The adsorption and reaction of formic acid (HCOOH) on clean and atomic oxygen‐covered Au(997) surfaces were studied by temperature‐programmed desorption/reaction spectroscopy (TPRS) and X‐ray photoelectron sp...The adsorption and reaction of formic acid (HCOOH) on clean and atomic oxygen‐covered Au(997) surfaces were studied by temperature‐programmed desorption/reaction spectroscopy (TPRS) and X‐ray photoelectron spectroscopy (XPS). At 105 K, HCOOH molecularly adsorbs on clean Au(997) and interacts more strongly with low‐coordinated Au atoms at (111) step sites than with those at (111) terrace sites. On an atomic oxygen‐covered Au(997) surface, HCOOH reacts with oxygen at‐oms to form HCOO and OH at 105 K. Upon subsequent heating, surface reactions occur among ad‐sorbed HCOO, OH, and atomic oxygen and produce CO2, H2O, and HCOOH between 250 and 400 K. The Au(111) steps bind surface adsorbates more strongly than the Au(111) terraces and exhibit larger barriers for HCOO(a) oxidation reactions. The surface reactions also depend on the relative coverages of co‐existing surface species. Our results elucidate the elementary surface reactions between formic acid and oxygen adatoms on Au surfaces and highlight the effects of the coordina‐tion number of the Au atoms on the Au catalysis.展开更多
This paper derives a non-stationary multiple-input multiple-output(MIMO) from the one-ring scattering model. The proposed channel model characterizes vehicular radio propagation channels with considerations of moving ...This paper derives a non-stationary multiple-input multiple-output(MIMO) from the one-ring scattering model. The proposed channel model characterizes vehicular radio propagation channels with considerations of moving base and mobile stations, which makes the angle of arrivals(AOAs) along with the angle of departures(AODs) time-variant. We introduce the methodology of including the time-variant impacts when characterizing non-stationary radio propagation channels through the geometrical channel modelling approach. We analyze the statistical properties of the proposed channel model including the local time-variant autocorrelation function(ACF) and the space cross-correlation functions(CCFs). We show that the model developed in this paper for non-stationary scenarios includes the existing one-ring wide-sense stationary channel model as its special case.展开更多
The stress analysis of surrounding rock for two random geometry tunnels is studied in this paper by using Schwarz’s alternating method. The simple and effective alternating algorithm is found, in which the surplus su...The stress analysis of surrounding rock for two random geometry tunnels is studied in this paper by using Schwarz’s alternating method. The simple and effective alternating algorithm is found, in which the surplus surface force is approximated by Fourier series, thus the iteration derivation can be conducted according to the precision required, finally, the stress results with high precision are obtained.展开更多
In the model of geometric programming, values of parameters cannot be gotten owing to data fluctuation and incompletion. But reasonable bounds of these parameters can be attained. This is to say, parameters of this mo...In the model of geometric programming, values of parameters cannot be gotten owing to data fluctuation and incompletion. But reasonable bounds of these parameters can be attained. This is to say, parameters of this model can be regarded as interval grey numbers. When the model contains grey numbers, it is hard for common programming method to solve them. By combining the common programming model with the grey system theory, and using some analysis strategies, a model of grey polynomial geometric programming, a model of θ positioned geometric programming and their quasi-optimum solution or optimum solution are put forward. At the same time, we also developed an algorithm for the problem. This approach brings a new way for the application research of geometric programming. An example at the end of this paper shows the rationality and feasibility of the algorithm.展开更多
Several models in noncommutative geometry (NCG) with mild changes to the standard model are introduced to discuss the neutrino mass problem. We use two constraints, Poincaré duality and gauge anomaly free, to dis...Several models in noncommutative geometry (NCG) with mild changes to the standard model are introduced to discuss the neutrino mass problem. We use two constraints, Poincaré duality and gauge anomaly free, to discuss the possibility of containing right-handed neutrinos in them. Our work shows that no model in this paper, with each generation containing a right-handed neutrino, can satisfy these two constraints at the same time. So, to consist with neutrino oscillation experiment results, maybe fundamental changes to the present version of NCG are usually needed to include Dirac massive neutrinos.展开更多
The mathematical modeling for evaluation of the sphericity error is proposed with minimum radial separation center. To obtain the minimum sphericity error from the form data, a geometric approximation technique was de...The mathematical modeling for evaluation of the sphericity error is proposed with minimum radial separation center. To obtain the minimum sphericity error from the form data, a geometric approximation technique was devised. The technique regarded the least square sphere center as the initial center of the concentric spheres containing all measurement points, and then the center was moved gradually to reduce the radial separation till the minimum radial separation center was got where the constructed concentric spheres conformed to the minimum zone condition. The method was modeled firstly, then the geometric approximation process was analyzed, and finally,the software for data processing was programmed. As evaluation example, five steel balls were measured and the measurement data were processed with the developed program. The average iteration times of the approximation technique is 4.2, and on average the obtained sphericity error is 0. 529μm smaller than the least square solution,with accuracy increased by 7. 696%.展开更多
