Datong coal was extracted with CS2, n-hexane, benzene, methanol, acetone, tetrahydro-furan（THF） and THF/methanol（1：3,v/v） mixed solvent sequentially. The extracts were analyzed with GC/MS. It is presented that gr...Datong coal was extracted with CS2, n-hexane, benzene, methanol, acetone, tetrahydro-furan（THF） and THF/methanol（1：3,v/v） mixed solvent sequentially. The extracts were analyzed with GC/MS. It is presented that group seperation of soluble organic compounds in the coal can be achieved by fractionated extraction using different solvents. The results show that CS2 was effective for extracting arenes from the coal sample, n-Hexane extractable fraction from Datong coal mainly consists of n-alkanes. A great variety of oxygen-containing compounds are dominant in the components of methanol-soluble fraction. Acyclic isoprenoids, pentecyclic triterpanes and a series of cyclohexanes with long-chain alkyl-substitutes are detected in acetone-soluble fraction. Dicyclic aramatic hydrocarbons are identified in benzene-soluble fraction and 4-6 cyclic condensed aramatic hydrocarbons are identified in THF-soluble fraction. The molecular structures detection of 1,2-dichlorobenzene, 2,4-dibromophnol, 2,4,6-tribromophenol and 4-chlorobenzophenone firstly provide information for existence form of bromine and chlorine in coal.展开更多
Piperock, a kind of characteristic ichnofabrics in Phanerozoic, was thought to decline gradually from Cambrian to Ordovician. A new compilation on the occurrences of the Cambrian and Ordovician piperocks of China and ...Piperock, a kind of characteristic ichnofabrics in Phanerozoic, was thought to decline gradually from Cambrian to Ordovician. A new compilation on the occurrences of the Cambrian and Ordovician piperocks of China and the world shows that piperocks generally flourished in Cambrian and declined in Ordovician, but a sharp decrease occurred during Middle and Late Cambrian. The case-study on the piperocks from the Lower-Middle Ordovician Hongshiya Formation at Dabaochang of Qiaojia, northern Yunnan Province, Southwest China indicates that the forming and preservation of piperocks were controlled by the depositional environment, the intensities of predation, competition, bioturbation, and the contents of nutrition and oxygen in watermass. A careful study on the development of the Cambrian and Ordovician piperocks suggests that the decrease of nearshore siliciclastic sediments and the low contents of oxygen and nutrition in the watermass may have contributed to the decline of piperocks in Middle and Late Cambrian.展开更多
基金Projects 20076051, G1999022101, and 98029016 supported by National Natural Science Foundation of China, the Special Found for Major State BasicResearch Project, and Research Found for the Doctoral Program of Higher Education
文摘Datong coal was extracted with CS2, n-hexane, benzene, methanol, acetone, tetrahydro-furan（THF） and THF/methanol（1：3,v/v） mixed solvent sequentially. The extracts were analyzed with GC/MS. It is presented that group seperation of soluble organic compounds in the coal can be achieved by fractionated extraction using different solvents. The results show that CS2 was effective for extracting arenes from the coal sample, n-Hexane extractable fraction from Datong coal mainly consists of n-alkanes. A great variety of oxygen-containing compounds are dominant in the components of methanol-soluble fraction. Acyclic isoprenoids, pentecyclic triterpanes and a series of cyclohexanes with long-chain alkyl-substitutes are detected in acetone-soluble fraction. Dicyclic aramatic hydrocarbons are identified in benzene-soluble fraction and 4-6 cyclic condensed aramatic hydrocarbons are identified in THF-soluble fraction. The molecular structures detection of 1,2-dichlorobenzene, 2,4-dibromophnol, 2,4,6-tribromophenol and 4-chlorobenzophenone firstly provide information for existence form of bromine and chlorine in coal.
基金supported by National Natural Science Foundation of China (Grant Nos. 40972020, 40825006)Chinese Academy of Sciences (Grant No. KZCX2-YW-Q05-01)State Key Laboratory of Palaeobiology and Stratigraphy
文摘Piperock, a kind of characteristic ichnofabrics in Phanerozoic, was thought to decline gradually from Cambrian to Ordovician. A new compilation on the occurrences of the Cambrian and Ordovician piperocks of China and the world shows that piperocks generally flourished in Cambrian and declined in Ordovician, but a sharp decrease occurred during Middle and Late Cambrian. The case-study on the piperocks from the Lower-Middle Ordovician Hongshiya Formation at Dabaochang of Qiaojia, northern Yunnan Province, Southwest China indicates that the forming and preservation of piperocks were controlled by the depositional environment, the intensities of predation, competition, bioturbation, and the contents of nutrition and oxygen in watermass. A careful study on the development of the Cambrian and Ordovician piperocks suggests that the decrease of nearshore siliciclastic sediments and the low contents of oxygen and nutrition in the watermass may have contributed to the decline of piperocks in Middle and Late Cambrian.
