In this paper,we present a new method for seismic stratigraphic absorption compensation based on the adaptive molecular decomposition.Using this method,we can remove most of the effects resulting from wavelets truncat...In this paper,we present a new method for seismic stratigraphic absorption compensation based on the adaptive molecular decomposition.Using this method,we can remove most of the effects resulting from wavelets truncation and interference which usually exist in the common time-frequency absorption compensation method.Based on the assumption that the amplitude spectrum of the source wavelet is smooth,we first construct a set of adaptive Gabor frames based on the time-variant properties of the seismic signal to transform the signal into the time-frequency domain and then extract the slowly varying component(the wavelet's time-varying amplitude spectrum) in each window in the timefrequency domain.Then we invert the absorption compensation filter parameters with an objective function defined using the correlation coefficients in each window to get the corresponding compensation filters.Finally,we use these filters to compensate the timefrequency spectrum in each window and then transform the time-frequency spectrum to the time domain to obtain the absorption-compensated signal.By using adaptive molecular decomposition,this method can adapt to isolated and overlapped seismic signals from the complex layers in the inhomogeneous viscoelastic medium.The viability of the method is verified by synthetic and real data sets.展开更多
Simulations were carried out for studying the periodic phase separation of a symmetric binary polymer blend on the basis of Cahn-Hilliard-Cook theory. The time dependent interaction parameter x(τ) was assumed to un...Simulations were carried out for studying the periodic phase separation of a symmetric binary polymer blend on the basis of Cahn-Hilliard-Cook theory. The time dependent interaction parameter x(τ) was assumed to undergo a step-wise oscillation. The hierarchic structures composed of both large and small domains were obtained. The mechanism of the periodic formation of hierarchic structures was also demonstrated.展开更多
A dynamic hierarchical description method for workflow is presented. The method provides a dynamic hierarchical way to define a workflow with non-determinate or dynamic factors. With this method, the main process defi...A dynamic hierarchical description method for workflow is presented. The method provides a dynamic hierarchical way to define a workflow with non-determinate or dynamic factors. With this method, the main process defined at build-time can be reified and extended by the principle of the sub-organizations at either the build-time or the run-time. To ensure the consistency and integrity of the description, a series of constraint rules are also discussed to realize seamless integration between a decomposed process and its original one. This approach supports the description of unpredictable uncertainties, the dynamic hierarchy of business process, and the dynamic modification of enterprise organizations, and all of these improve the flexibility and extendability of workflow management systems dramatically.展开更多
In pursuit of low-cost direct formic acid fuel cells,tungsten carbide(WC)supported Pd catalyst is considered as an ideal candidate for efficient decomposition of formic acid due to low Pd utilization and excellent per...In pursuit of low-cost direct formic acid fuel cells,tungsten carbide(WC)supported Pd catalyst is considered as an ideal candidate for efficient decomposition of formic acid due to low Pd utilization and excellent performance.Herein,different adsorption configurations and active sites of the intermediates,involved in the HCOOH decomposition,on WC(0001)-supported Pd monolayer(Pd/WC(0001))surface investigated by using density functional theory.The results reveal that trans-HCOOH,HCOO,cis-COOH,trans-COOH,HCO,CO,H2 O,OH and H exhibit chemisorption on Pd/WC(0001)surface,whereas cis-HCOOH and CO2 exhibit weak interactions with Pd/WC(0001)surface.In addition,the minimum energy pathways of HCOOH decomposition are analyzed to generate CO and CO2 due to the fracture of C–H,H–O and C–O bonds.The adsorbed HCOOH,HCOO,mH COO,cis-COOH and trans-COOH configurations exhibit dissociation rather than desorption.CO formation occurs through the decomposition of cis-COOH,trans-COOH and HCO,whereas the CO2 formation happens due to the decomposition of HCOO.It is found that the most favorable pathway for HCOOH decomposition on Pd/WC(0001)surface is HCOOH→HCOO→CO2,where the formation of CO2 from HCOO dehydrogenation determines the reaction rate.Overall,CO2 is the most dominant product of HCOOH decomposition on Pd/WC(0001)surface.The presence of WC,as monolayer Pd carrier,does not alter the catalytic behavior of Pd and significantly reduces the Pd utilization.展开更多
