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分子双轴性与液晶向列相的最高过热温度
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作者 樊军 王俊平 张志东 《液晶与显示》 CAS CSCD 2004年第2期107-111,共5页
向列相 (N) 各向同性相 (I)相变为弱一级相变 ,其相变潜热大约比溶化的相变潜热小2个数量级。在这种弱一级相变附近焓随温度的变化表明 :各向同性相最低过冷温度T 、N I相变温度TC 和向列相最高过热温度T 彼此十分接近。本文通过分子... 向列相 (N) 各向同性相 (I)相变为弱一级相变 ,其相变潜热大约比溶化的相变潜热小2个数量级。在这种弱一级相变附近焓随温度的变化表明 :各向同性相最低过冷温度T 、N I相变温度TC 和向列相最高过热温度T 彼此十分接近。本文通过分子统计理论研究这一现象。形成单轴向列相的液晶分子并不具有D∞ 对称性。在分子场近似下和二粒子集团近似下 ,随分子双轴性参数增大 ,T /T 增大并趋近于 1。 展开更多
关键词 向列相液晶 分子双轴性 最高过热温度 分子场近似 二粒子集团近似 相变温度
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Dy_2Fe_(17-x)Al_x化合物中的R──T交换耦合常数的计算
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作者 郝延明 高艳 +1 位作者 王博文 李淑英 《河北工业大学学报》 CAS 2001年第4期5-8,共4页
提出利用分子场近似结合中子衍射或X射线衍射的实验结果,计算R2Fe17型稀土过 渡族化合物中的稀土磁矩与过渡族磁矩之间的交换耦合常数的方法.计算了 Dy2Fe17-xAlx (x=2,3,4,5,6,7,8)化合物中的... 提出利用分子场近似结合中子衍射或X射线衍射的实验结果,计算R2Fe17型稀土过 渡族化合物中的稀土磁矩与过渡族磁矩之间的交换耦合常数的方法.计算了 Dy2Fe17-xAlx (x=2,3,4,5,6,7,8)化合物中的稀土磁矩与过渡族磁矩之间的交换耦合常数-JRT/k, 结果分别为7,77 K,7.27 K,7.39 K,8.62 K,8.64K,9.52 K,10.34 K.其中对x=5,6, 7,8的化合物计算结果与高场测量的实验值8.77 K,9.25 K,10.1K,10.9K符合得较好. 说明从分子场理论出发,利用X射线衍射或中子衍射的结果更细致地考虑一些替代的细 节,计算稀土过渡族化合物中的稀土(R)磁矩与过渡族(T)磁矩之间的交换耦合常数是 一种可取的方法. 展开更多
关键词 稀土过渡族金属间化合物 交换耦合常数 分子场近似 双格子模型 中子衍射 计算 磁性能 镝铁铝金属间化合物
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Analysis on Far-Field of Slab Waveguide and Its Gaussian Approximation
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作者 李连煌 郭福源 +2 位作者 彭玉家 唐晓姗 高瑞 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第2期347-350,共4页
This paper researches end diffraction of slab waveguide and then matching efficiency between the far-field and its Gaussian approximate field is analyzed leads to a new definition of divergence half-angle. Finally, wh... This paper researches end diffraction of slab waveguide and then matching efficiency between the far-field and its Gaussian approximate field is analyzed leads to a new definition of divergence half-angle. Finally, why the far-field can be approximated by a Gaussian function is presented according to characteristic of beam propagation factor. 展开更多
关键词 guided-wave optics DIFFRACTION divergence half-angle Gaussian approximation
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Novel Quantum Phases of Ultracold Bosonic Atoms in Honeycomb Optical Lattice
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作者 陆青青 侯净敏 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第5期861-863,共3页
We study the quantum phase transition of ultracold atoms in the honeycomb optical lattice. The Hamiltonian of ultracold bosonic atoms in the honeycomb optical lattice is derived. We take the mean-field approximation a... We study the quantum phase transition of ultracold atoms in the honeycomb optical lattice. The Hamiltonian of ultracold bosonic atoms in the honeycomb optical lattice is derived. We take the mean-field approximation and further solve the Hamiltonian with the numerical diagonalization method. We obtain the phase diagram and find that the Mort-insulator (MI), density wave (DW) and modulated superfluid (MS) phases appear. Furthermore, the phase diagram is analyzed according to the order parameter and the average number of particles. 展开更多
关键词 honeycomb optical lattice quantum phase transition ultracold atoms
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General Formulations of Finite-field Method Classifiedby Symmetry for Molecular Linear and Nonlinear Polarizabilities
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作者 陈锡华 林晨升 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2001年第5期369-380,共12页
The formulations of the finite-field approach to calculate the linear and non-linear optical coefficients (i, (ij, (ijk and (ijkl of a molecular system with different symmetries have been deduced and summarized. The p... The formulations of the finite-field approach to calculate the linear and non-linear optical coefficients (i, (ij, (ijk and (ijkl of a molecular system with different symmetries have been deduced and summarized. The possible choices of the energy sets of the 48 frequent point groups have been optimized and categorized into 11 classes. With the restriction of symmetry operators, a minimum of 9, no more than 21 energy points have to be calculated in order to determine the coefficients, except in the case of the first class to which C1 point group belongs and in which the 34 non-relative energy points selected in our uniform and general scheme are all needed. The symmetric operators that cause some of the tensor components to vanish have been demonstrated as well. 展开更多
关键词 nonlinear optical polarizability finite-field approach point group symmetry
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