A large amount of coal gangue from coal mining and processing is regarded as waste and usually stockpiled directly. In order to recycle the valuable elements from the coal gangue, an integrated process is proposed. Th...A large amount of coal gangue from coal mining and processing is regarded as waste and usually stockpiled directly. In order to recycle the valuable elements from the coal gangue, an integrated process is proposed. The process consists of three steps: 1concentrating alumina from the coal gangue via activation roasting followed by alkali leaching of Si O2 which produces alumina concentrate for alumina extraction by the Bayer process; 2) synthesizing tobermorite whiskers from the filtrated alkali liquo containing silicate via a hydrothermal method and reusing excess caustic liquor; and 3) enriching titanium component from the Baye process residue by sulfuric acid leaching. Alumina concentrate with 69.5% Al_2O_3 and mass ratio of alumina to silica(A/S) of 5.9pure 1.1 nm tobermorite whisker and TiO_2-rich material containing 33% TiO_2 are produced, respectively, with the optimal parameters Besides, the actual alumina digestion ratio of alumina concentrate reaches 80.4% at 270 oC for 40 min in the Bayer process.展开更多
With the increase in mining depth, the danger of coal and gas outbursts increases.In order to drain coal gas effectively and to eliminate the risk of coal and gas outbursts, we used a specific number of penetration bo...With the increase in mining depth, the danger of coal and gas outbursts increases.In order to drain coal gas effectively and to eliminate the risk of coal and gas outbursts, we used a specific number of penetration boreholes for draining of pressure relief gas.Based on the principle of overlying strata movement, deformation and pressure relief, a good effect of gas drainage was obtained.The practice in the Panyi coal mine has shown that, after mining the C11coal seam as the protective layer, the relative expansion deformation value of the protected layer C13 reached 2.63%, The permeability coefficient increased 2880 times, the gas drainage rate of the C13 coal seam increased to more than 60%, the amount of gas was reduced from 13.0 to 5.2 m3/t and the gas pressure declined from 4.4 to 0.4 MPa, which caused the danger the outbursts in the coal seams to be eliminated.The result was that we achieved a safe and highly efficient mining operation of the C13 coal seam.展开更多
To study the effect of different deformation mechanisms on the chemical structure of anthracite coals and further understand the correlation between changed chemical structures and coal and gas outburst, ten groups of...To study the effect of different deformation mechanisms on the chemical structure of anthracite coals and further understand the correlation between changed chemical structures and coal and gas outburst, ten groups of sub-high-temperature and sub-high-pressure deformation experiments were performed. All samples maintained primary structure, which were collected from the Qudi Mine in the southern Qinshui Basin of China. The samples were analyzed by ultimate analysis, Vitrinite Reflection(VR), Fourier Transform Infrared spectroscopy(FTIR), and Raman spectroscopy both before and after deformation experiments for contrasting. The results showed that the VR values of all samples after experiments were significantly higher than before experiments, which suggested that the metamorphism degree of anthracite coals was increased by deformation. The results also indicated that both temperature and strain rate had significant effects on the chemical structure of anthracite coals. At a high strain rate of 4×10?5 s?1, the deformation of the samples was mainly brittle in which the mechanical energy was transformed mainly into frictional energy. In this situation, all samples developed several distinct fractured surfaces and the change of chemical structures was not obvious. On the contrary, with the decrease of the strain rates, the ductile deformation was dominated and the mechanical energy was mainly transformed into strain energy, resulting in the accumulation of deformation energy confessed by increasing quantity of dislocation and creep in the coal's interior nucleus. The absorption in the aromatic ring groups increased; otherwise the absorption in the aliphatic structures and ether oxygen groups decreased rapidly. During these experiments, CO was collected from two experimental samples. The number of aromatic rings and the structure defects within the two generated gas samples increased and the degree of molecular structure orders decreased.展开更多
