism in continental collision orogens, particularly for those ultrahigh-pressure(UHP) metamorphic rocks, has become one of the remarkable topics in Earth science. It has bearing...High-temperature(HT, >850℃) metamorphism in continental collision orogens, particularly for those ultrahigh-pressure(UHP) metamorphic rocks, has become one of the remarkable topics in Earth science. It has bearing on the element and isotope behaviors of UHP rocks, their partial melting and related geodynamic effects during exhumation. In this paper, five representative continental collision orogens with typical HT/UHP rocks, including the Dabie orogen in China, the Kokchetav in Kazakhstan, the Caledonides in Greenland, the Rhodope in Greece, and the Erzgebirge in Germany are introduced, and their HT/UHP metamorphism and evolution processes are summarized. In addition, metamorphic P-T-t paths, multistage exhumation processes, and partial melting and preservation and retrogression of UHP index minerals during exhumation and their possible mechanisms are discussed. On this basis, the forthcoming key fields and scientific subjects of HT/UHP rocks within continental subduction channel are proposed.展开更多
Melting simulation methods are of crucial importance to determining melting temperature of materials efficiently.A high-efficiency melting simulation method saves much simulation time and computational resources.To co...Melting simulation methods are of crucial importance to determining melting temperature of materials efficiently.A high-efficiency melting simulation method saves much simulation time and computational resources.To compare the efficiency of our newly developed shock melting(SM)method with that of the well-established two-phase(TP)method,we calculate the high-pressure melting curve of Au using the two methods based on the optimally selected interatomic potentials.Although we only use 640 atoms to determine the melting temperature of Au in the SM method,the resulting melting curve accords very well with the results from the TP method using much more atoms.Thus,this shows that a much smaller system size in SM method can still achieve a fully converged melting curve compared with the TP method,implying the robustness and efficiency of the SM method.展开更多
It is proposed in the subduction channel model that the plate interface interaction is a basic mechanism for the mass and energy exchange between Earth’s surface and interior.The significant difference in composition...It is proposed in the subduction channel model that the plate interface interaction is a basic mechanism for the mass and energy exchange between Earth’s surface and interior.The significant difference in composition and nature between continental lithosphere and oceanic lithosphere inevitably leads to variations in deep physical and chemical processes as well as crust-mantle interaction products in these two settings.Many studies of experimental petrology have provided constraints on the potential partial melting and crust-mantle interaction in oceanic subduction channels for silicate and carbonate rocks.The partial melts of mafic and felsic compositions are adakitic or non-adakitic granitic melts depending on melting pressure or depth.A trivial amount of CO2 can lower significantly the melting temperature of peridotites and lead to pronounced enrichment of incompatible elements in carbonate melt.The silica saturated or unsaturated melts can react with mantle-wedge peridotites in subduction channels to generate complex products.However,the existing experiments are mostly dedicated to island arc settings above oceanic subduction zones rather than dehydration melting above continental subduction zones.It is crucial to conduct high pressure and high temperature experiments to investigate all possible reactions between peridotites and crustal materials and their derivatives under the conditions responsible for the slab-mantle interface in continental subduction channels.Experimental results,combined with natural observations,are possible to elucidate the processes of metamorphic dehydration,partial melting and mantle metasomatism in continental subduction channels.展开更多
基金Project (IRT1008) supported by Changjiang Scholars and Innovative Research Team in University, ChinaProject (51005035) supported by the National Natural Science Foundation of ChinaProject (51025520) supported by the National Natural Science Funds for Distinguished Young Scholar, China
文摘Direct current pulsed metal inert-gas (DC-PMIG) welding was carried out on AZ31B magnesium alloy to obtain continuous welding joints of 3 mm and 8 mm thickness with 1.6 mm diameter of filler wire. The behavior and mechanism of metal transfer, the parameter ranges of stable welding process, the microstructure and mechanical properties of magnesium alloy were investigated. The results show that the metal transfer form of magnesium alloy using DC-PMIG welding is realized in modes of globular transfer, projected transfer and spray transfer. Welding spatter with a large size will be produced in the mode of globular transfer, and high-quality joints with few spatters can be obtained in the mode of projected transfer and spray transfer when the linear energy of filler wire is 242-27l J/cm, droplet diameter is 1.6-0.9 mm tensile strength of weld beads is 94.2% of that of base metals. and transition frequency is 30-69 Hz. The average ultimate
基金Project(51074087)supported by the National Natural Science Foundation of ChinaProject(201102088)supported by the Natural Science Foundation of Liaoning Province,China+1 种基金Project(LJQ2011065)supported by Liaoning Excellent Talents in University,ChinaProject(2010921096)supported by Liaoning Baiqianwan Talents Program,China
文摘The electric pulse modification (EP, EPM) of liquid metal is a novel method for grain refinement. The structure of EP-modified Al-5%Cu melt was characterized by high-temperature X-ray diffractometry. The results show that the Cu-containing Al clusters remarkably increase in the EP-modified melt, furthermore, these clusters in that case tend to contract due to the decrease of relevant atomic radius and the co-ordination number. This kind of liquid-phase structure leads to a more homogeneous Cu-rich phase distribution in the final solidification structure. Differential scanning calorimetry (DSC) tests indicate that the solidification super-cooling degree of the EP-modified liquid phase is 2.36 times that of the unmodified. These facts suggest that the atom cluster changes in EP-modified Al-5%Cu melt would disagree with that by EPM model previously proposed in liquid pure metal.
