最近核邻型的光滑条件分位过程强逼近及其应用

文中证明了核邻型的光滑条件分位过程的强逼近，获得了其一致逼近速度．并由此结果推导出了光滑条件分位估计的渐近正态性、弱收敛和对数律等深刻结果．

The MAP/PH(PH/PH)/1 Discrete-time Queuing System with Repairable Server

In this paper, we discuss a discrete time repairable queuing system with Markovian arrival process, where lifetime of server, service time and repair time of server are all discrete phase type random variables. Using the theory of matrix geometric solution, we give the steady state distribution of queue length and waiting time. In addition, the stable availability of the system is also provided.

Phase Transition Analysis Based Quality Prediction for Multi-phase Batch Processes

Batch processes are usually involved with multiple phases in the time domain and many researches on process monitoring as well as quality prediction have been done using phase information. However, few of them consider phase transitions, though they exit widely in batch processes and have non-ignorable impacts on product qualities. In the present work, a phase-based partial least squares (PLS) method utilizing transition information is proposed to give both online and offline quality predictions. First, batch processes are divided into several phases using regression parameters other than prior process knowledge. Then both steady phases and transitions which have great influences on qualities are identified as critical-to-quality phases using statistical methods. Finally, based on the analysis of different characteristics of transitions and steady phases, an integrated algorithm is developed for quality prediction. The application to an injection molding process shows the effectiveness of the proposed algorithm in comparison with the traditional MPLS method and the phase-based PLS method.

Study on destressing technology for a roadway driven along goaf in a fully mechanized top-coal caving face

Based on the deformation characteristics of the roadways driven along goaf in fully mechanized top coal caving faces, the author considers that it is the key to ensure the stability of surrounding rocks of roadway driven along goaf to control the deformation during the period affected by mining. Considering the characteristics of the roadway layout in fully mechanized top coal caving faces, a technical scheme of destressing is put forward and the destressing effect is analyzed by using the software of Universal Distinct Element Code 3 0(UDEC 3 0).

Study on high and steep slope stability of surface mine based on RFPA-SRM

The instability and failure mechanism of high and steep slopes in surface mines, and the basis for some reasonable landslide prevention measures were provided using the RFPA-SRM. Based on the actual progress of the Pingzhuang Western Surface Mine and based on strength reduction method, the dynamic instability processes of the top high and steep slope was simulated. Also, the landslide mode was determined, the characteristics of the displacement distribution, the deformation, failure, and the stress distribution in the slope were demonstrated, and the stability was calculated. Conclusions can be drawn as follows： the landslide or failure of high and steep slopes on a surface mine is a gradual process, in which the slope undergoes the generation, expansion, and connection of the fractures and the displacement increases until landslide occurs; a small portion of the upper rocks fail due to the tension and the lower rocks fail due to the shear; the potential sliding surface is combined and the essential cause of the landslide is the shear stress concentration.

Multi-dimensional hierarchical CoS_(2)@MXene as trifunctional electrocatalysts for zinc-air batteries and overall water splitting

The demanding all-in-one electrocatalyst system for oxygen reduction reaction(ORR), oxygen evolution reaction(OER) and hydrogen evolution reaction(HER) in zinc-air batteries or water splitting requires elaborate material manufacturing, which is usually complicated and time-consuming.Efficient interface engineering between MXene and highly active electrocatalytic species(CoS_(2)) is, herein, achieved by an in situ hydrothermal growth and facile sulfurization process.The CoS_(2)@MXene electrocatalyst is composed by one-dimensional CoS_(2) nanowires and two-dimensional MXene nanosheets, which lead to a hierarchical structure(large specific surface area and abundant active sites), a spatial electron redistribution(high intrinsic activity), and high anchoring strength(superior performance stability). Therefore, the electrocatalyst achieves enhanced catalytic activity and longtime stability for ORR(a half-wave potential of 0.80 V), OER(an overpotential of 270 mV at 10 mA cm^(-2), i.e., η10= 270 mV)and HER(η10= 175 mV). Furthermore, the asymmetry water splitting system based on the CoS_(2)@MXene composites delivers a low overall voltage of 1.63 V at 10 mA cm^(-2). The solidstate zinc-air batteries using CoS_(2)@MXene as the air cathode display a small charge-discharge voltage gap(0.53 V at1 mA cm^(-2)) and superior stability(60 circles and 20-h continuous test). The energy interconversion between the chemical energy and electricity can be achieved by a self-powered system via integrating the water splitting system and quasisolid-state zinc-air batteries. Supported by in situ Raman analyses, the formation of cobalt oxyhydroxide species provides the active sites for water oxidation. This study paves apromising avenue for the design and application of multifunctional nanocatalysts.

Carbon isotope fractionation during CH_4 transport in paddy fields

In this study,to further promote the application of the stable carbon isotope natural abundance(SCINA)method to the study of CH4in paddy fields in China,field experiments were carried out to investigate carbon isotope fractionation during CH4transport in both rice-and non-rice-growing seasons.More importantly,two new methods for the measurement of the CH4transport fractionation factor(εtransport)in paddy fields were introduced.The results indicated that the closed chamber+syringe method was much better for the determination ofεtransport during the non-rice-growing season.Presently,εtransport was calculated using theδ13C value of the CH4emitted from a rice field minus that of the CH4in the floodwater(–6.7‰to–3.0‰).In addition,there were three methods available for estimatingεtransport during the rice-growing season:deduction of theδ13C value of the CH4in the floodwater from that of the CH4emitted from the field(–16.6‰to–15.2‰);deduction of theδ13C value of the CH4in the soil pore water from that of the CH4emitted from the field(–13.2‰to–1.1‰);and deduction of theδ13C value of the CH4in the aerenchyma of plants from that of the CH4emitted from plants(–16.3‰to–10.9‰).Unfortunately,the first two methods showed relatively large uncertainties.Only the last one,the dividing+cutting method,was not only scientific and reliable but also provided accurate measurements.