Aiming at the issue of the grinding integrity of face-gear with worm wheel, the envelope mathematical model of shaper, worm wheel and face-gear is established based on theories of differential geometry and gear mesh. ...Aiming at the issue of the grinding integrity of face-gear with worm wheel, the envelope mathematical model of shaper, worm wheel and face-gear is established based on theories of differential geometry and gear mesh. The judgment of completely grinding the face-gear with the avoidance of singularities is established, and the mathematical expression to show the reason why singularities appear is derived, through the research on the surface contact area and singularity rules of the worm thread surface. The disadvantage of current face-gear grinding method that only part of the working surface of the face-gear can be covered is analyzed and the influence of coefficient of judgment is studied through changing the design parameters.展开更多
An information model is defined to support sharing scientific information on Web for archaeological pottery. Apart from non-shape information, such as age, material, etc., the model also consists of shape information ...An information model is defined to support sharing scientific information on Web for archaeological pottery. Apart from non-shape information, such as age, material, etc., the model also consists of shape information and shape feature information. Shape information is collected by Lasers Scanner and geometric modelling techniques. Feature information is generated from shape information via feature extracting techniques. The model is used in an integrated storage, archival, and sketch-based query and retrieval system for 3D objects, native American ceramic vessels. A novel aspect of the information model is that it is totally implemented with XML, and is designed for Web-based visual query and storage application.展开更多
Positional error of line segments is usually described by using "g-band", however, its band width is in relation to the confidence level choice. In fact, given different confidence levels, a series of concen...Positional error of line segments is usually described by using "g-band", however, its band width is in relation to the confidence level choice. In fact, given different confidence levels, a series of concentric bands can be obtained. To overcome the effect of confidence level on the error indicator, by introducing the union entropy theory, we propose an entropy error ellipse index of point, then extend it to line segment and polygon, and establish an entropy error band of line segment and an entropy error donut of polygon. The research shows that the entropy error index can be determined uniquely and is not influenced by confidence level, and that they are suitable for positional uncertainty of planar geometry features.展开更多
A mathematic model is established using infinitesimal geometry for the cutting edge design of special milling cutters which use equal lead helix as cutting edges; equations are given for front-end and proclitic surfac...A mathematic model is established using infinitesimal geometry for the cutting edge design of special milling cutters which use equal lead helix as cutting edges; equations are given for front-end and proclitic surface of revolution of ball pillar milling cutters, ball taper milling cutters and angularly conical milling cutters; and corresponding models are established for the continuity cutting edge curves of milling cutters. Typical examples are given to illustrate the applications of mathematic models, which prove the correctness and applicability of these geometric models.展开更多
The effects of geometry on mechanical properties in woven fabric composites were explored. Two types of composites, including one-layered and two-layered composites, were designed and studied. For one-layered composit...The effects of geometry on mechanical properties in woven fabric composites were explored. Two types of composites, including one-layered and two-layered composites, were designed and studied. For one-layered composites, inter-strand gap effects on the mechanical properties were studied, while three cases of geometries with inter-strand gaps in two-layered composites were evaluated. A woven fiber micromechanics analytical model called MESOTEX was employed for theoretical simulation. The predicted results show that the inter-strand gap and simple variation of the strand positions in a repeating unit cell significantly affect the mechanical properties of woven fabric composites.展开更多
A great attention has been paid to slowing the degradation of coal nowadays. The spiral bunker is the main measure to lower the degradation. In this paper the application and research of spiral bunker are introduced. ...A great attention has been paid to slowing the degradation of coal nowadays. The spiral bunker is the main measure to lower the degradation. In this paper the application and research of spiral bunker are introduced. And two non-normal spiral chutes are discussed. One is in the tangential direction of the inner wall of the bunker, another is in the direction of the diameter of the bunker. Mathematical models of the non-normal spiral chutes are set up to optimize the geometrical parameters of the spiral curved surface, which would ensure that coal travels smoothly to the bottom of the bunker. The results would be useful for designing and retrofitting the spiral bunker.展开更多
