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A universal thermodynamic model of calculating mass action concentrations for structural units or ion couples in aqueous solutions and its applications in binary and ternary aqueous solutions 被引量:1
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作者 杨学民 赵伟洁 +2 位作者 柴国明 郭汉杰 张强 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第3期626-641,共16页
A universal thermodynamic model of calculating mass action concentrations for structural units or ion couples in ternary and binary strong electrolyte aqueous solution was developed based on the ion and molecule coexi... A universal thermodynamic model of calculating mass action concentrations for structural units or ion couples in ternary and binary strong electrolyte aqueous solution was developed based on the ion and molecule coexistence theory and verified in four kinds of binary aqueous solutions and two kinds of ternary aqueous solutions. The calculated mass action concentrations of structural units or ion couples in four binary aqueous solutions and two ternary solutions at 298.15 K have good agreement with the reported activity data from literatures after shifting the standard state and concentration unit. Therefore, the calculated mass action concentrations of structural units or ion couples from the developed universal thermodynamic model for ternary and binary aqueous solutions can be applied to predict reaction ability of components in ternary and binary strong electrolyte aqueous solutions. It is also proved that the assumptions applied in the developed thermodynamic model are correct and reasonable, i.e., strong electrolyte aqueous solution is composed of cations and anions as simple ions, H2O as simple molecule and other hydrous salt compounds as complex molecules. The calculated mass action concentrations of structural units or ion couples in ternary and binary strong electrolyte aqueous solutions strictly follow the mass action law. 展开更多
关键词 universal thermodynamic model mass action concentration activity ternary aqueous solution binary aqueous solution ion and molecule coexistence theory structural units ion couples components
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Thermodynamic model of lead oxide activity in PbO-CaO-SiO_2-FeO-Fe_2O_3 slag system
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作者 汪金良 温小椿 张传福 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第5期1633-1639,共7页
According to the ion and molecule coexistence theory, a thermodynamic model of lead oxide activity in PbO-CaO-SiO2-FeO-Fe2O3 slag system was established at the temperature of 1273-1733 K. The activities of Pb O in sla... According to the ion and molecule coexistence theory, a thermodynamic model of lead oxide activity in PbO-CaO-SiO2-FeO-Fe2O3 slag system was established at the temperature of 1273-1733 K. The activities of Pb O in slag were calculated, and their equal activity curves were plotted. The influences of slag basicity Q, iron oxide rate R and temperature T on activity NPb O and activity coefficient γPbO were also investigated. Results show that the calculated values of γPb O are in good agreement with the reported experimental data, showing that the model can wholly embody the slag structural characteristics. NPbO departures positively from Raoult values, and increases with increasing Pb O content in slag but changes little with T. γPbO increases with increasing Q, and goes through the maximum with increasing R for basic slag(Q0.3). Results can be applied to the thermodynamic research and operational optimization of modern lead smelting technologies. 展开更多
关键词 ion and molecule coexistence theory thermodynamic model lead oxide ACTIVITY
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脱磷保碳的理论与试验研究
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作者 沈昶 常立忠 +4 位作者 汪开忠 张萍 朱正海 何飞 周俐 《钢铁钒钛》 CAS 北大核心 2018年第3期107-112,共6页
基于分子—离子共存理论建立了CaO-MgO-FeO-SiO2-P2O5五元渣系作用浓度计算模型,在此基础上分析了炉渣组元对脱碳、脱磷反应吉布斯自由能变化的影响规律,证明了脱磷保碳的可行性,并通过高温试验发现:在初始碳含量为0.5%、磷含量为0.032... 基于分子—离子共存理论建立了CaO-MgO-FeO-SiO2-P2O5五元渣系作用浓度计算模型,在此基础上分析了炉渣组元对脱碳、脱磷反应吉布斯自由能变化的影响规律,证明了脱磷保碳的可行性,并通过高温试验发现:在初始碳含量为0.5%、磷含量为0.032 5%的情况下,当熔渣碱度控制在5左右、FeO含量控制在10%20%时,脱磷率可达75%以上,留碳率在50%70%。 展开更多
关键词 炼钢 脱磷 保碳 分子—离子共存理论 吉布斯自由能
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