期刊文献+
共找到6篇文章
< 1 >
每页显示 20 50 100
聚多巴胺磁分子印迹材料制备及其在食用油中黄曲霉毒素B富集中的应用 被引量:1
1
作者 胡美华 索莉莉 +2 位作者 董瑞婷 杨银堂 官吉军 《食品安全质量检测学报》 CAS 北大核心 2022年第19期6391-6398,共8页
目的建立了基于聚多巴胺磁性分子印迹聚合物吸附富集食用油中黄曲霉毒素B的方法。方法以多巴胺为功能单体和交联剂,5,7-二甲氧基香豆素为模拟模板分子,一步法在Fe_(3)O_(4) NPs表面制备磁分子印迹聚合物。采用透射电子显微镜和红外光谱... 目的建立了基于聚多巴胺磁性分子印迹聚合物吸附富集食用油中黄曲霉毒素B的方法。方法以多巴胺为功能单体和交联剂,5,7-二甲氧基香豆素为模拟模板分子,一步法在Fe_(3)O_(4) NPs表面制备磁分子印迹聚合物。采用透射电子显微镜和红外光谱仪对该分子印迹材料形态和结构进行表征,研究了其对两种黄曲霉毒素B吸附性能。最终以该印迹材料作为分散固相萃取剂,对影响黄曲霉毒素B吸附的条件进行了优化。结果该分子印迹材料对两种黄曲霉毒素B的吸附模式符合Langmuir理论,对黄曲霉毒素B_(1)和黄曲霉毒素B_(2)最大吸附容量分别为0.460和0.047 mg/g。在最佳萃取条件[材料用量(10 mg)、溶液pH(7)、超声时间(5 min)和1 mL(解吸2次,每次0.5 mL)3%乙酸/乙腈作为解析液]下,结合配有大体积流通池的超高效液相色谱-荧光检测法定量检测,黄曲霉毒素B_(1)和黄曲霉毒素B_(2)浓度分别在0.005~0.500 ng/mL(r=0.9989)和0.001~0.100 ng/mL(r=0.9992)范围内与对应的峰面积呈现良好的线性相关性,检出限分别为0.0024和0.00038 ng/mL,食用油样品加标回收率为93.2%~104.0%,相对标准偏差5.8%~7.7%,且可重复使用至少7次。结论该吸附富集方法具有快速、低廉、选择性高、稳定性好等特点,适用于食用油中黄曲霉毒素B的前处理。 展开更多
关键词 分子印迹材料 5 7-二甲氧基香豆素 黄曲霉毒素B 多巴胺 食用油 一步法
下载PDF
桥联多核铬配合物的研究进展
2
作者 常艳玲 唐宗薰 崔斌 《宝鸡文理学院学报(自然科学版)》 CAS 2004年第1期19-28,47,共11页
多核铬配合物既可以作为葡萄糖耐量因子(GTF)的模型配合物,同时在分子磁材料的研究中占有重要地位,得到了广泛的研究。结合55篇参考文献,概述了近年来氧桥联、氰桥联、硫氰根桥联等多核配合物的研究进展状况。
关键词 多核铬配合物 分子磁材料 桥联
下载PDF
Unusual Charge Transport and Spin Response of Doped Bilayer Triangular Antiferromagnets 被引量:3
3
作者 LIANGying MATian-Xing FENGShi-Ping 《Communications in Theoretical Physics》 SCIE CAS CSCD 2003年第6期749-756,共8页
Within the t-J model, the charge transport and spin response of the doped bilayer triangular antiferromagnetare studied by considering the bilayer interaction. Although the bilayer interaction leads to the band splitt... Within the t-J model, the charge transport and spin response of the doped bilayer triangular antiferromagnetare studied by considering the bilayer interaction. Although the bilayer interaction leads to the band splitting in theelectronic structure, the qualitative behaviors of the physical properties are the same as in the single layer case. Theconductivity spectrum shows the low-energy peak and unusual midinfrared band, the temperature-dependent resistivityis characterized by the nonlinearity metallic-like behavior in the higher temperature range and the deviation from themetallic-like behavior in the lower temperature range and the commensurate neutron scattering peak near the half-fillingis split into six incommensurate peaks in the underdoped regime, with the incommensurability increasing with the holeconcentration at lower dopings, and saturating at higher dopings. 展开更多
关键词 charge transport spin response t-J model
下载PDF
Effects of Transverse Field on Internal Energy and Specific Heat of a Molecular-Based Materials
4
作者 JIANG Wei YU Gui-Hong ZHANG Fan WANG Wei JIANG Yuan 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第11期965-968,共4页
The molecular-based magnetic materials AFe11 Fe111(C2O4)3 have a honeycomb structure in which FeII (S = 2) and FeIH (S= 5/2) occupy sites alternately. They can be described as mixed spin-2 and spin-5/2 Ising mod... The molecular-based magnetic materials AFe11 Fe111(C2O4)3 have a honeycomb structure in which FeII (S = 2) and FeIH (S= 5/2) occupy sites alternately. They can be described as mixed spin-2 and spin-5/2 Ising model with ferrimagnetic interlayer coupling. The influences of the transverse field on the internal energy and the specific heat of the molecalar-based magnetic system have been studied numerically by using the effective-field theory with self-spin correlations and the differential operator technique. 展开更多
关键词 transverse field molecular-based magnet internal energy specific heat
下载PDF
An introduction to molecular spintronics 被引量:2
5
作者 JIANG ShangDa GOB Karin +1 位作者 CERVETTI Christian BOGANI Lapo 《Science China Chemistry》 SCIE EI CAS 2012年第6期867-882,共16页
We review the progress and future possibilities in the emerging area of molecular spintronics. We first provide an overview of the different transport regimes in which electronic nanodevices can operate, then briefly ... We review the progress and future possibilities in the emerging area of molecular spintronics. We first provide an overview of the different transport regimes in which electronic nanodevices can operate, then briefly overview the important characteristics of molecular magnetic materials that can be useful for application in spintronics and we eventually present several schemes to include such systems into spintronic nanodevices. We hightlight the importance of a chemical approach to the area, and in the last section we showcase some approaches to the creation of hybrids made of carbon nanostructures and molecular magnets, which are gaining increasing attention. 展开更多
关键词 carbon nanostructures molecular spintronics molecular magnetism quantum transport electronicnanodevices
原文传递
Preface
6
作者 高松 《Science China Chemistry》 SCIE EI CAS 2012年第6期865-865,共1页
In the past three decades, molecular magnetism has been a rapidly growing interdisciplinary field in chemistry, phys- ics and materials sciences. It covers diverse range of topics including inorganic/organic/hybrid ma... In the past three decades, molecular magnetism has been a rapidly growing interdisciplinary field in chemistry, phys- ics and materials sciences. It covers diverse range of topics including inorganic/organic/hybrid magnetic molecular ma- terials, multifunctional and/or switchable magnetic molecu- lar materials, molecular nanomagnets, nanostructural mo- lecular magnets, molecular spintronics and biomagnetism. Much research on molecular magnetism has been carried out in China both before and after we organized the Interna- tional Conference on Molecule-Based Magnets 2010 (ICMM 2010) in Beijing. 展开更多
关键词 earthquake risk stress state meta-instable state evolution of the temperature field synergism bending fault
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部