文摘The aim of the work was the study of the effect of NEMP (nanosecond electromagnetic pulses) on steel properties. Steel treatment was performed under the workshop conditions. The mechanical properties and the microstructure of the experimental samples and samples prepared by usual way were analyzed. The treatment of metal melt with nanosecond electromagnetic pulses at the crystallization stage makes it possible to change mechanical properties of metal and its structure.
基金Project(51902239)supported by the National Natural Science Foundation of ChinaProject(2020JQ-808)supported by the Science and Technology Fund of Shaanxi Province,China+3 种基金Projects(19JK0400,19JK0402)supported by the Education Fund of Shaanxi Province,ChinaProject(SKLSP201752)supported by the State Key Laboratory of Solidification Processing in Northwestern Poly Technical University,ChinaProject(XAGDXJJ17008)supported by the Principal Fund of Xi’an Technological University,ChinaProject supported by the Youth Innovation Team of Shaanxi Universities,China。
文摘Particle erosion of C/C-SiC composites prepared by reactive melt infiltration with different Al addition was studied by gas-entrained solid particle impingement test.SEM,EDS and XRD were performed to analyze the composites before and after erosion.The results indicate that a U shape relationship curve presents between the erosion rates and Al content,and the lowest erosion rate occurs at 40 wt%Al.Except for the important influence of compactness,the increasing soft Al mixed with reactive SiC,namely the mixture located between carbon and residual Si also,plays a key role in the erosion of the C/C-SiC composites through crack deflection,plastic deformation and bonding cracked Si.
基金This work was supported by the Major State Basic Research Program(No.G2000078503)Shandong Natural Science Foundation(No.Y2000E06).
文摘This article presents the evidence in support of the direct magma degassing as the principal mechanism of volatiles releasing into the hydrothermal fluids in the Okinawa Trough, as contrasted to the argument for the hydrothermal stripping of volatiles from the volcanic rocks.\ Laser Raman microprobe and stepped-heating techniques are employed to determine the compositions and contents of the volatiles in pumices in the middle Okinawa Trough. The results show that the volatiles are similar to the gases in the hydrothermal fluids and hydrothermal minerals in composition, the mean percent content of each component and variation trend. This indicates the direct influence of magma degassing on the hydrothermal fluids. In addition, the contents of volatiles in pumices are rather low and do not support the hydrothermal stripping as the main mechanism to enrich the fluids with gases. The results are consistent with the idea that the direct magma degassing is more important than hydrothermal stripping in supplying gases to the hydrothermal fluids in the Okinawa Trough.
基金Project(NSFC-GDNSF U0933002) supported by the Joint Funds of the National Natural Science Foundation of China and the Natural Science Foundation of Guangdong Province,ChinaProject(50978122) supported by the National Natural Science Foundation of China
文摘Protoplasts from Candida tropicalis and Candida lipolytica were fused under an optimized electrofusion (electrical pulse strength 6 kV/cm, pulse duration time 40μs and pulse times 5) and then regenerated on YEPD media for achieving new genotypes with higher chromium loading capacity. A target fusant RHJ-004 was screened out by its chromium resistance and chromium-sorbing capacity tests for further research. The comparative study of applicability shows that the fusant has better performance than its parent strains in respect of solution pH, biomass concentration and chromium loading capacity. Especially for treating low concentration Cr(VI) (〈20 mg/L), above 80% chromium is sequestered from the aqueous phase at pH 1-9. Atomic force microscopy (AFM) visualizes the distribution of chromium on the binding sites of the cells, suggesting that the altered surface structure and intracellular constitutes of the fusant associate with its increased biosorption capacity. The rapid biosorption processes of chromium foUow the Langmuir model well.
