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浅论铝盐的水解和吸附电中和过程中被凝聚物浓度的影响 被引量:12
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作者 王晓昌 《环境化学》 CAS CSCD 北大核心 1996年第6期530-535,共6页
通过对凝聚机理和铝盐在水中水解过程的分析,提出了铝盐水解物吸附引起胶体电中和的数学模式.论述了被凝聚物浓度对铝盐水解过程的影响.在实际的凝聚过程中,铝盐的水解和向胶体表面的吸附是同时进行的,部分铝盐在完成水解之前就以中间... 通过对凝聚机理和铝盐在水中水解过程的分析,提出了铝盐水解物吸附引起胶体电中和的数学模式.论述了被凝聚物浓度对铝盐水解过程的影响.在实际的凝聚过程中,铝盐的水解和向胶体表面的吸附是同时进行的,部分铝盐在完成水解之前就以中间产物的形态吸附于胶体表面.胶体溶液的浓度愈高,这种倾向就愈强.由于较低水解度的物种具有较高的单位电荷浓度,它们能显示较强的电中和能力;因此,随着胶体溶液浓度的增高,达到最佳凝聚ζ电位所需的比投药量会降低. 展开更多
关键词 铝盐 水解 吸附电中和 Ζ电位 凝聚浓度
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BCl_(3)同位素分离中二聚体的浓度 被引量:1
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作者 李业军 郭静 +3 位作者 马俊平 唐显 李鑫 闫冰 《物理学报》 SCIE EI CAS CSCD 北大核心 2022年第24期158-164,共7页
在激光辅助凝聚抑制同位素分离的过冷超饱和超声速气流中,同位素分子BCl_(3)与载气原子(稀有气体原子RG:He,Ne,Ar,Kr,Xe)间的接触碰撞形成二聚体BCl_(3):RG,二聚体浓度与温度等参数的关系对同位素分离中参数调控与选择具有重要意义.本... 在激光辅助凝聚抑制同位素分离的过冷超饱和超声速气流中,同位素分子BCl_(3)与载气原子(稀有气体原子RG:He,Ne,Ar,Kr,Xe)间的接触碰撞形成二聚体BCl_(3):RG,二聚体浓度与温度等参数的关系对同位素分离中参数调控与选择具有重要意义.本文基于分子间相互作用解析势函数,考虑二体、三体碰撞诱导的二聚体缔合与解离,给出了BCl_(3):RG二聚体浓度随绝对温度变化的关系.结果表明:二体碰撞在BCl_(3):RG形成中占据主导,在BCl_(3)初始摩尔分数为0.01-0.10内,BCl_(3):RG二聚体浓度随BCl_(3)初始摩尔分数变化大致呈线性关系,初始摩尔分数不仅决定理论上二聚体浓度的极限值,还主导了低温区二聚体浓度;在超声速流气室温度为20 K左右时,采用较重的惰性气体Kr形成二聚体的浓度最大,同时给出了不同温度区间各种载气对应的二聚体浓度大小;进一步,通过二聚体中有效解离能和伸缩振动频率等参数的变化,在分子尺度上利用简单模型解释了激光辅助凝聚抑制的内在微观机制. 展开更多
关键词 激光激发同位素分离 BCl_(3) 二聚体 凝聚浓度
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Study on Application of Novel Flocculating Agent in Treating Refinery Wastewater with High Concentration of Pollutants
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作者 Zhang Baoji Qin Bing(SINOPEC Research Institute of Petroleum Processing,Beijing 100083) 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2009年第2期57-61,共5页
After conducting a lot of screening experiments the appropriate flocculating formulations for treating high-concentration wastewater discharged from a certain refinery were selected. The oil removal rate and COD remov... After conducting a lot of screening experiments the appropriate flocculating formulations for treating high-concentration wastewater discharged from a certain refinery were selected. The oil removal rate and COD removal achieved by these flocculating formulations were better than that achieved by the conventional compound formulation consisting of polyaluminium chloride(PAC) and polyacrylamide(PAA) . Addition of an oil/water separating agent to the formulation could improve its oil removal performance to facilitate the oil/water separation of the oil-in-water emulsion in the high-concentration wastewater along with improved adaptability of the formulation to the wastewater containing high concentration of pollutants. This flocculating agent has promising prospects for commercial application. 展开更多
关键词 WASTEWATER POLLUTANTS flocculating agent oil/water separation
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Effects of Ionic Dependence of DNA Persistence Length on the DNA Condensation at Room Temperature
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作者 毛伟 刘艳辉 +1 位作者 胡林 许厚强 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第5期639-644,共6页
DNA persistence length is a key parameter for quantitative interpretation of the conformational properties of DNA and related to the bending rigidity of DNA.A series of experiments pointed out that,in the DNA condensa... DNA persistence length is a key parameter for quantitative interpretation of the conformational properties of DNA and related to the bending rigidity of DNA.A series of experiments pointed out that,in the DNA condensation process by multivalent cations,the condensed DNA takes elongated coil or compact globule states and the population of the compact globule states increases with an increase in ionic concentration.At the same time,single molecule experiments carried out in solution with multivalent cations(such as spermidine,spermine)indicated that DNA persistence length strongly depends on the ionic concentration.In order to revolve the effects of ionic concentration dependence of persistence length on DNA condensation,a model including the ionic concentration dependence of persistence length and strong correlation of multivalent cation on DNA is provided.The autocorrelation function of the tangent vectors is found as an effective way to detect the ionic concentration dependence of toroidal conformations.With an increase in ion concentration,the first periodic oscillation contained in the autocorrelation function shifts,the number of segment contained in the first periodic oscillation decreases gradually.According to the experiments,the average long-axis length is defined to estimate the ionic concentration dependence of condensation process further.The relation between long-axis length and ionic concentration matches the experimental results qualitatively. 展开更多
关键词 DNA condensation Monte Carlo simulation persistence length multivalent cation
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