This paper introduced domestic and overseas status, the historical evolution and the development history of earthquake disaster reduction planning. The urgencies and realistic significance were analyzed to carry out e...This paper introduced domestic and overseas status, the historical evolution and the development history of earthquake disaster reduction planning. The urgencies and realistic significance were analyzed to carry out earthquake disaster reduction planning for districts or countries in the northwest. With Hongsibao District in Wuzhong City, Ningxia Province as an example, this article analyzed in detail the present situation and the special problems of earthquake disaster reduction planning in Northwest China. The relevant solving measures were put forward in order to offer a reference for the scientific establishment and effective implementation of earth- quake disaster reduction planning in Northwest China. The foundation of earthquake disaster reduction in the Hongsibao District is still very weak, there is a single earthquake monitoring means, the emergency rescue system is not complete, the working mechanism is not perfect, and the lack of funding for the work of earthquake disaster reduction.展开更多
Methanol oxidation reaction (MOR) at Pt and Pt electrode surface deposited with various amounts of Ru (denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML) in 0.1 mol/L HClO4+0.5 mol/L MeOH has been ...Methanol oxidation reaction (MOR) at Pt and Pt electrode surface deposited with various amounts of Ru (denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML) in 0.1 mol/L HClO4+0.5 mol/L MeOH has been studied under potentiostatic conditions by in situ FTIR spectroscopy in attenuated-total-reflection con guration and di erential electro-chemical mass spectrometry under controlled flow conditions. Results reveal that (i) CO is the only methanol-related adsorbate observed by IR spectroscopy at all the Pt and PtRu electrodes examined at potentials from 0.3 V to 0.6 V (vs. RHE); (ii) at Pt0.56Ru0.44, two IR bands, one from CO adsorbed at Ru islands and the other from COL at Pt substrate are detected, while at other electrodes, only a single band for COL adsorbed at Pt is observed; (iii) MOR activity decreases in the order of Pt0.73Ru0.27〉Pt0.56Ru0.44〉Pt0.83Ru0.17〉Pt; (iv) at 0.5 V, MOR at Pt0.73Ru0.27 reaches a current e ciency of 50% for CO2 production, the turn-over frequency from CH3OH to CO2 is ca. 0.1 molecule/(site sec). Suggestions for further improving of PtRu catalysts for MOR are provided.展开更多
The influence of the drop-casted nickel boride catalyst loading on glassy carbon electrodes was investigated in a spectroelectrochemical ATR-FTIR thin-film flow cell applied in alkaline glycerol electrooxidation.The c...The influence of the drop-casted nickel boride catalyst loading on glassy carbon electrodes was investigated in a spectroelectrochemical ATR-FTIR thin-film flow cell applied in alkaline glycerol electrooxidation.The continuously operated radial flow cell consisted of a borehole electrode positioned 50μm above an internal reflection element enabling operando FTIR spectroscopy.It is identified as a suitable tool for facile and reproducible screening of electrocatalysts under well-defined conditions,additionally providing access to the selectivities in complex reaction networks such as glycerol oxidation.The fast product identification by ATR-IR spectroscopy was validated by the more time-consuming quantitative HPLC analysis of the pumped electrolyte.High degrees of glycerol conversion were achieved under the applied laminar flow conditions using 0.1 M glycerol and 1 M KOH in water and a flow rate of 5μL min^(–1).Conversion and selectivity were found to depend on the catalyst loading,which determined the catalyst layer thickness and roughness.The highest loading of 210μg cm^(–2)resulted in 73%conversion and a higher formate selectivity of almost 80%,which is ascribed to longer residence times in rougher films favoring readsorption and C–C bond scission.The lowest loading of 13μg cm^(–2)was sufficient to reach 63%conversion,a lower formate selectivity of 60%,and,correspondingly,higher selectivities of C_(2)species such as glycolate amounting to 8%.Thus,only low catalyst loadings resulting in very thin films in the fewμm thickness range are suitable for reliable catalyst screening.展开更多
Bimetallic catalysts can improve CO2 reduction efficiency via the combined properties of two metals.CuPd shows enhanced CO2 reduction activity compared to copper alone.Using differential electrochemical mass spectrome...Bimetallic catalysts can improve CO2 reduction efficiency via the combined properties of two metals.CuPd shows enhanced CO2 reduction activity compared to copper alone.Using differential electrochemical mass spectrometry(DEMS)and electrochemical infrared(IR)spectroscopy,volatile products and adsorbed intermediates were measured during CO2 and CO reduction on Cu and CuPd.The IR band corresponding to adsorbed CO appears 300 mV more positive on CuPd than that on Cu,indicating acceleration of CO2 reduction to CO.Electrochemical IR spectroscopy measurements in CO-saturated solutions reveal similar potentials for CO adsorption and CO3^2-desorption on CuPd and Cu,indicating that CO adsorption is controlled by desorption of CO3^2-.DEMS measurements carried out during CO reduction at both electrodes showed that the onset potential for reduction of CO to CH4 and CH3OH on CuPd is about 200 mV more positive than that on Cu.We attribute these improvements to interaction of Cu and Pd,which shifts the d-band center of the Cu sites.展开更多