This paper is devoted to a study of geometric properties of AR(q) nonlinear regression models. We present geometric frameworks for regression parameter space and autoregression parameter space respectively based on th...This paper is devoted to a study of geometric properties of AR(q) nonlinear regression models. We present geometric frameworks for regression parameter space and autoregression parameter space respectively based on the weighted inner product by fisher information matrix. Several geometric properties related to statistical curvatures are given for the models. The results of this paper extended the work of Bates & Watts(1980,1988)[1.2] and Seber & Wild (1989)[3].展开更多
Most implantation cases are implemented using implants selected from the available standard set, but in some cases, only those implants conforming to individual patient's skeletal morphology can serve the purpose....Most implantation cases are implemented using implants selected from the available standard set, but in some cases, only those implants conforming to individual patient's skeletal morphology can serve the purpose. This paper proposes a new approach to design and fabricate custom-made exact-fit medical implants. With a real surgical case as the example,technical design details are presented; and three algorithms are given respectively for segmentation based on object features, triangular mesh defragmentation and mesh cutting.展开更多
基金supported by the National Basic Research Program of China (973 Program, 2013CB933104)the National Natural Science Foundation of China (21525313, 20973161, 21373192)+1 种基金the Fundamental Research Funds for the Central Universities (WK2060030017)Collaborative In-novation Center of Suzhou Nano Science and Technology~~
文摘The adsorption and reaction of formic acid (HCOOH) on clean and atomic oxygen‐covered Au(997) surfaces were studied by temperature‐programmed desorption/reaction spectroscopy (TPRS) and X‐ray photoelectron spectroscopy (XPS). At 105 K, HCOOH molecularly adsorbs on clean Au(997) and interacts more strongly with low‐coordinated Au atoms at (111) step sites than with those at (111) terrace sites. On an atomic oxygen‐covered Au(997) surface, HCOOH reacts with oxygen at‐oms to form HCOO and OH at 105 K. Upon subsequent heating, surface reactions occur among ad‐sorbed HCOO, OH, and atomic oxygen and produce CO2, H2O, and HCOOH between 250 and 400 K. The Au(111) steps bind surface adsorbates more strongly than the Au(111) terraces and exhibit larger barriers for HCOO(a) oxidation reactions. The surface reactions also depend on the relative coverages of co‐existing surface species. Our results elucidate the elementary surface reactions between formic acid and oxygen adatoms on Au surfaces and highlight the effects of the coordina‐tion number of the Au atoms on the Au catalysis.
基金supported by Shandong Agricultural University Funding of First-class DisciplinesShandong Agricultural University Key Cultivation Discipline Funding for NSFC Proposers+1 种基金supported by Grant of Beihang University Beidou Technology Transformation and Industrialization (BARI1709)Open Project of National Engineering Research Center for Information Technology in Agriculture (No.KF2015W003)
文摘This paper derives a non-stationary multiple-input multiple-output(MIMO) from the one-ring scattering model. The proposed channel model characterizes vehicular radio propagation channels with considerations of moving base and mobile stations, which makes the angle of arrivals(AOAs) along with the angle of departures(AODs) time-variant. We introduce the methodology of including the time-variant impacts when characterizing non-stationary radio propagation channels through the geometrical channel modelling approach. We analyze the statistical properties of the proposed channel model including the local time-variant autocorrelation function(ACF) and the space cross-correlation functions(CCFs). We show that the model developed in this paper for non-stationary scenarios includes the existing one-ring wide-sense stationary channel model as its special case.
文摘The stress analysis of surrounding rock for two random geometry tunnels is studied in this paper by using Schwarz’s alternating method. The simple and effective alternating algorithm is found, in which the surplus surface force is approximated by Fourier series, thus the iteration derivation can be conducted according to the precision required, finally, the stress results with high precision are obtained.
基金Supported by the NSF Jiangsu Province(BK2003211)Supported by the NSF of Henan Province(2003120001)
文摘In the model of geometric programming, values of parameters cannot be gotten owing to data fluctuation and incompletion. But reasonable bounds of these parameters can be attained. This is to say, parameters of this model can be regarded as interval grey numbers. When the model contains grey numbers, it is hard for common programming method to solve them. By combining the common programming model with the grey system theory, and using some analysis strategies, a model of grey polynomial geometric programming, a model of θ positioned geometric programming and their quasi-optimum solution or optimum solution are put forward. At the same time, we also developed an algorithm for the problem. This approach brings a new way for the application research of geometric programming. An example at the end of this paper shows the rationality and feasibility of the algorithm.
文摘Several models in noncommutative geometry (NCG) with mild changes to the standard model are introduced to discuss the neutrino mass problem. We use two constraints, Poincaré duality and gauge anomaly free, to discuss the possibility of containing right-handed neutrinos in them. Our work shows that no model in this paper, with each generation containing a right-handed neutrino, can satisfy these two constraints at the same time. So, to consist with neutrino oscillation experiment results, maybe fundamental changes to the present version of NCG are usually needed to include Dirac massive neutrinos.
基金Supported by National Natural Science Foundation of China(No.50175081) andTianjin Municipal Science and Technology Commission (No.0431835116).