The maximum effective hole-diameter mathematical modei describing the flow of slightly compressible fluid through a commingled reservoir was solved rigorously with consideration of wellbore storage and different skin ...The maximum effective hole-diameter mathematical modei describing the flow of slightly compressible fluid through a commingled reservoir was solved rigorously with consideration of wellbore storage and different skin factors. The exact solutions for wellbore pressure and the production rate obtained from layer j for a well production at a constant rate from a radial drainage area with infinite and constant pressure and no flow outer boundary condition were expressed in terms of ordinary Bessel functions. These solutions were computed numerically by the Crump's numerical inversion method and the behavior of systems was studied as a function of various reservoir parameters. The modei was compared with the real wellbore radii modei. The new modei is numerically stable when the skin factor is positive and negative, but the real wellbore radii modei is numerically stable only when the skin factor is positive.展开更多
Accurate prediction of magmatic intrusion into a coal bed is illustrated using the method of seismic spectral decomposition.The characteristics of coal seismic reflections are first analyzed and the effect of variable...Accurate prediction of magmatic intrusion into a coal bed is illustrated using the method of seismic spectral decomposition.The characteristics of coal seismic reflections are first analyzed and the effect of variable time windows and domain frequencies on the spectral decomposition are examined.The higher domain frequency of coal bed reflections using the narrower STFT time window,or the smaller ST scale factor,are acceptable.When magmatic rock intrudes from the bottom of the coal bed the domain frequency of the reflections is decreased slightly,the frequency bandwidth is narrowed correspondingly,and the response from spectral decomposition is significantly reduced.Intrusion by a very thin magmatic rock gives a spectral decomposition response that is just slightly less than what is seen from a normal coal bed.Results from an actual mining area were used to validate the method.Predicting the boundary of magmatic intrusions with the method discussed herein was highly accurate and has been validated by observations from underground mining.展开更多
The optimal selection of schemes of water transportation projects is a process of choosing a relatively optimal scheme from a number of schemes of water transportation programming and management projects, which is of ...The optimal selection of schemes of water transportation projects is a process of choosing a relatively optimal scheme from a number of schemes of water transportation programming and management projects, which is of importance in both theory and practice in water resource systems engineering. In order to achieve consistency and eliminate the dimensions of fuzzy qualitative and fuzzy quantitative evaluation indexes, to determine the weights of the indexes objectively, and to increase the differences among the comprehensive evaluation index values of water transportation project schemes, a projection pursuit method, named FPRM-PP for short, was developed in this work for selecting the optimal water transportation project scheme based on the fuzzy preference relation matrix. The research results show that FPRM-PP is intuitive and practical, the correction range of the fuzzy rained is both stable and accurate; preference relation matrix A it produces is relatively small, and the result obtherefore FPRM-PP can be widely used in the optimal selection of different multi-factor decision-making schemes.展开更多
The photocatalytic degradation of norfloxacin by bismuth tungstate(Bi2WO6)with different hierarchical architectures wasinvestigated under visible light irradiation.Bi2WO6was prepared by hydrothermal method with the re...The photocatalytic degradation of norfloxacin by bismuth tungstate(Bi2WO6)with different hierarchical architectures wasinvestigated under visible light irradiation.Bi2WO6was prepared by hydrothermal method with the reaction solution pH rangingfrom4to11.The relatively ultrathin Bi2WO6nanoflakes prepared at pH4showed excellent adsorption and photodegradationefficiency towards norfloxacin.The characterization results showed that Bi2WO6prepared at pH4had a larger specific area andfaster photo-generated carrier separation rate.The decay rate reached the maximum in weak alkaline reaction solution,which couldbe attributed to the presence of moderate OH-anions.The present study demonstrated that the smaller size of Bi2WO6could be anefficient photocatalyst on the degradation of norfloxacin in the aquatic environment.展开更多
The rapid recombination of photo-generated electron-hole pairs,insufficient active sites,and strong photocorrosion have considerably restricted the practical application of Cd S in photocatalytic fields.Herein,we desi...The rapid recombination of photo-generated electron-hole pairs,insufficient active sites,and strong photocorrosion have considerably restricted the practical application of Cd S in photocatalytic fields.Herein,we designed and constructed a 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling interfaces.Experiments using electron spin resonance spectroscopy,ultraviolet photoelectron spectroscopy,and in-situ irradiation X-ray photoelectron spectroscopy were conducted to confirm the 2D layered CdS/WO_(3) step-scheme(S-scheme)heterojunctions and CdS/MX ohmic junctions.Impressively,it was found that the strong interfacial electric fields in the S-scheme heterojunction photocatalysts could effectively promote spatially directional charge separation and transport between CdS and WO_(3) nanosheets.In addition,2D Ti_(3)C_(2) MXene nanosheets with a smaller work function and excellent metal conductivity when used as a co-catalyst could build ohmic junctions with Cd S nanosheets,thus providing a greater number of electron transfer pathways and hydrogen evolution sites.Results showed that the highest visible-light hydrogen evolution rate of the optimized MX-Cd S/WO_(3) layered multi-heterostructures could reach as high as 27.5 mmol/g/h,which was 11.0 times higher than that of pure CdS nanosheets.Notably,the apparent quantum efficiency reached 12.0% at 450 nm.It is hoped that this study offers a reliable approach for developing multifunctional photocatalysts by integrating S-scheme and ohmic-junction built-in electric fields and rationally designing a 2D/2D interface for efficient light-to-hydrogen fuel production.展开更多
