In order to investigate the effects of freezing and thawing on the compressibility of fine-grained soils, freezing and thawing tests and subsequent compression tests with fine-grained soils in an oedometer were carrie...In order to investigate the effects of freezing and thawing on the compressibility of fine-grained soils, freezing and thawing tests and subsequent compression tests with fine-grained soils in an oedometer were carried out. During the freezing, a part of the soils is loosened and another part is over-consolidated under the freezing pressure σE. The compression curves after the freezing and thaw consolidation are neither different from the normal consolidation curve nor from the rebound curve of an unfrozen soil, until the consolidation pressure σz = σE is arrived. Based on the experimental results, a theoretical model has been devel- oped to predict the frost heaves, the thaw-settlements and the compressive deformations of fine-grained soils after the thaw consolidation. The theoretical results are very close to the experimental results.展开更多
The reactor unit for one-stage technology for production of concentrated ethylene glycol-water solutions is described.Such solutions could be useful for production of automotive antifreezes. The technology is based on...The reactor unit for one-stage technology for production of concentrated ethylene glycol-water solutions is described.Such solutions could be useful for production of automotive antifreezes. The technology is based on the highly selective hydration ofethylene oxide in the presence of heterogeneous catalyst-anion-exchange resin in HCO3-/CO/3/2-_form. The mathematical model of reactor allowed evaluating of economical benefit in comparison with conventional method.展开更多
A series of triaxial compression tests for frozen clay were performed by KoDCGF （freezing with non-uniform temperature under loading after K0 consolidation） method and GFC （freezing with non-uniform temperature wit...A series of triaxial compression tests for frozen clay were performed by KoDCGF （freezing with non-uniform temperature under loading after K0 consolidation） method and GFC （freezing with non-uniform temperature without experiencing Ko consolidation） method at various confining pressures and thermal gradients. The experimental results indicate that the triaxial compression strength for frozen clay in KoDCGF test increases with the increase of confining pressure, but it decreases as the confining pressure increases further in GFC test. In other words, the compression strength for frozen clay with identical confining pressure decreases with the increase in thermal gradient both in KoDCGF test and GFC test. The strength of frozen clay in KoDCGF test is dependent of pore ice strength, soil particle strength and interaction between soil skeleton and pore ice. The decrease of water content and distance between soil particles leads to the decrease of pore size and the increase of contact area between particles in KoDCGF test, which further results in a higher compression strength than that in GFC test. The compression strength for frozen clay with thermal gradient can be descried by strength for frozen clay with a uniform temperature identical to the temperature at the height of specimen where the maximum tensile stress appears.展开更多
Geological disasters will happen in cold regions because of the effects of freeze-thaw cycles on rocks or soils, so studying the effects of these cycles on the mechanical characteristics and permeability properties of...Geological disasters will happen in cold regions because of the effects of freeze-thaw cycles on rocks or soils, so studying the effects of these cycles on the mechanical characteristics and permeability properties of rocks is very important. In this study, red sandstone samples were frozen and thawed with o, 4, 8 and 12 cycles, each cycle including 12 h of freezing and 12 h of thawing. The P-wave velocities of these samples were measured, and the mechanical properties and evolution of the steady-state permeabilities were investigated in a series of uniaxial and triaxial compression tests. Experimental results show that, with the increasing of cyclic freeze-thaw times, the P-wave velocity of the red sandstone decreases. The number of freeze-thaw cycles has a significant influence on the uniaxial compressive strength, elastic modulus, cohesion, and angle of internal friction. The evolution of permeability of the rock samples after cycles of freeze-thaw in a complete stress-strain process under triaxial compression is closely related to the variation of the microstructure in the rock. There is a highly corresponding relationship between volumetric strain and permeability with axial strain in all stages of the stress-strain behaviour.展开更多
文摘In order to investigate the effects of freezing and thawing on the compressibility of fine-grained soils, freezing and thawing tests and subsequent compression tests with fine-grained soils in an oedometer were carried out. During the freezing, a part of the soils is loosened and another part is over-consolidated under the freezing pressure σE. The compression curves after the freezing and thaw consolidation are neither different from the normal consolidation curve nor from the rebound curve of an unfrozen soil, until the consolidation pressure σz = σE is arrived. Based on the experimental results, a theoretical model has been devel- oped to predict the frost heaves, the thaw-settlements and the compressive deformations of fine-grained soils after the thaw consolidation. The theoretical results are very close to the experimental results.
文摘The reactor unit for one-stage technology for production of concentrated ethylene glycol-water solutions is described.Such solutions could be useful for production of automotive antifreezes. The technology is based on the highly selective hydration ofethylene oxide in the presence of heterogeneous catalyst-anion-exchange resin in HCO3-/CO/3/2-_form. The mathematical model of reactor allowed evaluating of economical benefit in comparison with conventional method.
基金funded by the Applied Basic Research Project (Key Platform) by Ministry of Transport(No.2014319363200)the National Natural Science Foundation (No.51378057 & 41371081)
基金Project(50534040) supported by the National Natural Science Foundation of ChinaProject(20110491489) supported by China Postdoctoral Science FoundationProject(2011QNA03) supported by Fundamental Research Funds for the Central Universities of China
文摘A series of triaxial compression tests for frozen clay were performed by KoDCGF （freezing with non-uniform temperature under loading after K0 consolidation） method and GFC （freezing with non-uniform temperature without experiencing Ko consolidation） method at various confining pressures and thermal gradients. The experimental results indicate that the triaxial compression strength for frozen clay in KoDCGF test increases with the increase of confining pressure, but it decreases as the confining pressure increases further in GFC test. In other words, the compression strength for frozen clay with identical confining pressure decreases with the increase in thermal gradient both in KoDCGF test and GFC test. The strength of frozen clay in KoDCGF test is dependent of pore ice strength, soil particle strength and interaction between soil skeleton and pore ice. The decrease of water content and distance between soil particles leads to the decrease of pore size and the increase of contact area between particles in KoDCGF test, which further results in a higher compression strength than that in GFC test. The compression strength for frozen clay with thermal gradient can be descried by strength for frozen clay with a uniform temperature identical to the temperature at the height of specimen where the maximum tensile stress appears.
基金supported by the National Basic Research Program of China (973 Program) (Grant No. 2011CB013503)the National Natural Science Foundation of China (Grant No. 51374112)the Promotion Program for Young and Middle-aged Teacher in Science and Technology Research of Huaqiao University (ZQN-PY112)
文摘Geological disasters will happen in cold regions because of the effects of freeze-thaw cycles on rocks or soils, so studying the effects of these cycles on the mechanical characteristics and permeability properties of rocks is very important. In this study, red sandstone samples were frozen and thawed with o, 4, 8 and 12 cycles, each cycle including 12 h of freezing and 12 h of thawing. The P-wave velocities of these samples were measured, and the mechanical properties and evolution of the steady-state permeabilities were investigated in a series of uniaxial and triaxial compression tests. Experimental results show that, with the increasing of cyclic freeze-thaw times, the P-wave velocity of the red sandstone decreases. The number of freeze-thaw cycles has a significant influence on the uniaxial compressive strength, elastic modulus, cohesion, and angle of internal friction. The evolution of permeability of the rock samples after cycles of freeze-thaw in a complete stress-strain process under triaxial compression is closely related to the variation of the microstructure in the rock. There is a highly corresponding relationship between volumetric strain and permeability with axial strain in all stages of the stress-strain behaviour.