In recent years,natural disasters in coastal areas have become more frequent due to sea level rise and other impact factors under the scenario of global warming,causing great losses to human society.Mangrove forest,an...In recent years,natural disasters in coastal areas have become more frequent due to sea level rise and other impact factors under the scenario of global warming,causing great losses to human society.Mangrove forest,an important shelterbelt in coastal areas,plays an extremely important role in reducing the coastal hazards risk.In this paper,the effects of mangrove ecosystem on coastal hazards reduction are reviewed from the aspects of wind prevention,wave attenuation,sedimentation acceleration,tsunamis mitigation,and provide theoretical support and technical guidance for the protection and cultivation of mangrove forests.展开更多
A continuous online in situ attenuated total reflection Fourier-transform infrared(ATR-FTIR)spectroscopic technique was used to investigate the adsorption and desorption kinetics of heptyl xanthate(KHX)on the surface ...A continuous online in situ attenuated total reflection Fourier-transform infrared(ATR-FTIR)spectroscopic technique was used to investigate the adsorption and desorption kinetics of heptyl xanthate(KHX)on the surface of ZnO and Cu(Ⅱ)activated ZnO.The results showed that Cu(Ⅱ)facilitated the xanthate adsorption process on the surface,and led to the formation of cuprous xanthate(CuX),dixanthogen(X_(2))and xanthate aggregates.The adsorption of xanthate on the surface of ZnO and Cu(Ⅱ)activated ZnO was found to both follow the pseudo-first-order kinetic model.When the NaOH solution was used as a desorption agent,the adsorbed xanthate can largely be removed due to the competition between OH^(−)and HX−.However,for Cu(Ⅱ)activated ZnO,the peak intensities at 1197 and 1082 cm^(−1) had no obvious weakening,and the absorption intensities at 1261 and 1026 cm^(−1) increased in the first 5 min,indicating an ion-exchange reaction between OH^(−)and surface zinc bonded xanthate HX−and the reorganization of adsorbed xanthate.展开更多
In the present work,a nanoporous ZnO/n-Si structure has been proposed as a new type infrared photodetector.Triggered by one laser pulse with wavelength of 1064 nm,this structure exhibits a double-peak decay of transie...In the present work,a nanoporous ZnO/n-Si structure has been proposed as a new type infrared photodetector.Triggered by one laser pulse with wavelength of 1064 nm,this structure exhibits a double-peak decay of transient photovoltage.Also,the time interval between these two peaks increases linearly with the increase of irradiated pulsed energy,indicating the promising application of this hetero-junction in photo-energy detection of infrared pulsed laser.A possible mechanism for this particular photoresponse has been discussed.展开更多
Protic ionic liquid (PIL) triethylammonium acetate was prepared by mixing equimolar amounts of acetic acid and triethylamine, and then studied using the combination of the Attenuated Total Reflection Fourier Transform...Protic ionic liquid (PIL) triethylammonium acetate was prepared by mixing equimolar amounts of acetic acid and triethylamine, and then studied using the combination of the Attenuated Total Reflection Fourier Transform Infrared spectroscopy, in-situ infrared spectroscopy, pH, and conductivity titration measurements. It was found that the equimolar synthesized triethylammonium acetate was separated into two layers, which suggesting that there were both chemical and phase equilibrium in this solution. Molecular species could be directly observed in the IR spectra over the range of 1200-1800 cm-1 and also checked by 1H NMR. Based on analysis, the upper layer was rich in amine with little acid and PIL, and the down layer was rich in PIL with residual acetic acid and amine. And single PIL-rich layer could be separated into two layers again when the mole ratio of newly added triethyamine to the theoretical produced triethylammonium acetate reached 0.12.展开更多
基金Supported by State Key Laboratory of Loess and Quaternary Geology Open-end Fund(SKLLQG1426)Post-doctoral Foundation and National Natural Science Foundation of China(41102107)~~
文摘This paper introduced domestic and overseas status, the historical evolution and the development history of earthquake disaster reduction planning. The urgencies and realistic significance were analyzed to carry out earthquake disaster reduction planning for districts or countries in the northwest. With Hongsibao District in Wuzhong City, Ningxia Province as an example, this article analyzed in detail the present situation and the special problems of earthquake disaster reduction planning in Northwest China. The relevant solving measures were put forward in order to offer a reference for the scientific establishment and effective implementation of earth- quake disaster reduction planning in Northwest China. The foundation of earthquake disaster reduction in the Hongsibao District is still very weak, there is a single earthquake monitoring means, the emergency rescue system is not complete, the working mechanism is not perfect, and the lack of funding for the work of earthquake disaster reduction.