Oxygen vacancies in metal oxides: recent progresstowards advanced catalyst design

Energy crisis and environmental problems urgently drive the proposal of new strategies to improve human wellbeing and assist sustainable development.To this end,scientists have explored many metal oxides-based photocatalysts with high stability,low cost,earth abundance,and potentially high catalytic activity relevant for key applications such as H2O splitting,CO2 reduction,N2 fixation,and advanced oxidation of pollutants.In these metal oxides,oxygen vacancies(OVs)are ubiquitous and intrinsic defects with pronounced impacts on the physicochemical properties of the catalysts,which may open new opportunities for obtaining efficient metal oxides.The thorough understanding of the structural and electronic nature of OVs is necessary to determine how they serve as catalytically active sites.In this review,we summarize the origin of OVs,the strategies to introduce OVs,as well as the fundamental structure-activity relationships to relate these crystal defects to catalyst properties including light absorption,charge separation,etc.We emphasize the mechanism of OVs formation and their effects on the intrinsic catalytic characteristics of the metal oxides.We also present some multicomponent catalytic platforms where OVs contribute to catalysis via synergy.Finally,opportunities and challenges on engineering defects in photocatalysts are summarized to highlight the future directions of this research field.

In-situ observation for formation and dissociation of carbon dioxide hydrate in porous media by magnetic resonance imaging

The study of formation and dissociation of CO 2 hydrate in porous media was characterized by magnetic resonance imaging (MRI) system in in situ conditions. This work simulated porous media by using glass beads of uniform size. The growth and dissociation habit of CO2 hydrate was observed under different temperature and pressure conditions. The induction time and the hydrate saturation during the growth and dissociation process in different sizes of porous media were obtained by using the MRI signal intensity. The results indicate that hydrate growth rate and the induction time are affected by the size of porous media, pressure, and degree of supercooling. There are three hydrate growth stages, i.e., initial growth stage, rapid growth stage and steady stage. In this study,the CO2 hydrate forms preferentially at the surface of vessel and then gradually grows inward. The hydrate tends to cement the glass beads together and occupies the pore gradually. As the hydrate decomposes gradually, the dissociation rate increases to the maximum and then decreases to zero.

The molecular dynamics of neural metabolism during the action potential

Neural information processing is tightly coupled to both energy consumption and derivation from substrates.In this study,the energy function of the neuron during the action potential(AP)is described and analyzed.It has been observed that energy consumption during the AP does not match predictions of the conventional theory of neural energy dynamics.On short time scales,neural energy expenditure shifts between positive and negative phases.During the AP,the energy source switches from neuronal stores(positive expenditure or net consumption)to exploitation of external substrates,specifically the glucose and oxygen carried in cerebral blood(the negative consumption phase).Based on the idea of reductionism,this paper demonstrates how ion channels,membrane pumps and transporters,ionotropic and metabotropic receptor signaling pathways,astrocyte glycolysis and the production lactate,and the glutamate-glutamine cycle all serve to relate cerebral blood flow and neuronal metabolism to neuronal activity and so maintain neuronal energy charge during the AP.

Nonparametric estimation of quantiles for a class of stationary processes

We study smoothed quantile estimator for a class of stationary processes. We obtain the convergency rates and the Bahadur representation, as well as the asymptotic normality for this estimator by the method of m-dependent approximation. Our results can be used in the study of the estimation of value-at-risk(Va R) and applied to many time series which have important applications in econometrics.

In situ observations of tungsten speciation and partitioning behavior during fluid exsolution from granitic melt

Most economically important tungsten(W)deposits are of magmatic-hydrothermal origin.The species and partitioning of W during fluid exsolution,considered to be the controlling factors for the formation of ore deposits,are thus of great significance to investigate.However,this issue has not been well addressed mainly due to the significant difference in reported partition coefficients(e.g.,from strongly incompatible to strongly compatible)between fluid and melt(D_(W)^(fluid/melt)).Here,we used an in situ Raman spectroscopic approach to describe the W speciation,and to quantitatively determine the Dfluid/melt of individual and total W species in granite melts and coexisting Na2WO4 solutions at elevated temperatures(T;700–800C)and pressures(P;0.35–1.08 GPa).Results show that WO_(4)^(2-)and HWO4are predominant W species,and the fractions of these two species are similar in melt and coexisting fluid.The partitioning behaviors of WO_(4)^(2-)and HWO4are comparable,exhibiting strong enrichment in the fluid.The total DW fluid/melt ranges from 8.6 to 37.1.Specifically,DW fluid/melt decreases with rising T–P,indicating that shallow exsolution favors enrichment of W in evolved fluids.Furthermore,Rayleigh fractionation modeling based on the obtained D_(W)^(fluid/melt)data was used to describe the fluid exsolution processes.Our results strongly support that fluid exsolution can serve as an important mechanism to generate W-rich oreforming fluids.This study also indicates that in situ approach can be used to further investigate the geochemical behavior of ore-forming elements during the magmatic-hydrothermal transition,especially for rare metals associated with granite and pegmatite.