Indomethacin has been encapsulated with polyelectrolyte multilayers for controlled release. Gelatin and alginate were alternatively deposited on indomethacin microcrystals. The released amount of indomethacin from coa...Indomethacin has been encapsulated with polyelectrolyte multilayers for controlled release. Gelatin and alginate were alternatively deposited on indomethacin microcrystals. The released amount of indomethacin from coated microcrystals in pH6. 8 phosphate buffer solution (PBS) was measured with a UV spectrophometer. The polyelectrolyte multilayer capsule thickness was proved to control the release rate. The effects of osmotic pressure existed during the release process of indomethacin from microcapsules coated by (gelatin/alginate) 4.展开更多
Dissociation of molecular hydrogen (H2) is extensively studied to understand the mechanism of hydrogenation reactions. In this study, H2 dissociation by Aul-doped closed-shell titanium oxide cluster anions AuTi3O7 a...Dissociation of molecular hydrogen (H2) is extensively studied to understand the mechanism of hydrogenation reactions. In this study, H2 dissociation by Aul-doped closed-shell titanium oxide cluster anions AuTi3O7 and AuTi3O8 has been identified by mass spectrometry and quantum chemistry calculations. The clusters were generated by laser ablation and mass- selected to react with H2 in art ion trap reactor. In the reaction of AuTi3O8 with H2, the ion pair Au+-O22 rather than Au+-O2 is the active site to promote H2 dissociation. This finding is in contrast with the previous result that the lattice oxygen is usually the reactive oxygen species in H2 dissociation. The higher reactivity of the peroxide species is further supported by frontier molecular orbital analysis. This study provides new insights into gold catalysis involving H2 activation and dissociation.展开更多
基金supported by the National 863 Program of China (Grant No.2006A09A102)National Natural Science Foundation of China (Grant No.40730424)Important National Science & Technology Specific Projects (Grant No.2008ZX05023005005)
文摘In this paper,we present a new method for seismic stratigraphic absorption compensation based on the adaptive molecular decomposition.Using this method,we can remove most of the effects resulting from wavelets truncation and interference which usually exist in the common time-frequency absorption compensation method.Based on the assumption that the amplitude spectrum of the source wavelet is smooth,we first construct a set of adaptive Gabor frames based on the time-variant properties of the seismic signal to transform the signal into the time-frequency domain and then extract the slowly varying component(the wavelet's time-varying amplitude spectrum) in each window in the timefrequency domain.Then we invert the absorption compensation filter parameters with an objective function defined using the correlation coefficients in each window to get the corresponding compensation filters.Finally,we use these filters to compensate the timefrequency spectrum in each window and then transform the time-frequency spectrum to the time domain to obtain the absorption-compensated signal.By using adaptive molecular decomposition,this method can adapt to isolated and overlapped seismic signals from the complex layers in the inhomogeneous viscoelastic medium.The viability of the method is verified by synthetic and real data sets.
文摘Simulations were carried out for studying the periodic phase separation of a symmetric binary polymer blend on the basis of Cahn-Hilliard-Cook theory. The time dependent interaction parameter x(τ) was assumed to undergo a step-wise oscillation. The hierarchic structures composed of both large and small domains were obtained. The mechanism of the periodic formation of hierarchic structures was also demonstrated.
文摘A dynamic hierarchical description method for workflow is presented. The method provides a dynamic hierarchical way to define a workflow with non-determinate or dynamic factors. With this method, the main process defined at build-time can be reified and extended by the principle of the sub-organizations at either the build-time or the run-time. To ensure the consistency and integrity of the description, a series of constraint rules are also discussed to realize seamless integration between a decomposed process and its original one. This approach supports the description of unpredictable uncertainties, the dynamic hierarchy of business process, and the dynamic modification of enterprise organizations, and all of these improve the flexibility and extendability of workflow management systems dramatically.
