圆筒型浮式生产储卸油装置(Floating Production Storage and Offloading,FPSO)较差的垂荡性能成为阻碍其走向深远海油气资源开发利用的一个重要因素,减动结构的设计能一定程度上改善垂荡性能。本文基于计算流体力学(Computational Flui...圆筒型浮式生产储卸油装置(Floating Production Storage and Offloading,FPSO)较差的垂荡性能成为阻碍其走向深远海油气资源开发利用的一个重要因素,减动结构的设计能一定程度上改善垂荡性能。本文基于计算流体力学(Computational Fluid Dynamics,CFD)的方法,利用Fluent软件建立三维数值水池模型,采用强迫垂荡运动的方式,计算了不同运动参数下带延伸筒体和减动结构的圆筒型FPSO的垂荡阻尼系数和附加质量。研究结果表明:垂荡阻尼系数与垂荡运动周期负相关,与垂荡运动幅值呈线性正相关,且垂荡运动周期较小时,垂荡阻尼系数受垂荡运动幅值的影响较明显。垂荡附加质量随着垂荡运动周期增大呈现明显上升趋势,但其对垂荡运动幅值不敏感。垂荡运动周期接近垂荡固有周期时,垂荡附加质量出现极小值。本文的计算结果能够为工程实际提供一定参考。展开更多
The excited state structural dynamics of phenyl absorbing S2（A＇）, S3（A＇）, and S6（A＇） states were troseopy and complete active space self-consistent and the UV absorption bands were assigned on azide （PhN3） ...The excited state structural dynamics of phenyl absorbing S2（A＇）, S3（A＇）, and S6（A＇） states were troseopy and complete active space self-consistent and the UV absorption bands were assigned on azide （PhN3） after excitation to the light studied using the resonance Raman specfield calculations. The vibrational spectra the basis of the Fourier transform （FT）- Raman, FT-infrared measurements, the density-functional theory computations and the normal mode analysis. The A-, B-, and C-bands resonance Raman spectra in cyclohex- ane, acetonitrile, and methanol solvents were, respectively, obtained at 273.9, 252.7, 245.9, 228.7, 223.1, and 208.8 nm excitation wavelengths to probe the corresponding structural dynamics of PhN3. The results indicated that the structural dynamics in the S2 （A＇）, S3（A＇）, and S6（A＇） states were significantly different. The crossing points of the potential energy surfaces, S2S1（1） and S2S1（2）, were predicted to play a key role in the low-lying excited state decay dynamics, in accordance with Kasha＇s rule, and NT=N8 dissociation. Two decay channels initiated from the Franck-Condon region of the S2（A＇） state were predicted： the radiative S2,min→S0 radiative decay and the S2→S1 internal conversion through the crossing points S2S1 （1）/S2S1（2）.展开更多
The decay dynamics of N, N-dimethylthioacetamide after excitation to the S3（ππ＊） state was studied by using the resonance Raman spectroscopy and complete active space self- consistent field method calculations. T...The decay dynamics of N, N-dimethylthioacetamide after excitation to the S3（ππ＊） state was studied by using the resonance Raman spectroscopy and complete active space self- consistent field method calculations. The UV-absorption and vibrational spectra were as- signed. The A-band resonance Raman spectra were obtained in acetonitrile, methanol and water with the laser excitation wavelengths in resonance with the first intense absorption band to probe the Franck-Condon region structural dynamics. The CASSCF calculations were carried out to determine the excitation energies and optimized structures of the lower- lying singlet states and conical intersection point. The A-band structural dynamics and the corresponding decay mechanism were obtained by the analysis of the resonance Raman in- tensity pattern and the CASSCF calculated structural parameters. The major decay channel of S3,FC （ππ＊）→S3（ππ＊）/S1 （nπ＊）→S1（nπ＊） is proposed.展开更多
In this paper, the method of semi-active control with variable damper is presented to deal with the relatively poor transversal seismic condition of bridge. Based on the LQR control algorithm the control effectiveness...In this paper, the method of semi-active control with variable damper is presented to deal with the relatively poor transversal seismic condition of bridge. Based on the LQR control algorithm the control effectiveness for transverse vibration of pier-beam structure of bridge are discussed. Taking the structure as a multiple-degree of freedom system, the calculating model of structure-variable damper system is set up and the differential equation is derived, combined with practical example the control system is simulated and studied by various semi-active control algorithms and passive strategy with MATLAB. The results show that the semi-active control with variable damper can decrease the transverse vibration effectively and the control effect is obvious.展开更多
Herein is introduced the mechanism for active control influencing the generation of the near-wall streamwise vortices,which are closely related to the production of high skin friction in wall-bounded turbulent flows.A...Herein is introduced the mechanism for active control influencing the generation of the near-wall streamwise vortices,which are closely related to the production of high skin friction in wall-bounded turbulent flows.A new opposition control scheme with adjusting control amplitude is proposed and evaluated in turbulent channel flow by direct numerical simulations.The maximum drag reduction rate can be greatly enhanced by the strengthened control.Finally the effectiveness of the control to the coherent structures at high Reynolds numbers is investigated by using a linear transient growth model.展开更多