文摘Methanol oxidation reaction (MOR) at Pt and Pt electrode surface deposited with various amounts of Ru (denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML) in 0.1 mol/L HClO4+0.5 mol/L MeOH has been studied under potentiostatic conditions by in situ FTIR spectroscopy in attenuated-total-reflection con guration and di erential electro-chemical mass spectrometry under controlled flow conditions. Results reveal that (i) CO is the only methanol-related adsorbate observed by IR spectroscopy at all the Pt and PtRu electrodes examined at potentials from 0.3 V to 0.6 V (vs. RHE); (ii) at Pt0.56Ru0.44, two IR bands, one from CO adsorbed at Ru islands and the other from COL at Pt substrate are detected, while at other electrodes, only a single band for COL adsorbed at Pt is observed; (iii) MOR activity decreases in the order of Pt0.73Ru0.27〉Pt0.56Ru0.44〉Pt0.83Ru0.17〉Pt; (iv) at 0.5 V, MOR at Pt0.73Ru0.27 reaches a current e ciency of 50% for CO2 production, the turn-over frequency from CH3OH to CO2 is ca. 0.1 molecule/(site sec). Suggestions for further improving of PtRu catalysts for MOR are provided.
文摘The influence of the drop-casted nickel boride catalyst loading on glassy carbon electrodes was investigated in a spectroelectrochemical ATR-FTIR thin-film flow cell applied in alkaline glycerol electrooxidation.The continuously operated radial flow cell consisted of a borehole electrode positioned 50μm above an internal reflection element enabling operando FTIR spectroscopy.It is identified as a suitable tool for facile and reproducible screening of electrocatalysts under well-defined conditions,additionally providing access to the selectivities in complex reaction networks such as glycerol oxidation.The fast product identification by ATR-IR spectroscopy was validated by the more time-consuming quantitative HPLC analysis of the pumped electrolyte.High degrees of glycerol conversion were achieved under the applied laminar flow conditions using 0.1 M glycerol and 1 M KOH in water and a flow rate of 5μL min^(–1).Conversion and selectivity were found to depend on the catalyst loading,which determined the catalyst layer thickness and roughness.The highest loading of 210μg cm^(–2)resulted in 73%conversion and a higher formate selectivity of almost 80%,which is ascribed to longer residence times in rougher films favoring readsorption and C–C bond scission.The lowest loading of 13μg cm^(–2)was sufficient to reach 63%conversion,a lower formate selectivity of 60%,and,correspondingly,higher selectivities of C_(2)species such as glycolate amounting to 8%.Thus,only low catalyst loadings resulting in very thin films in the fewμm thickness range are suitable for reliable catalyst screening.