基金supported by the National Natural Science Foundation of China(21776259)Key Laboratory of Micro-Nano Powder and Advanced Energy Materials of Anhui Higher Education Institutes,Chizhou University~~
文摘In pursuit of low-cost direct formic acid fuel cells,tungsten carbide(WC)supported Pd catalyst is considered as an ideal candidate for efficient decomposition of formic acid due to low Pd utilization and excellent performance.Herein,different adsorption configurations and active sites of the intermediates,involved in the HCOOH decomposition,on WC(0001)-supported Pd monolayer(Pd/WC(0001))surface investigated by using density functional theory.The results reveal that trans-HCOOH,HCOO,cis-COOH,trans-COOH,HCO,CO,H2 O,OH and H exhibit chemisorption on Pd/WC(0001)surface,whereas cis-HCOOH and CO2 exhibit weak interactions with Pd/WC(0001)surface.In addition,the minimum energy pathways of HCOOH decomposition are analyzed to generate CO and CO2 due to the fracture of C–H,H–O and C–O bonds.The adsorbed HCOOH,HCOO,mH COO,cis-COOH and trans-COOH configurations exhibit dissociation rather than desorption.CO formation occurs through the decomposition of cis-COOH,trans-COOH and HCO,whereas the CO2 formation happens due to the decomposition of HCOO.It is found that the most favorable pathway for HCOOH decomposition on Pd/WC(0001)surface is HCOOH→HCOO→CO2,where the formation of CO2 from HCOO dehydrogenation determines the reaction rate.Overall,CO2 is the most dominant product of HCOOH decomposition on Pd/WC(0001)surface.The presence of WC,as monolayer Pd carrier,does not alter the catalytic behavior of Pd and significantly reduces the Pd utilization.
基金National Natural Science Foundation of China(No.50206016)Special Funds for Major State Basic Research Program of China(973 Program,No.1999022308)
文摘The maximum effective hole-diameter mathematical modei describing the flow of slightly compressible fluid through a commingled reservoir was solved rigorously with consideration of wellbore storage and different skin factors. The exact solutions for wellbore pressure and the production rate obtained from layer j for a well production at a constant rate from a radial drainage area with infinite and constant pressure and no flow outer boundary condition were expressed in terms of ordinary Bessel functions. These solutions were computed numerically by the Crump's numerical inversion method and the behavior of systems was studied as a function of various reservoir parameters. The modei was compared with the real wellbore radii modei. The new modei is numerically stable when the skin factor is positive and negative, but the real wellbore radii modei is numerically stable only when the skin factor is positive.
基金provided by the National Natural Science Foundation of China (Nos. 40804026 and 40874054)the Postdoctoral Science Foundation of China (No. 20100471003)+2 种基金the Postdoctoral Science Foundation of Jiangsu Province (No.1002023B)the Open Projects of State Key Laboratory of Coal Resources and Mine Safety (No. 10KF05)the Youth Foundation of CUMT,are gratefully acknowledged
文摘Accurate prediction of magmatic intrusion into a coal bed is illustrated using the method of seismic spectral decomposition.The characteristics of coal seismic reflections are first analyzed and the effect of variable time windows and domain frequencies on the spectral decomposition are examined.The higher domain frequency of coal bed reflections using the narrower STFT time window,or the smaller ST scale factor,are acceptable.When magmatic rock intrudes from the bottom of the coal bed the domain frequency of the reflections is decreased slightly,the frequency bandwidth is narrowed correspondingly,and the response from spectral decomposition is significantly reduced.Intrusion by a very thin magmatic rock gives a spectral decomposition response that is just slightly less than what is seen from a normal coal bed.Results from an actual mining area were used to validate the method.Predicting the boundary of magmatic intrusions with the method discussed herein was highly accurate and has been validated by observations from underground mining.
基金The authors would like to acknowledge the funding support of the National Natural Science Foundation of China (Nos. 50579009, 70425001 ) the National 10th Five Year Scientific Project of China for Tackling the Key Problems (2004BA608B-02-02)the Excellence Youth Teacher Sustentation Fund Program of the Ministry of Education of China (Department of Education and Personnel [ 2002 ] 350).
文摘The optimal selection of schemes of water transportation projects is a process of choosing a relatively optimal scheme from a number of schemes of water transportation programming and management projects, which is of importance in both theory and practice in water resource systems engineering. In order to achieve consistency and eliminate the dimensions of fuzzy qualitative and fuzzy quantitative evaluation indexes, to determine the weights of the indexes objectively, and to increase the differences among the comprehensive evaluation index values of water transportation project schemes, a projection pursuit method, named FPRM-PP for short, was developed in this work for selecting the optimal water transportation project scheme based on the fuzzy preference relation matrix. The research results show that FPRM-PP is intuitive and practical, the correction range of the fuzzy rained is both stable and accurate; preference relation matrix A it produces is relatively small, and the result obtherefore FPRM-PP can be widely used in the optimal selection of different multi-factor decision-making schemes.