基金Projects(51234008,51174230)supported by the National Natural Science Foundation of ChinaProject(NCET-11-0515)supported by the Program for New Century Excellent Talents in University,ChinaProject supported by Co-Innovation Center for Clean and Efficient Utilization of Strategic Metal Mineral Resources,China
文摘A large amount of coal gangue from coal mining and processing is regarded as waste and usually stockpiled directly. In order to recycle the valuable elements from the coal gangue, an integrated process is proposed. The process consists of three steps: 1concentrating alumina from the coal gangue via activation roasting followed by alkali leaching of Si O2 which produces alumina concentrate for alumina extraction by the Bayer process; 2) synthesizing tobermorite whiskers from the filtrated alkali liquo containing silicate via a hydrothermal method and reusing excess caustic liquor; and 3) enriching titanium component from the Baye process residue by sulfuric acid leaching. Alumina concentrate with 69.5% Al_2O_3 and mass ratio of alumina to silica(A/S) of 5.9pure 1.1 nm tobermorite whisker and TiO_2-rich material containing 33% TiO_2 are produced, respectively, with the optimal parameters Besides, the actual alumina digestion ratio of alumina concentrate reaches 80.4% at 270 oC for 40 min in the Bayer process.
基金Projects 2005CB221503 supported by the National Basic Research Program of China70533050 and 50674089 by the National Natural Science Foundationof China
文摘With the increase in mining depth, the danger of coal and gas outbursts increases.In order to drain coal gas effectively and to eliminate the risk of coal and gas outbursts, we used a specific number of penetration boreholes for draining of pressure relief gas.Based on the principle of overlying strata movement, deformation and pressure relief, a good effect of gas drainage was obtained.The practice in the Panyi coal mine has shown that, after mining the C11coal seam as the protective layer, the relative expansion deformation value of the protected layer C13 reached 2.63%, The permeability coefficient increased 2880 times, the gas drainage rate of the C13 coal seam increased to more than 60%, the amount of gas was reduced from 13.0 to 5.2 m3/t and the gas pressure declined from 4.4 to 0.4 MPa, which caused the danger the outbursts in the coal seams to be eliminated.The result was that we achieved a safe and highly efficient mining operation of the C13 coal seam.
基金supported by National Natural Science Foundation of China(Grant No.41030422)Strategic Leading Special Science and Technology from Academy of Chinese Academy of Sciences(Grant No.XDA05030100)
文摘To study the effect of different deformation mechanisms on the chemical structure of anthracite coals and further understand the correlation between changed chemical structures and coal and gas outburst, ten groups of sub-high-temperature and sub-high-pressure deformation experiments were performed. All samples maintained primary structure, which were collected from the Qudi Mine in the southern Qinshui Basin of China. The samples were analyzed by ultimate analysis, Vitrinite Reflection(VR), Fourier Transform Infrared spectroscopy(FTIR), and Raman spectroscopy both before and after deformation experiments for contrasting. The results showed that the VR values of all samples after experiments were significantly higher than before experiments, which suggested that the metamorphism degree of anthracite coals was increased by deformation. The results also indicated that both temperature and strain rate had significant effects on the chemical structure of anthracite coals. At a high strain rate of 4×10?5 s?1, the deformation of the samples was mainly brittle in which the mechanical energy was transformed mainly into frictional energy. In this situation, all samples developed several distinct fractured surfaces and the change of chemical structures was not obvious. On the contrary, with the decrease of the strain rates, the ductile deformation was dominated and the mechanical energy was mainly transformed into strain energy, resulting in the accumulation of deformation energy confessed by increasing quantity of dislocation and creep in the coal's interior nucleus. The absorption in the aromatic ring groups increased; otherwise the absorption in the aliphatic structures and ether oxygen groups decreased rapidly. During these experiments, CO was collected from two experimental samples. The number of aromatic rings and the structure defects within the two generated gas samples increased and the degree of molecular structure orders decreased.
