Based on the geological condition of Zhangxiaolou deep mine in Xuzhou mining area, under 986 m in depth, 20.6-31.6 MPa in maximum horizontal principal stress, and friable and fractured surrounding rock, test researche...Based on the geological condition of Zhangxiaolou deep mine in Xuzhou mining area, under 986 m in depth, 20.6-31.6 MPa in maximum horizontal principal stress, and friable and fractured surrounding rock, test researches on partial relieving pressure were completed for the entry with U-steel arched yielding support. The relieving pressure parameters, technology process and results of springing blasting by boreholes and excavating pockets in the two sides of entry were introduced. It is demonstrated that springing will not be shaped under the condition of single borehole arrangement after exploded, the arrangement by a group, it will make borehole bottom form springing in 0.6-0.8 m in diameter, that convergence of two sides and roof to floor have some increments by using springing blasting for reliving pressure. This kind of method for reliving pressure is not suitable to use in the deep mine, and that the convergence of two sides obviously declined by excavating pocket in two sides, it can be still used in the entry with metal support, while maintenance of entry in deep mines is difficult, and can not be supported by bolt or bolt with wire mesh.展开更多
The ultrafast dynamics of benzaldehyde upon 260, 271, 284, and 287 nm excitations have been studied by femtosecond pinup-probe time-of-flight mass spectrometry. A bi-exponential decay component model was applied to fi...The ultrafast dynamics of benzaldehyde upon 260, 271, 284, and 287 nm excitations have been studied by femtosecond pinup-probe time-of-flight mass spectrometry. A bi-exponential decay component model was applied to fit the transient profiles of benzaldehyde ions and fragment ions. At the S2 origin, the first decay of the component was attributed to the internal conversion to the high vibrational levels of S1 state. Lifetimes of the first component decreased with increasing vibrational energy, due to the influence of high density of the vibrational levels. The second decay was assigned to the vibrational relaxation of the S1 whose lifetime was about 600 fs. Upon 287 nm excitation, the first decay became ultra-short （-56 fs） which was taken for the intersystem cross from S1 to T2, while the second decay component was attributed to the vibrational relaxation. The pump-probe transient of fragment was also studied with the different probe intensity at 284 nm pump.展开更多
基金Supported by the Key Project of the National Natural Science Foundation （50490273）
文摘Based on the geological condition of Zhangxiaolou deep mine in Xuzhou mining area, under 986 m in depth, 20.6-31.6 MPa in maximum horizontal principal stress, and friable and fractured surrounding rock, test researches on partial relieving pressure were completed for the entry with U-steel arched yielding support. The relieving pressure parameters, technology process and results of springing blasting by boreholes and excavating pockets in the two sides of entry were introduced. It is demonstrated that springing will not be shaped under the condition of single borehole arrangement after exploded, the arrangement by a group, it will make borehole bottom form springing in 0.6-0.8 m in diameter, that convergence of two sides and roof to floor have some increments by using springing blasting for reliving pressure. This kind of method for reliving pressure is not suitable to use in the deep mine, and that the convergence of two sides obviously declined by excavating pocket in two sides, it can be still used in the entry with metal support, while maintenance of entry in deep mines is difficult, and can not be supported by bolt or bolt with wire mesh.
基金V. ACKNOWLEDGMENT This work was supported by the National Natural Science Foundation of China （No.20633070 and No.20473090）.
文摘The ultrafast dynamics of benzaldehyde upon 260, 271, 284, and 287 nm excitations have been studied by femtosecond pinup-probe time-of-flight mass spectrometry. A bi-exponential decay component model was applied to fit the transient profiles of benzaldehyde ions and fragment ions. At the S2 origin, the first decay of the component was attributed to the internal conversion to the high vibrational levels of S1 state. Lifetimes of the first component decreased with increasing vibrational energy, due to the influence of high density of the vibrational levels. The second decay was assigned to the vibrational relaxation of the S1 whose lifetime was about 600 fs. Upon 287 nm excitation, the first decay became ultra-short （-56 fs） which was taken for the intersystem cross from S1 to T2, while the second decay component was attributed to the vibrational relaxation. The pump-probe transient of fragment was also studied with the different probe intensity at 284 nm pump.