基金Projects(51579096,51222805,51521006,51508175) supported by the National Natural Science Foundation of ChinaProject supported by the National Program for Support of Top-Notch Young Professionals of China+1 种基金Project(NCET–11–0129) supported by the Program for New Century Excellent Talents in University from the Ministry of Education of ChinaProject(CX2015B095) supported by the Hunan Province Innovation Foundation for Postgraduate,China
文摘The photocatalytic degradation of norfloxacin by bismuth tungstate(Bi2WO6)with different hierarchical architectures wasinvestigated under visible light irradiation.Bi2WO6was prepared by hydrothermal method with the reaction solution pH rangingfrom4to11.The relatively ultrathin Bi2WO6nanoflakes prepared at pH4showed excellent adsorption and photodegradationefficiency towards norfloxacin.The characterization results showed that Bi2WO6prepared at pH4had a larger specific area andfaster photo-generated carrier separation rate.The decay rate reached the maximum in weak alkaline reaction solution,which couldbe attributed to the presence of moderate OH-anions.The present study demonstrated that the smaller size of Bi2WO6could be anefficient photocatalyst on the degradation of norfloxacin in the aquatic environment.
文摘The rapid recombination of photo-generated electron-hole pairs,insufficient active sites,and strong photocorrosion have considerably restricted the practical application of Cd S in photocatalytic fields.Herein,we designed and constructed a 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling interfaces.Experiments using electron spin resonance spectroscopy,ultraviolet photoelectron spectroscopy,and in-situ irradiation X-ray photoelectron spectroscopy were conducted to confirm the 2D layered CdS/WO_(3) step-scheme(S-scheme)heterojunctions and CdS/MX ohmic junctions.Impressively,it was found that the strong interfacial electric fields in the S-scheme heterojunction photocatalysts could effectively promote spatially directional charge separation and transport between CdS and WO_(3) nanosheets.In addition,2D Ti_(3)C_(2) MXene nanosheets with a smaller work function and excellent metal conductivity when used as a co-catalyst could build ohmic junctions with Cd S nanosheets,thus providing a greater number of electron transfer pathways and hydrogen evolution sites.Results showed that the highest visible-light hydrogen evolution rate of the optimized MX-Cd S/WO_(3) layered multi-heterostructures could reach as high as 27.5 mmol/g/h,which was 11.0 times higher than that of pure CdS nanosheets.Notably,the apparent quantum efficiency reached 12.0% at 450 nm.It is hoped that this study offers a reliable approach for developing multifunctional photocatalysts by integrating S-scheme and ohmic-junction built-in electric fields and rationally designing a 2D/2D interface for efficient light-to-hydrogen fuel production.
基金The National Key Fundamental Research FundGrant number:9732003C8615700+1 种基金The National Natural Science Fund of ChinaGrant number:20376068
文摘Indomethacin has been encapsulated with polyelectrolyte multilayers for controlled release. Gelatin and alginate were alternatively deposited on indomethacin microcrystals. The released amount of indomethacin from coated microcrystals in pH6. 8 phosphate buffer solution (PBS) was measured with a UV spectrophometer. The polyelectrolyte multilayer capsule thickness was proved to control the release rate. The effects of osmotic pressure existed during the release process of indomethacin from microcapsules coated by (gelatin/alginate) 4.
基金supported by the National Natural Science Foundation of China(No.21573246,No.21773253,and No.21773254)the Beijing Natural Science Foundation(2172059)the Youth Innovation Promotion Association,Chinese Academy of Sciences(2016030)
文摘Dissociation of molecular hydrogen (H2) is extensively studied to understand the mechanism of hydrogenation reactions. In this study, H2 dissociation by Aul-doped closed-shell titanium oxide cluster anions AuTi3O7 and AuTi3O8 has been identified by mass spectrometry and quantum chemistry calculations. The clusters were generated by laser ablation and mass- selected to react with H2 in art ion trap reactor. In the reaction of AuTi3O8 with H2, the ion pair Au+-O22 rather than Au+-O2 is the active site to promote H2 dissociation. This finding is in contrast with the previous result that the lattice oxygen is usually the reactive oxygen species in H2 dissociation. The higher reactivity of the peroxide species is further supported by frontier molecular orbital analysis. This study provides new insights into gold catalysis involving H2 activation and dissociation.