基金supported by the National Natural Science Foundation of China(No.91545124 and No.21750110437)supported by the Chinese Academy of Sciences President’s International Fellowship Initiative(No.2017PM0049)。
文摘Bimetallic catalysts can improve CO2 reduction efficiency via the combined properties of two metals.CuPd shows enhanced CO2 reduction activity compared to copper alone.Using differential electrochemical mass spectrometry(DEMS)and electrochemical infrared(IR)spectroscopy,volatile products and adsorbed intermediates were measured during CO2 and CO reduction on Cu and CuPd.The IR band corresponding to adsorbed CO appears 300 mV more positive on CuPd than that on Cu,indicating acceleration of CO2 reduction to CO.Electrochemical IR spectroscopy measurements in CO-saturated solutions reveal similar potentials for CO adsorption and CO3^2-desorption on CuPd and Cu,indicating that CO adsorption is controlled by desorption of CO3^2-.DEMS measurements carried out during CO reduction at both electrodes showed that the onset potential for reduction of CO to CH4 and CH3OH on CuPd is about 200 mV more positive than that on Cu.We attribute these improvements to interaction of Cu and Pd,which shifts the d-band center of the Cu sites.
文摘In recent years,natural disasters in coastal areas have become more frequent due to sea level rise and other impact factors under the scenario of global warming,causing great losses to human society.Mangrove forest,an important shelterbelt in coastal areas,plays an extremely important role in reducing the coastal hazards risk.In this paper,the effects of mangrove ecosystem on coastal hazards reduction are reviewed from the aspects of wind prevention,wave attenuation,sedimentation acceleration,tsunamis mitigation,and provide theoretical support and technical guidance for the protection and cultivation of mangrove forests.
基金supported by the National Natural Science Foundation of China (Nos.51274104,50874052)the National Basic Research Program of China (No.2011CB933700)。
文摘A continuous online in situ attenuated total reflection Fourier-transform infrared(ATR-FTIR)spectroscopic technique was used to investigate the adsorption and desorption kinetics of heptyl xanthate(KHX)on the surface of ZnO and Cu(Ⅱ)activated ZnO.The results showed that Cu(Ⅱ)facilitated the xanthate adsorption process on the surface,and led to the formation of cuprous xanthate(CuX),dixanthogen(X_(2))and xanthate aggregates.The adsorption of xanthate on the surface of ZnO and Cu(Ⅱ)activated ZnO was found to both follow the pseudo-first-order kinetic model.When the NaOH solution was used as a desorption agent,the adsorbed xanthate can largely be removed due to the competition between OH^(−)and HX−.However,for Cu(Ⅱ)activated ZnO,the peak intensities at 1197 and 1082 cm^(−1) had no obvious weakening,and the absorption intensities at 1261 and 1026 cm^(−1) increased in the first 5 min,indicating an ion-exchange reaction between OH^(−)and surface zinc bonded xanthate HX−and the reorganization of adsorbed xanthate.
基金supported by the National Key Basic Research Program of China (Grant No. 2014CB744300)the Specially Funded Program on National Key Scientific Instruments and Equipment Development (GrantNo. 2012YQ140005)+1 种基金the Beijing National Science Foundation (Grant No. 4122064)the Science Foundation of the China University of Petroleum (Beijing)
文摘In the present work,a nanoporous ZnO/n-Si structure has been proposed as a new type infrared photodetector.Triggered by one laser pulse with wavelength of 1064 nm,this structure exhibits a double-peak decay of transient photovoltage.Also,the time interval between these two peaks increases linearly with the increase of irradiated pulsed energy,indicating the promising application of this hetero-junction in photo-energy detection of infrared pulsed laser.A possible mechanism for this particular photoresponse has been discussed.
基金supported by the National Natural Science Foundation of China (20990221, 20976151)
文摘Protic ionic liquid (PIL) triethylammonium acetate was prepared by mixing equimolar amounts of acetic acid and triethylamine, and then studied using the combination of the Attenuated Total Reflection Fourier Transform Infrared spectroscopy, in-situ infrared spectroscopy, pH, and conductivity titration measurements. It was found that the equimolar synthesized triethylammonium acetate was separated into two layers, which suggesting that there were both chemical and phase equilibrium in this solution. Molecular species could be directly observed in the IR spectra over the range of 1200-1800 cm-1 and also checked by 1H NMR. Based on analysis, the upper layer was rich in amine with little acid and PIL, and the down layer was rich in PIL with residual acetic acid and amine. And single PIL-rich layer could be separated into two layers again when the mole ratio of newly added triethyamine to the theoretical produced triethylammonium acetate reached 0.12.