基金Project(50774075)supported by the National Natural Science Foundation of ChinaProject(2006BAE04B01-4)supported by Key Technologies R&D Program,China
文摘The effects of a pulsed magnetic field on the solidified microstructure of pure Mg were investigated.The results show that microstructure of pure Mg is considerably refined via columnar-to-equiaxed growth under the pulsed magnetic field and the average grain size is refined to 260?? under the optimal processing conditions.A mathematical model was built to describe the interaction of the electromagnetic-flow fields during solidification with ANSYS software.The pulsed electric circuit was first solved and then it is substituted into the magnetic field model.The fluid flow model was solved with the acquired electromagnetic force.The effects of pulse voltage frequency on the current wave and on the distribution of magnetic and flow fields were numerically studied.The pulsed magnetic field increases melt convection,which stirs and fractures the dendritic arms into pieces.These broken pieces are transported into the bulk liquid by the liquid flow and act as nuclei to enhance grain refinement.The Joule heat effect produced by the electric current also participates in the microstructural refinement.
基金supported by the National Basic Research Program of China(Grant No.2015CB856104)the National Natural Science Foundation of China(Grant No.41273036)
文摘High-temperature(HT, >850℃) metamorphism in continental collision orogens, particularly for those ultrahigh-pressure(UHP) metamorphic rocks, has become one of the remarkable topics in Earth science. It has bearing on the element and isotope behaviors of UHP rocks, their partial melting and related geodynamic effects during exhumation. In this paper, five representative continental collision orogens with typical HT/UHP rocks, including the Dabie orogen in China, the Kokchetav in Kazakhstan, the Caledonides in Greenland, the Rhodope in Greece, and the Erzgebirge in Germany are introduced, and their HT/UHP metamorphism and evolution processes are summarized. In addition, metamorphic P-T-t paths, multistage exhumation processes, and partial melting and preservation and retrogression of UHP index minerals during exhumation and their possible mechanisms are discussed. On this basis, the forthcoming key fields and scientific subjects of HT/UHP rocks within continental subduction channel are proposed.
基金Supported by the National Natural Science Foundation of China under Grant No.41574076the NSAF of China under Grant No.U1230201/A06the Young Core Teacher Scheme of Henan Province under Grant No.2014GGJS-108
文摘Melting simulation methods are of crucial importance to determining melting temperature of materials efficiently.A high-efficiency melting simulation method saves much simulation time and computational resources.To compare the efficiency of our newly developed shock melting(SM)method with that of the well-established two-phase(TP)method,we calculate the high-pressure melting curve of Au using the two methods based on the optimally selected interatomic potentials.Although we only use 640 atoms to determine the melting temperature of Au in the SM method,the resulting melting curve accords very well with the results from the TP method using much more atoms.Thus,this shows that a much smaller system size in SM method can still achieve a fully converged melting curve compared with the TP method,implying the robustness and efficiency of the SM method.
基金supported by the National Basic Research Program of China(Grant No.2015CB856101)the National Natural Science Foundation of China(Grant Nos.41172070,41425012)the Ministry of Education of China and the State Administration of Foreign Expert Affairs of China(Grant No.B07039)
文摘It is proposed in the subduction channel model that the plate interface interaction is a basic mechanism for the mass and energy exchange between Earth’s surface and interior.The significant difference in composition and nature between continental lithosphere and oceanic lithosphere inevitably leads to variations in deep physical and chemical processes as well as crust-mantle interaction products in these two settings.Many studies of experimental petrology have provided constraints on the potential partial melting and crust-mantle interaction in oceanic subduction channels for silicate and carbonate rocks.The partial melts of mafic and felsic compositions are adakitic or non-adakitic granitic melts depending on melting pressure or depth.A trivial amount of CO2 can lower significantly the melting temperature of peridotites and lead to pronounced enrichment of incompatible elements in carbonate melt.The silica saturated or unsaturated melts can react with mantle-wedge peridotites in subduction channels to generate complex products.However,the existing experiments are mostly dedicated to island arc settings above oceanic subduction zones rather than dehydration melting above continental subduction zones.It is crucial to conduct high pressure and high temperature experiments to investigate all possible reactions between peridotites and crustal materials and their derivatives under the conditions responsible for the slab-mantle interface in continental subduction channels.Experimental results,combined with natural observations,are possible to elucidate the processes of metamorphic dehydration,partial melting and mantle metasomatism in continental subduction channels.