Excess heat capacities at glass transition temperature in two types of glass-forming systems of [xNaNO3(1x)KNO3]60·[Ca(NO3)2]40(0x1) and Ca(NO3)2yH2O(4y13) are studied.In the former system,with the replacement of...Excess heat capacities at glass transition temperature in two types of glass-forming systems of [xNaNO3(1x)KNO3]60·[Ca(NO3)2]40(0x1) and Ca(NO3)2yH2O(4y13) are studied.In the former system,with the replacement of K + cation with Na + cation,the excess heat capacity is around 65.1 J mol-1·K-1,while the excess increases by 38.9 J mol-1·K-1 upon one molar H2O content in latter system.A quantitative description to the excess heat capacity is built up with the thermal effects of atomic and molecular translational motion in liquids.The results might offer a further understanding to the glass transition.展开更多
A dual-core photonic crystal fiber(PCF)polarization splitter based on lead silicate glass is proposed.The characteristics of the polarization splitter are analyzed using full-vector finite element method.Compared with...A dual-core photonic crystal fiber(PCF)polarization splitter based on lead silicate glass is proposed.The characteristics of the polarization splitter are analyzed using full-vector finite element method.Compared with the silica glass PCF polarization splitter with the same structure,it is shown that the new material polarizer can realize splitting with less coupling loss and higher extinction ratio.When the wavelength is 1 550 nm and the PCF length in the beam splitter is 688μm,the coupling loss is only 0.001 9 d B,and the extinction ratio for the input core is-64.1 d B.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 51071170 and 11274353)the National Basic Research Program of China (Grant Nos. 2007CB613904 and 2010CB-731603)
文摘Excess heat capacities at glass transition temperature in two types of glass-forming systems of [xNaNO3(1x)KNO3]60·[Ca(NO3)2]40(0x1) and Ca(NO3)2yH2O(4y13) are studied.In the former system,with the replacement of K + cation with Na + cation,the excess heat capacity is around 65.1 J mol-1·K-1,while the excess increases by 38.9 J mol-1·K-1 upon one molar H2O content in latter system.A quantitative description to the excess heat capacity is built up with the thermal effects of atomic and molecular translational motion in liquids.The results might offer a further understanding to the glass transition.
基金supported by the National Natural Science Foundation of China(No.11004152)
文摘A dual-core photonic crystal fiber(PCF)polarization splitter based on lead silicate glass is proposed.The characteristics of the polarization splitter are analyzed using full-vector finite element method.Compared with the silica glass PCF polarization splitter with the same structure,it is shown that the new material polarizer can realize splitting with less coupling loss and higher extinction ratio.When the wavelength is 1 550 nm and the PCF length in the beam splitter is 688μm,the coupling loss is only 0.001 9 d B,and the extinction ratio for the input core is-64.1 d B.
