Within the model, a definition of novel saturation and dilution degree is presented. A novel expression of equilibrium constant is derived by including interactions between components to reversible processes running b...Within the model, a definition of novel saturation and dilution degree is presented. A novel expression of equilibrium constant is derived by including interactions between components to reversible processes running between the components particles under a dynamic equilibrium. For partition equilibria, three types of basic processes are proposed and corresponding partition isotherms were derived. The isotherms are applied to the components partition between two phases for main heterogenous systems types. For construction and prediction ternary phase diagrams, a new method, the Component Binding by Saturation Model （CBSM） method, is proposed. Applying the partition isotherms derived, new extraction, evaporation and adsorption isotherms are expressed. Directly, or after an approximation, from the new adsorption isotherms, well-known adsorption isotherms are obtained.展开更多
文摘Within the model, a definition of novel saturation and dilution degree is presented. A novel expression of equilibrium constant is derived by including interactions between components to reversible processes running between the components particles under a dynamic equilibrium. For partition equilibria, three types of basic processes are proposed and corresponding partition isotherms were derived. The isotherms are applied to the components partition between two phases for main heterogenous systems types. For construction and prediction ternary phase diagrams, a new method, the Component Binding by Saturation Model （CBSM） method, is proposed. Applying the partition isotherms derived, new extraction, evaporation and adsorption isotherms are expressed. Directly, or after an approximation, from the new adsorption isotherms, well-known adsorption isotherms are obtained.