文摘圆筒型浮式生产储卸油装置(Floating Production Storage and Offloading,FPSO)较差的垂荡性能成为阻碍其走向深远海油气资源开发利用的一个重要因素,减动结构的设计能一定程度上改善垂荡性能。本文基于计算流体力学(Computational Fluid Dynamics,CFD)的方法,利用Fluent软件建立三维数值水池模型,采用强迫垂荡运动的方式,计算了不同运动参数下带延伸筒体和减动结构的圆筒型FPSO的垂荡阻尼系数和附加质量。研究结果表明:垂荡阻尼系数与垂荡运动周期负相关,与垂荡运动幅值呈线性正相关,且垂荡运动周期较小时,垂荡阻尼系数受垂荡运动幅值的影响较明显。垂荡附加质量随着垂荡运动周期增大呈现明显上升趋势,但其对垂荡运动幅值不敏感。垂荡运动周期接近垂荡固有周期时,垂荡附加质量出现极小值。本文的计算结果能够为工程实际提供一定参考。
基金This work is supported by the National Natural Science Foundation of China （No.21473163, No.21033002, No.21202032） and the National Basic Research Program of China （No.2013CB834604）.
文摘The excited state structural dynamics of phenyl absorbing S2（A＇）, S3（A＇）, and S6（A＇） states were troseopy and complete active space self-consistent and the UV absorption bands were assigned on azide （PhN3） after excitation to the light studied using the resonance Raman specfield calculations. The vibrational spectra the basis of the Fourier transform （FT）- Raman, FT-infrared measurements, the density-functional theory computations and the normal mode analysis. The A-, B-, and C-bands resonance Raman spectra in cyclohex- ane, acetonitrile, and methanol solvents were, respectively, obtained at 273.9, 252.7, 245.9, 228.7, 223.1, and 208.8 nm excitation wavelengths to probe the corresponding structural dynamics of PhN3. The results indicated that the structural dynamics in the S2 （A＇）, S3（A＇）, and S6（A＇） states were significantly different. The crossing points of the potential energy surfaces, S2S1（1） and S2S1（2）, were predicted to play a key role in the low-lying excited state decay dynamics, in accordance with Kasha＇s rule, and NT=N8 dissociation. Two decay channels initiated from the Franck-Condon region of the S2（A＇） state were predicted： the radiative S2,min→S0 radiative decay and the S2→S1 internal conversion through the crossing points S2S1 （1）/S2S1（2）.
基金This work was supported by the National Natu- ral Science Foundation of China （No.21033002 and No.21202032） and the National Basic Research Pro- gram of China （No.2013CB834604）.
文摘The decay dynamics of N, N-dimethylthioacetamide after excitation to the S3（ππ＊） state was studied by using the resonance Raman spectroscopy and complete active space self- consistent field method calculations. The UV-absorption and vibrational spectra were as- signed. The A-band resonance Raman spectra were obtained in acetonitrile, methanol and water with the laser excitation wavelengths in resonance with the first intense absorption band to probe the Franck-Condon region structural dynamics. The CASSCF calculations were carried out to determine the excitation energies and optimized structures of the lower- lying singlet states and conical intersection point. The A-band structural dynamics and the corresponding decay mechanism were obtained by the analysis of the resonance Raman in- tensity pattern and the CASSCF calculated structural parameters. The major decay channel of S3,FC （ππ＊）→S3（ππ＊）/S1 （nπ＊）→S1（nπ＊） is proposed.
文摘In this paper, the method of semi-active control with variable damper is presented to deal with the relatively poor transversal seismic condition of bridge. Based on the LQR control algorithm the control effectiveness for transverse vibration of pier-beam structure of bridge are discussed. Taking the structure as a multiple-degree of freedom system, the calculating model of structure-variable damper system is set up and the differential equation is derived, combined with practical example the control system is simulated and studied by various semi-active control algorithms and passive strategy with MATLAB. The results show that the semi-active control with variable damper can decrease the transverse vibration effectively and the control effect is obvious.
基金Tsupported by the National Natural Science Foundation of China (Grant Nos. 10925210 and 11132005)
文摘Herein is introduced the mechanism for active control influencing the generation of the near-wall streamwise vortices,which are closely related to the production of high skin friction in wall-bounded turbulent flows.A new opposition control scheme with adjusting control amplitude is proposed and evaluated in turbulent channel flow by direct numerical simulations.The maximum drag reduction rate can be greatly enhanced by the strengthened control.Finally the effectiveness of the control to the coherent structures at high Reynolds numbers is investigated by using a linear transient growth model.