文摘The mathematical modeling for evaluation of the sphericity error is proposed with minimum radial separation center. To obtain the minimum sphericity error from the form data, a geometric approximation technique was devised. The technique regarded the least square sphere center as the initial center of the concentric spheres containing all measurement points, and then the center was moved gradually to reduce the radial separation till the minimum radial separation center was got where the constructed concentric spheres conformed to the minimum zone condition. The method was modeled firstly, then the geometric approximation process was analyzed, and finally,the software for data processing was programmed. As evaluation example, five steel balls were measured and the measurement data were processed with the developed program. The average iteration times of the approximation technique is 4.2, and on average the obtained sphericity error is 0. 529μm smaller than the least square solution,with accuracy increased by 7. 696%.
基金Projects(51275530,51535012) supported by the National Natural Science Foundation of ChinaProject(2011CB706800) supported by the National Basic Research Program of China
文摘Aiming at the issue of the grinding integrity of face-gear with worm wheel, the envelope mathematical model of shaper, worm wheel and face-gear is established based on theories of differential geometry and gear mesh. The judgment of completely grinding the face-gear with the avoidance of singularities is established, and the mathematical expression to show the reason why singularities appear is derived, through the research on the surface contact area and singularity rules of the worm thread surface. The disadvantage of current face-gear grinding method that only part of the working surface of the face-gear can be covered is analyzed and the influence of coefficient of judgment is studied through changing the design parameters.
基金Project (No. IIS-9980166) supported by the National NaturalScience Foundation of America
文摘An information model is defined to support sharing scientific information on Web for archaeological pottery. Apart from non-shape information, such as age, material, etc., the model also consists of shape information and shape feature information. Shape information is collected by Lasers Scanner and geometric modelling techniques. Feature information is generated from shape information via feature extracting techniques. The model is used in an integrated storage, archival, and sketch-based query and retrieval system for 3D objects, native American ceramic vessels. A novel aspect of the information model is that it is totally implemented with XML, and is designed for Web-based visual query and storage application.
基金ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .40 0 71 0 68) .
文摘Positional error of line segments is usually described by using "g-band", however, its band width is in relation to the confidence level choice. In fact, given different confidence levels, a series of concentric bands can be obtained. To overcome the effect of confidence level on the error indicator, by introducing the union entropy theory, we propose an entropy error ellipse index of point, then extend it to line segment and polygon, and establish an entropy error band of line segment and an entropy error donut of polygon. The research shows that the entropy error index can be determined uniquely and is not influenced by confidence level, and that they are suitable for positional uncertainty of planar geometry features.
文摘A mathematic model is established using infinitesimal geometry for the cutting edge design of special milling cutters which use equal lead helix as cutting edges; equations are given for front-end and proclitic surface of revolution of ball pillar milling cutters, ball taper milling cutters and angularly conical milling cutters; and corresponding models are established for the continuity cutting edge curves of milling cutters. Typical examples are given to illustrate the applications of mathematic models, which prove the correctness and applicability of these geometric models.
基金Work supported by the Second Stage of the Brain Korea 21 Projects
文摘The effects of geometry on mechanical properties in woven fabric composites were explored. Two types of composites, including one-layered and two-layered composites, were designed and studied. For one-layered composites, inter-strand gap effects on the mechanical properties were studied, while three cases of geometries with inter-strand gaps in two-layered composites were evaluated. A woven fiber micromechanics analytical model called MESOTEX was employed for theoretical simulation. The predicted results show that the inter-strand gap and simple variation of the strand positions in a repeating unit cell significantly affect the mechanical properties of woven fabric composites.
文摘A great attention has been paid to slowing the degradation of coal nowadays. The spiral bunker is the main measure to lower the degradation. In this paper the application and research of spiral bunker are introduced. And two non-normal spiral chutes are discussed. One is in the tangential direction of the inner wall of the bunker, another is in the direction of the diameter of the bunker. Mathematical models of the non-normal spiral chutes are set up to optimize the geometrical parameters of the spiral curved surface, which would ensure that coal travels smoothly to the bottom of the bunker. The results would be useful for designing and retrofitting the spiral bunker.
基金Supported by the NSSFC(02BTJ001) Supported by the NSSFC(04BTJ002) Supported by the Grant for Post-Doctorial Fellows in Southeast University
文摘This paper is devoted to a study of geometric properties of AR(q) nonlinear regression models. We present geometric frameworks for regression parameter space and autoregression parameter space respectively based on the weighted inner product by fisher information matrix. Several geometric properties related to statistical curvatures are given for the models. The results of this paper extended the work of Bates & Watts(1980,1988)[1.2] and Seber & Wild (1989)[3].
文摘Most implantation cases are implemented using implants selected from the available standard set, but in some cases, only those implants conforming to individual patient's skeletal morphology can serve the purpose. This paper proposes a new approach to design and fabricate custom-made exact-fit medical implants. With a real surgical case as the example,technical design details are presented; and three algorithms are given respectively for segmentation based on object features, triangular mesh defragmentation and mesh cutting.