The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay ...The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay periods. When the anodes were immersed into acid zinc sulphate electrolyte without MnO4- ions, the Pb-0.72%Ag anode entered complete passivation state in the shortest time among the five anodes, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by measurement of open circuit potential. During immersion of the anodes, MnO4 ions accelerated the passivation and increased the corrosion current density of the anodes. After immersion in zinc electrolyte with MnO4-, the anode Pb-0.72%Ag had the best corrosion resistance, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, then the close anodes Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by the electrochemical impedance spectroscopy （EIS） analysis.展开更多
In the present work,a nanoporous ZnO/n-Si structure has been proposed as a new type infrared photodetector.Triggered by one laser pulse with wavelength of 1064 nm,this structure exhibits a double-peak decay of transie...In the present work,a nanoporous ZnO/n-Si structure has been proposed as a new type infrared photodetector.Triggered by one laser pulse with wavelength of 1064 nm,this structure exhibits a double-peak decay of transient photovoltage.Also,the time interval between these two peaks increases linearly with the increase of irradiated pulsed energy,indicating the promising application of this hetero-junction in photo-energy detection of infrared pulsed laser.A possible mechanism for this particular photoresponse has been discussed.展开更多
ZnS:Mn2+ nanocrystals(NCs) with particle size from 1.9 nm to 3.2 nm are synthesized via chemical precipitation method with different [S2-]/[Zn2+] ratios.The size-dependent decay for Mn emission exhibits a double expon...ZnS:Mn2+ nanocrystals(NCs) with particle size from 1.9 nm to 3.2 nm are synthesized via chemical precipitation method with different [S2-]/[Zn2+] ratios.The size-dependent decay for Mn emission exhibits a double exponential behavior.And two lifetime values,in millisecond time domain,can both be shortened with size increasing,which is attributed to enhanced interaction between host and Mn2+ impurity.A molecular structure model is proposed to interpret the tendency of two lifetime components,which is correlated to the number of S vacancy(Vs) defects around Mn2+.展开更多
基金Project(RDCPJ346365-06)supported by the Natural Sciences and Engineering Research Council of CanadaProject(51208193)supported by the National Natural Science Foundation of ChinaProject(11jj6034)supported by the Hunan Provincial Natural Science Foundation
文摘The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay periods. When the anodes were immersed into acid zinc sulphate electrolyte without MnO4- ions, the Pb-0.72%Ag anode entered complete passivation state in the shortest time among the five anodes, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by measurement of open circuit potential. During immersion of the anodes, MnO4 ions accelerated the passivation and increased the corrosion current density of the anodes. After immersion in zinc electrolyte with MnO4-, the anode Pb-0.72%Ag had the best corrosion resistance, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, then the close anodes Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by the electrochemical impedance spectroscopy （EIS） analysis.
基金supported by the National Key Basic Research Program of China (Grant No. 2014CB744300)the Specially Funded Program on National Key Scientific Instruments and Equipment Development (GrantNo. 2012YQ140005)+1 种基金the Beijing National Science Foundation (Grant No. 4122064)the Science Foundation of the China University of Petroleum (Beijing)
文摘In the present work,a nanoporous ZnO/n-Si structure has been proposed as a new type infrared photodetector.Triggered by one laser pulse with wavelength of 1064 nm,this structure exhibits a double-peak decay of transient photovoltage.Also,the time interval between these two peaks increases linearly with the increase of irradiated pulsed energy,indicating the promising application of this hetero-junction in photo-energy detection of infrared pulsed laser.A possible mechanism for this particular photoresponse has been discussed.
基金supported by the National Natural Science Foundation of China(Nos.60877029,10904109,60977035 and 60907021)the Natural Science Foundation of Tianjin(No.09JCYBJC01400)the Tianjin Key Subject for Materials Physics and Chemistry
文摘ZnS:Mn2+ nanocrystals(NCs) with particle size from 1.9 nm to 3.2 nm are synthesized via chemical precipitation method with different [S2-]/[Zn2+] ratios.The size-dependent decay for Mn emission exhibits a double exponential behavior.And two lifetime values,in millisecond time domain,can both be shortened with size increasing,which is attributed to enhanced interaction between host and Mn2+ impurity.A molecular structure model is proposed to interpret the tendency of two lifetime components,which is correlated to the number of S vacancy(Vs) defects around Mn2+.
